Coal combustion by-products-based lightweight structural materials and processes for making them

• US 6,277,189 B1
• Filed: 08/31/1999
• Issued: 08/21/2001
• Est. Priority Date: 08/31/1999
• Status: Expired due to Fees

• Current Assignee: Board of Trustees of Southern Illinois University
• Original Assignee: Board of Trustees of Southern Illinois University
• Inventors: Chugh, Yoginder P.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US09/386,978
• Time in Patent Office: 721 Days
• Field of Search: 106/705, 106/708, 106/709, 106/711, 106/640, 106/819, 106/823, 106/DIG.1, 264/333
• US Class Current: 106/705
• CPC Class Codes: C04B 18/061 Ashes from fluidised bed furnaces
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 28/021 Ash cements, e.g. fly ash cements fly ash as filler C04B18/08; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration alkali-activated combustion residues as such C04B7/243; mixtures of the lime-pozzuolane type C04B28/18; Kiln dust cements
• CPC Class Codes: C04B 38/02 by adding chemical blowing agents
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C04B 40/0281 Hardening in an atmosphere of increased relative humidity
• CPC Class Codes: C04B 40/0286 Hardening under water
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10S 106/01 Fly ash

Abstract

Mortar mixes comprising as a major part, Class F fly ash and fluidized bed combustion ash in amounts and proportions sufficient to reduce the negative effects of the presence of unburned carbon in the Class F fly ash and the presence of sulfate in the fluidized bed combustion ash and which mortar mixes also include, as a minor part, a cementitious material. The mortar produced by mixing the mortar mix with water can include a density reduction material and can be formed into support members for use in mines.

Claims

1. A mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material.

2. The mortar mix as set forth in claim 1, wherein the Class F fly ash-to-FBC ash weight ratio is at least about 2:

1.

3. The mortar mix as set forth in claim 2, comprising about 50% to about 85% by weight Class F fly-ash and about 1% to about 20% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

4. The mortar mix as set forth in claim 3, comprising about 50% to about 75% by weight class F fly-ash and about 5% to about 15% by weight FBC ash;

and about 20% to about 30% by weight cementitious material.

5. The mortar mix as set forth in claim 4, further comprising about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof.

6. The mortar mix as set forth in claim 5, wherein a blended cement replaces a portion of the cementitious material in an amount of about 1% to about 3% by weight of the mortar mix.

21. The mortar mix as set forth in claim 1, wherein the Class F fly ash-to-FBC ash weight ratio is not over about 1:

2.

22. The mortar mix as set forth in claim 21, comprising about 10% to about 25% by weight Class F fly-ash and about 50% to about 85% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

23. The mortar mix as set forth in claim 22, comprising about 10% to about 25% by weight class F fly-ash and about 60% to about 80% by weight FBC ash;

and about 10% to about 20% by weight cementitious material.

24. The mortar mix as set forth in claim 23, further comprising about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof.

25. The mortar mix as set forth in claim 24, wherein a blended cement replaces a portion of the cementitious material in an amount of about 1% to about 5% by weight of the mortar mix.

7. A mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material.

8. A mortar as set forth in claim 7 wherein the weight ratio of the Class F fly ash to the FBC ash is at least about 2:

1.

9. The mortar as set forth in claim 8, further comprising about 0.5-1.5% by volume fibers.

10. The mortar as set forth in claim 9, further comprising a density reducer in an amount sufficient to provide a cured mortar having a density of from about 50 to about 100 pounds per cubic foot.

11. The mortar as set forth in claim 10, wherein the Class F fly-ash and the FBC fly-ash are products of the combustion of coal.

12. The mortar as set forth in claim 11, wherein the Class F fly-ash contains less than 10% calcium oxide and has a loss on ignition of less that 10%.

13. The mortar as set forth in claim 12, wherein the FBC fly-ash comprises calcium oxide in an amount of from about 8% to about 30% by weight.

14. The mortar as set forth in claim 9, wherein the fibers are selected from the group consisting of synthetic fibers and natural fibers.

15. The mortar as set forth in claim 14, wherein the fibers are synthetic fibers and are selected from the group consisting of fibers of carbon, metal, polymer, and any blend thereof.

16. The mortar as set forth in claim 15, wherein the fibers are polymer fibers and are selected from the group consisting of fibers of nylon, polypropylene and polyester.

17. The mortar as set forth in claim 16, wherein the fibers are waste polyester carpet fibers having a longitudinally twisted aspect.

