Epoxy/thermoplastic photocurable adhesive composition

• US 6,274,643 B1
• Filed: 07/26/2000
• Issued: 08/14/2001
• Est. Priority Date: 05/01/1998
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Meyer, Christopher M., Karim, Naimul, George, Clayton A.
• Primary Examiner(s): Berman, Susan W.
• Assistant Examiner(s): MCCLENDON, SANZA L
• Application Number:
  US09/626,212
• Time in Patent Office: 384 Days
• Field of Search: 522/181, 522/122, 522/100, 522/102, 522/113, 522/134, 522/143, 522/31, 522/83, 522/64, 522/66, 522/71, 428/413, 428/424.2, 428/424.8, 427/487, 427/517, 427/508, 427/496
• US Class Current: 522/31
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C09J 131/04 Homopolymers or copolymers of vinyl acetate
• CPC Class Codes: C09J 163/00 Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

Abstract

A curable composition comprising a) a curable epoxy resin, a thermoplastic ethylene-vinyl acetate copolymer resin, and an effective amount of a photocatalyst for the curable epoxy resin, wherein the composition is free from hydrocarbon polyolefins and wherein the sum of a) and b) is 100 weight percent.

Claims

1. A curable composition formed by mixing components comprising:

a) from about 20 to about 80 weight percent of a curable epoxy resin;

b) from about 20 to about 80 weight percent of a thermoplastic ethylene-vinyl acetate copolymer resin; and

c) an effective amount of a sulfonium or cationic organometallic salt photocatalyst for the curable epoxy resin, such that the total of components a) and b) is 100 weight percent and wherein the composition is free from hydrocarbon polyolefins and solvent and is a homogeneous mixture.

2. The curable composition according to claim 1 wherein said composition is a molten mixture.

3. The curable composition of claim 1 further comprising up to 50 percent by volume of one or more additives that alter the physical characteristics of the resulting cured composition.

4. The curable composition of claim 3 wherein the one or more additives comprises aluminum oxide.

5. The curable composition according to claim 1 wherein said composition is an unsupported film.

6. The curable composition of claim 1 wherein said composition is an adhesive film used in a tape or a protected film.

7. The curable composition according to claim 1 wherein the ethylene-vinyl acetate copolymer contains at least 28 percent vinyl acetate by weight of the copolymer.

8. The curable composition according to claim 6 provided in a roll construction.

9. The curable composition according to claim 1 wherein the photocatalyst is a cationic organometallic salt.

10. The curable composition according to claim 1 wherein the cationic organometallic salt is selected from the group consisting of (η

⁶-xylenes (mixed isomers)) (η

⁵-cyclopentadienyl)Fe⁺¹ SbF₆⁻

, (η

⁶-xylenes (mixed isomers)) (η

⁵-cyclopentadienyl)Fe⁺¹ PF₆⁻

, (η

⁶-xylene) (η

⁵-cyclopentadienyl)Fe⁺¹SbF₆⁻

, (η

⁶ -mesitylene) (η

⁵-cyclopentadienyl)Fe⁺¹SbF₆⁻

and mixtures thereof.

11. The curable composition according to claim 1 wherein said curable epoxy resin comprises at least one of an aliphatic, alicyclic, aromatic, and heterocyclic polyepoxide.

12. The curable composition of claim 1 wherein said composition is bonded to a substrate and cured.

13. The cured composition of claim 12 wherein said substrate is a metal or a polymer.

14. The curable composition according to claim 6 wherein said tape is bonded to a substrate and cured.