Anodic electrochromic materials having a solublizing moiety
First Claim
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1. An electrochromic medium for use in an electrochromic device, comprising:
- at least one solvent;
a cathodic electrochromic material;
an anodic electrochromic material which includes;
a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene; and
a second moiety, wherein the second moiety comprises at least one constituent which serves to increase solubility of the first moiety in the at least one solvent relative to the first moiety without the second moiety.
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Abstract
Anodic electrochromic materials for use in an electrochromic device comprising a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene, and a second moiety, wherein the second moiety comprises at least one constituent which serves to increase the solubility of the first moiety in an associated solvent relative to solubility of the first moiety without the second moiety.
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Citations
30 Claims
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1. An electrochromic medium for use in an electrochromic device, comprising:
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at least one solvent;
a cathodic electrochromic material;
an anodic electrochromic material which includes;
a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene; and
a second moiety, wherein the second moiety comprises at least one constituent which serves to increase solubility of the first moiety in the at least one solvent relative to the first moiety without the second moiety. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10)
wherein R1-R10 are the same or different and comprise H or a straight or branched alkyl group containing approximately 1 to approximately 10 carbon atoms and wherein at least one of R1-R10 is associated with the second moiety.
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4. The electrochromic medium according to claim 3, wherein R1-R10 are the same or different and at least three of R1-R10 comprise a straight or branched alkyl group containing approximately 1 to approximately 40 carbon atoms, and wherein any remainder of R1-R10 comprise H.
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5. The electrochromic medium according to claim 1, wherein the second moiety is selected from the group comprising nitriles, nitro constituents, sulfoxides, sulfonates, phosphonium constituents, phosphonates, phosphonites, ammonium constituents, viologens including bipyridinyl constituents, carbonyls including carbonates, carbamates, ketones, esters, and amides, ethers including polyethers, amines including tertiary amines, alkenes, alkynes, and mixtures thereof.
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6. The electrochromic medium according to claim 1, wherein the second moiety is represented by at least one of the formulae:
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wherein R11-R31 are the same or different and comprise H or a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 10 carbon atoms;
wherein Ar is an aryl constituent including phenyl;
wherein m is an integer ranging from approximately 1 to approximately 5;
wherein n is an integer ranging from approximately 1 to approximately 20; and
wherein X is associated with the first moiety and is selected from the group comprising a direct bond, an alkyl, aryl, alkaryl, aralkyl, ether, or polyether chain containing approximately 1 to approximately 40 carbon atoms, a silyl or siloxyl chain containing approximately 1 to approximately 40 silicon atoms, and mixtures thereof.
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7. The electrochromic medium according to claim 1, wherein the second moiety is represented the formula:
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8. The electrochromic medium according to claim 1, wherein the at least one solvent is selected from the group comprising 3-methylsulfolane, glutaronitrile, dimethyl sulfoxide, dimethyl formamide, acetonitrile, polyethers including tetraglyme, alcohols including ethoxyethanol, nitriles including 3-hydroxypropionitrile, 2-methylglutaronitrile, ketones including 2-acetylbutyrolactone, cyclopentanone, cyclic esters including beta-propiolactone, gamma-butyrolactone, gamma-valerolactone, propylene carbonate, ethylene carbonate and homogenous mixtures of the same.
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9. The electrochromic medium according to claim 1, wherein the concentration of the anodic electrochromic material ranges from approximately 1 mM to approximately 1000 mM.
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10. The electrochromic medium according to claim 9, wherein the concentration of the anodic electrochromic material ranges from approximately 5mM to approximately 500 mM.
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11. An electrochromic device, comprising:
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at least one substantially transparent substrate; and
an electrochromic medium which comprises;
at least one solvent;
a cathodic electrochromic material; and
an anodic electrochromic material which includes;
a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene; and
a second moiety, wherein the second moiety comprises at least one constituent which serves to increase solubility of the first moiety in the at least one solvent relative to the first moiety without the second moiety. - View Dependent Claims (12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25)
wherein R1-R10 are the same or different and comprise H or a straight or branched alkyl group containing approximately 1 to approximately 10 carbon atoms and wherein at least one of R1-R10 is associated with the second moiety.
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14. The electrochromic device according to claim 13, wherein R1-R10 are the same or different and at least three of R1-R10 comprise a straight or branched alkyl group containing approximately 1 to approximately 40 carbon atoms, and wherein any remainder of R1-R10 comprise H.
