Method and apparatus for real time gas analysis

• US 6,272,905 B1
• Filed: 12/21/1999
• Issued: 08/14/2001
• Est. Priority Date: 08/18/1997
• Status: Expired due to Fees

• Current Assignee: Metasensors, Inc.
• Original Assignee: Metasensors, Inc.
• Inventors: Drzewiecki, Tadeusz M.
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): WIGGINS, JOHN DAVID
• Application Number:
  US09/468,793
• Time in Patent Office: 602 Days
• Field of Search: 73/53.01, 73/23.2, 73/23.3, 73/23.34, 73/30.01, 73/31.01, 73/61.41, 73/61.44, 73/1 G, 422/83, 422/84, 422/94
• US Class Current: 73/53.01
• CPC Class Codes: A61M 16/0051 with alarm devices
• CPC Class Codes: A61M 16/021 operated by electrical means A61M16/202 – A61M16/205 take precedence
• CPC Class Codes: A61M 16/0808 Condensation traps
• CPC Class Codes: A61M 16/085 Gas sampling
• CPC Class Codes: A61M 2016/1025 the O2 concentration
• CPC Class Codes: A61M 2016/103 the CO2 concentration
• CPC Class Codes: A61M 2016/1035 the anaesthetic agent concentration
• CPC Class Codes: A61M 2230/432 partial CO2 pressure (P-CO2)
• CPC Class Codes: A61M 2230/435 partial O2 pressure (P-O2)
• CPC Class Codes: G01F 1/3227 using fluidic oscillators fluidic oscillators per se F15C1/00
• CPC Class Codes: G01N 2291/02872 Pressure
• CPC Class Codes: G01N 2291/02881 Temperature
• CPC Class Codes: Y10T 137/2234 And feedback passage[s] or path[s]
• CPC Class Codes: Y10T 137/2506 By viscosity or consistency

Abstract

A method and apparatus for real time gas analysis involving determining individual concentrations of fluid constituents in a mixture of known constituents by measuring properties of the mixture and solving a set of equations, which relate the individual gas concentrations to the measured properties of the mixture, for the unknown individual gas concentrations. The individual concentrations of four gasses in a mixture are determined by: passing the mixture through a flowmeter, a capillary, an orifice, and a sonic oscillator; transducing temperature, pressure and acoustic frequency measurements taken from the sensors; determining the density, viscosity, and the specific heat of the mixture; forming three equations which respectively relate these three properties to individual gas concentrations; and solving the three equations and the constitutive equation which requires that the sum of the concentrations equal unity, for the four unknown individual gas concentrations. A single oscillator can serve as both a sensor (e.g., flowmeter, acoustic velocimeter) and an orifice. The fluidic sensors can be formed as a single chip disposable sensor module. By modifying only the processing software, the same sensors or a subset of the sensors can be used to verify or determine the identity of an unknown gas which is supplied by itself in a pure form or in a mixture of other gasses whose identities are known. By measuring N-1 properties of the gas mixture as a whole, the capabilities of an existing sensor system for measuring M gas concentrations can be extended to measure N additional gas concentrations, provided the identities of the gasses in the mixture are known. Similarly, by modifying only the processing software the same sensor can be used to analyze any sets of gas mixtures.

Claims

1. Method of determining whether a fluid flowing from a source is an expected, single-constituent fluid, the method comprising the steps of:

a) measuring the flow rate of the fluid;

b) measuring a pressure drop of the fluid across an orifice;

c) measuring a pressure drop of the fluid across a capillary;

d) computing at least one property of the fluid from the flow rate, the orifice pressure drop and the capillary pressure drop, said at least one property including at least one of density and viscosity; and

e) if each of said at least one property of the fluid is within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid, indicating that the fluid is the expected, single-constituent fluid.

2. The method of claim 1, further comprising:

f) indicating that the fluid is not the expected, single-constituent fluid if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

3. The method of claim 1, further comprising:

f) inhibiting a flow of the fluid if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

4. The method of claim 1, further comprising:

f) actuating an aural or visual alarm if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

5. The method of claim 1, wherein the method is performed repeatedly while the fluid is flowing.

7. The method of claim 1, further comprising:

f) measuring an acoustic frequency of the mixture; and

wherein step d) includes computing from the acoustic frequency the specific heat of the fluid as one of said at least one property of the fluid.

