Semi-flooded lead acid battery cell

• US 6,274,263 B1
• Filed: 11/06/1998
• Issued: 08/14/2001
• Est. Priority Date: 10/27/1995
• Status: Expired due to Term

• Current Assignee: Philadelphia Scientific LLC (Philadelphia Scientific)
• Original Assignee: William E.M. Jones
• Inventors: Jones, William E. M.
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US09/188,025
• Time in Patent Office: 1,012 Days
• Field of Search: 429/53, 429/54, 429/56, 429/57, 429/82, 429/87, 429/204, 429/228
• US Class Current: 429/53
• CPC Class Codes: H01M 10/06 Lead-acid accumulators semi-lead accumulators H01M10/20
• CPC Class Codes: H01M 10/121 Valve regulated lead acid batteries [VRLA]
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 10/52 Removing gases inside the secondary cell, e.g. by absorption vent plugs or other mechanical arrangements for facilitating escape of gases H01M50/30
• CPC Class Codes: H01M 10/523 by recombination on a catalytic material
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 50/308 Detachable arrangements, e.g. detachable vent plugs or plug systems
• CPC Class Codes: H01M 50/325 comprising deformable valve members, e.g. elastic or flexible valve members
• CPC Class Codes: H01M 50/383 Flame arresting or ignition-preventing means
• CPC Class Codes: H01M 50/394 Gas-pervious parts or elements
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A lead acid storage battery cell having a sealed housing in which a positive electrode and a negative electrode are immersed in a liquid electrolyte. The negative electrode is partially exposed to a gas space within the battery cell housing. A pressure relief valve allows excess gas to escape the battery cell while preventing air from outside the cell from entering the gas space. Exposing a section of the negative plate to oxygen gas that evolves within the battery and collects in the gas space reduces water consumption of the cell and extends the maintenance-free life of the battery. The addition of a catalyst to recombine oxygen and hydrogen offers further improvement.

Claims

1. A lead acid battery, comprising:

a sealed housing;

a positive electrode comprising PbO₂ active material;

a negative electrode comprising lead active material;

a liquid electrolyte within said sealed housing in contact with said positive and negative electrodes, said electrolyte comprising sulfuric acid and having a liquid levels;

a gas space within said housing in which oxygen gas collects, said gas space having a bottom defined by said liquid level, a portion of said negative electrode being exposed in said gas space above said liquid level to thereby expose a portion of the lead active material to said gas space; and

a pressure relief valve disposed in said battery in communication with said gas space to allow gas to escape said sealed housing while preventing oxygen from outside the housing to contact said negative electrode.

2. A lead-acid electric battery in accordance to claim 1, wherein said positive electrode is completely submerged in said electrolyte.

3. A lead-acid battery in accordance with claim 1 wherein said negative electrode comprises a plate comprising said lead active material, said plate having a plate-section comprising a portion of said lead active material, said plate-section extending above the liquid level.

4. A lead-acid battery in accordance with claim 3 wherein said plate-section is an integral part of said plate.

5. A lead-acid battery in accordance with claim 1 wherein between about 0.25 percent and about 25 percent of the active material of the negative electrode is exposed in said gas space.

6. A lead-acid battery in accordance with claim 1 further comprising a negative strap connecting said negative electrode to a negative terminal disposed outside said housing, wherein said strap is submerged in said electrolyte.

7. A lead-acid battery in accordance with claim 1 further comprising a catalyst for recombining oxygen gas and hydrogen gas to form water, said catalyst being in communication with said gas space.

8. A lead-acid battery in accordance with claim 7 wherein between about 0.25 percent and about 25 percent of the active material of the negative plate is exposed in said gas space.

9. A lead-acid battery in accordance with claim 7 wherein said catalyst is selected from the group consisting of palladium, platinum, rhodium and tungsten carbide.

10. A lead-acid battery in accordance with claim 7 wherein said catalyst is combined with said pressure relief valve.

11. A lead-acid battery in accordance with claim 7 further comprising a separator disposed between said negative and positive electrodes.

12. A lead-acid battery in accordance with claim 11 wherein said separator comprises an absorptive separator made of a week wick material and having a section partially immersed in said electrollyte and another section in contact with said active material of said negative electrode above said liquid level.

13. A lead-acid battery in accordance with claim 12 wherein said sponge-like separator comprises glass fibers having a thickness of at least 10 microns.

14. A lead-acid storage battery, comprising:

a sealed housing;

a positive electrode comprising PbO₂ active material;

a negative electrode comprising lead active material;

a fluid electrolyte comprising sulfuric acid within said housing and in contact with said positive and negative electrodes;

a gas space disposed within said housing wherein oxygen gas produced within the battery collects, and in which a portion of said negative electrode is exposed to said oxygen gas as it collects in said gas space;

a catalyst for combining oxygen gas and hydrogen gas to form water, said catalyst positioned to be in communication with said gas space; and

a pressure relief valve disposed in said housing to allow excess gas to escape from said housing.

15. A lead-acid storage battery in accordance with claim 14 wherein said positive and negative electrodes comprise one or more alternating positive and negative plates.

16. A lead-acid storage battery in accordance with claim 15 wherein between about 0.25 percent and about 25 percent of the active material of the negative plate is exposed to oxygen gas in the gas space.

17. A lead-acid storage battery in accordance with claim 15 further comprising a separator disposed between said negative and positive plates.

18. A lead-acid storage battery in accordance with claim 17 wherein said separator comprises an absorptive separator having a section partially immersed in said electrolyte and another section in contact with said active material of said negative plate above said liquid level.

19. A lead-acid storage battery in accordance with claim 14 wherein between about 0.25 percent and about 25 percent of the active material of the negative electrode is exposed to oxygen gas in the gas space.

20. A method of reducing water consumption in a lead-acid storage battery having a sealed housing in which a negative electrode comprising lead as the active material and a positive electrode comprising PbO₂ as the active material are in contact with an electrolyte comprising sulfuric acid;

said method comprising;

(a) collecting oxygen gas produced within the battery in a gas space wherein said housing;

(b) exposing a portion of the active material of said negative electrode to the oxygen gas collected within said gas space wherein at least a potion of said oxygen gas reacts with hydrogen ions to form water;

(c) venting excess gas from said sealed housing; and

(d) preventing gas outside said sealed housing from entering said sealed housing.

21. The method of claim 20 further comprising the step of (e) exposing a catalyst to said gas collected in said gas space, said catalyst capable of combining oxygen gas and hydrogen gas to from water.

22. The method of claim 21 wherein steps (c) and (d) are carried out by a pressure relief valve, and the catalyst of step (e) is positioned within said pressure relief valve.

23. The method of claim 20 wherein said electrolyte is liquid electrolyte.