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15. The electrochromic device according to claim, 11, wherein the second moiety is selected from the group comprising nitriles, nitro constituents, sulfoxides, sulfonates, phosphonium constituents, phosphonates, phosphonites, ammonium constituents, viologens including bipyridinyl constituents, carbonyls including carbonates, carbamates, ketones, esters, and amides, ethers including polyethers, amines including tertiary amines, alkenes, alkynes, and mixtures thereof.
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16. The electrochromic device according to claim 11, wherein the second moiety is represented by at least one of the formulae:
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wherein R11-R31 are the same or different and comprise H or a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 10 carbon atoms;
wherein Ar is an aryl constituent including phenyl;
wherein m is an integer ranging from approximately 1 to approximately 5;
wherein n is an integer ranging from approximately 1 to approximately 20; and
wherein X is associated with the first moiety and is selected from the group comprising a direct bond, an alkyl, aryl, alkaryl, aralkyl, ether, or polyether chain containing approximately 1 to approximately 40 carbon atoms, a silyl or siloxyl chain containing approximately 1 to approximately 40 silicon atoms, and mixtures thereof.
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17. The electrochromic device according to claim 11, wherein the second moiety is represented the formula:
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18. The electrochromic device according to claim 11, wherein the at least one solvent is selected from the group comprising 3-methylsulfolane, glutaronitrile, dimethyl sulfoxide, dimethyl formamide, acetonitrile, polyethers including tetraglyme, alcohols including ethoxyethanol, nitriles including 3-hydroxypropionitrile, 2-methylglutaronitrile, ketones including 2-acetylbutyrolactone, cyclopentanone, cyclic esters including beta-propiolactone, gamma-butyrolactone, gamma-valerolactone, propylene carbonate, ethylene carbonate and homogenous mixtures of the same.
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19. The electrochromic device according to claim 11, wherein the concentration of the anodic electrochromic material ranges from approximately 1 mM to approximately 1000 mM.
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20. The electrochromic device according to claim 19, wherein the concentration of the anodic electrochromic material ranges from approximately 5 mM to approximately 500 mM.
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21. The electrochromic device according to claim 11, comprising a first substantially transparent substrate and a second substrate.
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22. The electrochromic device according to claim 21, wherein the device is an electrochromic window.
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23. The electrochromic device according to claim 21, wherein the second substrate is plated with a reflective material.
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24. The electrochromic device according to claim 23, wherein the reflective material is selected from the group comprising chromium, rhodium, silver, alloys of the same, and mixtures thereof.
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25. The electrochromic device according to claim 24, wherein the device is an electrochromic mirror.
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26. An anodic electrochromic material for use in an electrochromic device, comprising:
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a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene; and
a second moiety, wherein the second moiety comprises at least one constituent which serves to increase solubility of the first moiety in an associated solvent relative to the first moiety without the second moiety, and wherein the second moiety is selected from the group comprising nitriles, nitro constituents, sulfoxides, sulfonates, phosphonium constituents, phosphonates, phosphonites, polyethers, viologens including bipyridinyl constituents, carbonyls including carbonates, carbamates, ketones, cyclic esters, and amides, and mixtures thereof. - View Dependent Claims (27, 28, 29, 30)
wherein R1-R10 are the same or different and comprise H or a straight or branched alkyl group containing approximately 1 to approximately 10 carbon atoms and wherein at least one of R1-R10 is associated with the second moiety.
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29. The anodic electrochromic material according to claim 28, wherein R1-R10 are the same or different and at least three of R1-R10 comprise a straight or branched alkyl group containing approximately 1 to approximately 40 carbon atoms, and wherein any remainder of R1-R10 comprise H.
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30. The anodic electrochromic material according to claim 26, wherein the second moiety is represented by at least one of the formulae:
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wherein R11-17, R21-23, R25, and R29-31 are the same or different and comprise H or a branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 10 carbons;
wherein Ar is an aryl constituent including phenyl; and
wherein X is associated with the first moiety and is selected from the group comprising a direct bond, an alkyl, aryl, alkaryl, aralkyl, ether, or polyether chain containing approximately 1 to approximately 40 carbon atoms, a silyl or siloxyl chain containing approximately 1 to approximately 40 silicon atoms, and mixtures thereof.
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Specification