18. The mortar as set forth in claim 10, wherein the density reducer comprises an air entrainment material.

19. The mortar as set forth in claim 10, wherein the density reducer comprises a micro-bubble foam material.

20. The mortar as set forth in claim 11, wherein the FBC fly-ash is preconditioned FBC fly-ash.

26. A mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material, wherein the weight ratio of the Class F fly ash to the FBC ash is at most about 1:

2.

27. A mortar as set forth in claim 26 wherein the mortar mix comprises about 10% to about 25% by weight Class F fly ash, about 50% to about 85% by weight FBC ash and about 5% to about 30% by weight cementitious material.

28. The mortar mix as set forth in claim 27, further comprising about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof.

29. The mortar as set forth in claim 28, further comprising a density reducer in an amount sufficient to provide a cured mortar having a density of from about 20 to about 50 pounds per cubic foot.

30. The mortar as set forth in claim 29, wherein the Class F fly ash contains less than 10% calcium oxide and has a loss on ignition of less that 10%.

31. The mortar as set forth in claim 30, wherein the FBC fly ash contains calcium oxide in an amount of from about 8% to about 30% by weight.

32. The mortar as set forth in claim 28, wherein the fibers are selected from the group consisting of synthetic fibers and natural fibers.

33. The mortar as set forth in claim 32, wherein the fibers are natural fibers and are selected from the group consisting of animal fibers and plant fibers.

34. The mortar as set forth in claim 33, wherein the fibers are synthetic fibers and are selected from the group consisting of fibers of carbon, metal, polymer, and any blend thereof.

35. The mortar as set forth in claim 34, wherein the fibers are polymer fibers and are selected from the group consisting of fibers of nylon, polypropylene and polyester.

36. The mortar as set forth in claim 35, wherein the fibers are waste polyester carpet fibers having a longitudinally twisted aspect.

37. The mortar as set forth in claim 29, wherein the density reducer comprises an air entrainment material.

38. The mortar as set forth in claim 29, wherein the density reducer comprises a micro-bubble foam material.

39. The mortar as set forth in claim 31, wherein the FBC fly-ash is preconditioned FBC fly-ash.

40. The mortar as set forth in claim 29, wherein the cementitious material is portland cement.

41. The mortar as set forth in claim 29, wherein the cementitious material is cement kiln dust.

42. A structural composition comprising a cured product of a mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material.

43. A structural composition as set forth in claim 42 wherein the weight ratio of the Class F fly ash to the FBC ash is at least about 2:

1.

44. A structural composition as set forth in claim 43, wherein the mortar mix further comprises about 0.5-1.5% by volume fibers selected from the group consisting of nylon, polypropylene and polyester fibers.

45. The structural composition as set forth in claim 43, and having a density of about 50 pcf to about 100 pcf.

46. The structural composition as set forth in claim 45, and having a compressive strength of at least about 3000 psi.

47. A structural composition comprising a cured product of a mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material, wherein the weight ratio of the Class F fly ash to the FBC ash is at most about 1:

2 and the mortar mix comprises about 10% to about 25% by weight Class F fly ash, about 50% to about 85% by weight FBC ash, about 5% to about 30% by weight cementitious material, about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof, and a density reducer in an amount sufficient to provide a cured mortar having a density of from about 20 to about 50 pounds per cubic foot, and wherein the Class F fly ash contains calcium oxide in an amount of from about 8% to about 30% by weight.

48. A structural composition comprising a cured product of a mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material, wherein the weight ratio of the Class F fly ash to the FBC ash is at most about 1:

2.

49. A structural composition comprising a cured product of a mortar comprising about 22 parts to about 35 parts by weight water per 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material, wherein the weight ratio of the Class F fly ash to the FBC ash is at most about 1:

2 and the mortar mix comprises about 10% to about 25% by weight Class F fly ash, about 50% to about 85% by weight FBC ash, and about 5% to about 30% by weight cementitious material.

50. The structural composition as set forth in claim 49, and having a density of about 20 pcf to about 50 pcf.

51. The structural composition as set forth in claim 50, and having a compressive strength of at least 2000 psi.

52. A method for preparing a mortar mix comprising mixing together into a mortar mix about 50% to about 85% by weight Class F fly-ash and about 1% to about 20% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

53. A method for preparing a mortar mix comprising mixing together into a mortar mix about 10% to about 25% by weight Class F fly-ash and about 50% to about 85% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

54. A method for preparing a mortar comprising mixing together about 22 parts to about 35 parts by weight water per 100 parts of a mortar mix that includes about 50% to about 85% by weight Class F fly-ash and about 1% to about 20% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

55. The method as set forth in claim 54, wherein the mortar mix further comprises about 0.5% to about 1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof.