8. The method of claim 1, wherein, if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid, the method further comprises:

f) comparing each of said at least one property of the fluid to a value of a corresponding property of a second, single-constituent fluid; and

g) if each of said at least one property of the fluid is within a predetermined threshold of a value of a corresponding property of the second, single-constituent fluid, indicating that the fluid is the second, single-constituent fluid.

9. The method of claim 1, wherein said expected, single-constituent fluid is oxygen.

10. The method of claim 1, wherein said expected, single-constituent fluid is nitrous oxide.

11. The method of claim 1, wherein said expected, single-constituent fluid is a volatile anesthesia gas.

6. The method of claim , wherein step a) includes measuring the flow rate of the fluid through a fluidic flowmeter.

12. An apparatus for determining whether a fluid flowing from a source is an expected, single-constituent fluid, comprising:

a flowmeter configured to measure the flow rate of the fluid;

an orifice and a first sensor configured to measure a pressure drop of the fluid across the orifice;

a capillary and a second sensor configured to measure a pressure drop of the fluid across a capillary; and

a processor configured to;

compute at least one property of the fluid from the flow rate, the orifice pressure drop and the capillary pressure drop, said at least one property including at least one of density and viscosity; and

determine that the fluid is the expected, single-constituent fluid if each of said at least one property of the fluid is within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

13. The apparatus of claim 12, wherein the apparatus is configured to receive the fluid flowing from a pressurized tank.

14. The apparatus of claim 12, wherein the apparatus is configured to receive the fluid flowing from a supply line.

15. The apparatus of claim 12, wherein the apparatus is configured to receive the fluid flowing from a wall outlet supplying the fluid.

16. The apparatus of claim 12, wherein the apparatus further comprises:

an upstream terminal connectable to the source; and

a downstream terminal connectable to a local supply line.

17. The apparatus of claim 12, wherein the apparatus operates continuously while fluid is flowing from the source.

18. The apparatus of claim 12, wherein the apparatus repeatedly determines whether the fluid flowing from the source is the expected, single-constituent fluid.

19. The apparatus of claim 12, wherein the apparatus operates using electricity generated from pressure from flow of the fluid.

20. The apparatus of claim 12, wherein said processor determines that the fluid is not the expected, single-constituent fluid if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

21. The apparatus of claim 12, wherein said processor commands that the flow of the fluid be inhibited if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

22. The apparatus of claim 12, further comprising an alarm that is actuated if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid.

23. The apparatus of claim 22, wherein said alarm includes a visual display.

24. The apparatus of claim 22, wherein said alarm includes an audible sound.

25. The apparatus of claim 12, wherein said expected, single-constituent fluid is oxygen.

26. The apparatus of claim 12, wherein said expected, single-constituent fluid is nitrous oxide.

27. The apparatus of claim 12, wherein said expected, single-constituent fluid is a volatile anesthesia gas.

28. The apparatus of claim 12, wherein said flowmeter includes a fluidic oscillator through which the fluid flows and a plurality of microphones adapted to measure an oscillation frequency of the fluid in the fluidic oscillator.

29. The apparatus of claim 28, wherein a nozzle of said fluidic oscillator serves as said orifice.

30. The apparatus of claim 28, wherein said fluidic oscillator is a fluidic amplifier feedback oscillator flowmeter.

31. The apparatus of claim 12, wherein said capillary is one of a plurality of capillaries arranged to provide parallel resistance to flow of the mixture through said capillaries.

32. The apparatus of claim 12, further comprising a sonic oscillator and a third sensor configured to measure an acoustic frequency of the fluid flowing through said sonic oscillator, wherein said processor computes from the acoustic frequency the specific heat of the fluid as one of said at least one property of the fluid.

33. The apparatus of claim 12, wherein, if any of said at least one property of the fluid is not within a predetermined threshold of a value of a corresponding property of the expected, single-constituent fluid, said processor:

compares each of said at least one property of the fluid to a value of a corresponding property of a second, single-constituent fluid, and determines that the fluid is the second, single-constituent fluid if each of said at least one property of the fluid is within a predetermined threshold of a value of a corresponding property of the second, single-constituent fluid.