56. The method as set forth in claim 55, wherein the mortar mix further comprises a density reducer in an amount sufficient to provide a cured mortar having a density of from about 50 to about 100 pounds per cubic foot.

57. A method for preparing a mortar comprising mixing together about 22 parts to about 35 parts by weight water per 100 parts of a mortar mix that includes about 10% to about 25% by weight Class F fly-ash and about 50% to about 85% by weight fluidized bed combustion (FBC) ash;

and about 5% to about 30% by weight cementitious material.

58. The method as set forth in claim 57, wherein the mortar mix further comprises about 0.5% to about 1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof.

59. The method as set forth in claim 58, wherein the mortar mix further comprises a density reducer in an amount sufficient to provide a cured mortar having a density of from about 20 to about 50 pounds per cubic foot.

60. A method for making a coal combustion by-product-based structural member comprising the steps of:

a. preparing a mortar by mixing about 22 parts to about 35 parts by weight water with 100 parts by weight of a mortar mix comprising synergistic amounts of Class F fly ash and fluidized bed combustion (FBC) ash, and a cementitious material;

b. molding the mortar into a shape; and

c. curing the molded mortar into a structural member.

61. The method as set forth in claim 60, wherein the molding step includes bubble removal from the mortar prior to curing.

62. The method as set forth in claim 61, wherein the mortar is molded by placing the mortar in a mold and the curing includes exposing the molded mortar to high relative humidity followed by immersion of the molded mortar in water having a temperature of from about 140°

F. to about 170°

F.

63. The method as set forth in claim 62, wherein the molded mortar is exposed to the high relative humidity for about 8 to about 24 hours, the molded mortar is immersed in the water for an additional 24-48 hours, and the immersion step is followed by cooling of the molded mortar to ambient temperature over a period of about 10 to about 30 hours.

64. The method as set forth in claim 63, wherein the temperature during exposure to high relative humidity is maintained at 90°

F. to about 120°

F.

65. The method as set forth in claim 64, wherein the curing includes exposing the molded mortar to high relative humidity followed by exposure of the molded mortar to ambient pressure steam.

66. The method as set forth in claim 65, wherein the molded structural member is exposed to the high relative humidity for about 8 to about 24 hours and then exposed to ambient pressure steam for about an additional 24 to about 48 hours, followed by cooling to ambient temperature over a period of about 20 to about 30 hours.

67. The method as set forth in claim 66, wherein the temperature during exposure to high relative humidity is maintained at 90°

F. to about 120°

F.

68. The method as set forth in claim 63, wherein all curing is carried out without removing the molded mortar from the mold.

69. The method as set forth in claim 66, wherein all curing is carried out without removing the molded mortar from the mold.

70. The method as set forth in claim 62 wherein the molded mortar is removed from the mold after exposure to the high relative humidity and prior to immersion in the water.

71. The method as set forth in claim 63 wherein the molded mortar is removed from the mold after exposure to the high relative humidity and prior to immersion in the water and the exposure of the molded mortar to the high relative humidity takes place at ambient temperature.

72. A support member for use in mining comprising a cured product of about 50% to about 85% by weight Class F fly-ash;

about 1% to about 20% by weight fluidized bed combustion (FBC) ash;

about 5% to about 30% by weight cementitious material;

about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof;

about 22 parts to about 35 parts by weight water per 100 parts combined weight of the Class F fly-ash, the FBC ash, the cementitious material and the fibers; and

a density reducer;

the cured product having a density of from about 50 to about 100 pounds per cubic foot.

73. The support member as set forth in claim 72, having a compressive load carrying strength per unit weight that is at least equal to that of wood.

74. The support member as set forth in claim 73, wherein the support member is free of a mold.

75. The support member as set forth in claim 73, wherein the support member is provided with a disposable mold.

76. The support member as set forth in claim 75, wherein the disposable mold is sheet metal.

77. The support member as set forth in claim 75, wherein the disposable mold is plastic pipe.

78. The support member as set forth in claim 77, wherein the disposable mold is PVC pipe in an annular configuration.

79. A support member for use in mining comprising a cured product of about 10% to about 20% by weight Class F fly-ash;

about 50% to about 85% by weight fluidized bed combustion (FBC) ash;

about 5% to about 30% by weight cementitious material;

about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof;

about 30 parts to about 45 parts by weight water per 100 parts combined weight of the Class F fly-ash, the FBC ash, the cementitious material and the fibers; and

a density reducer;

the cured product having a density of from about 20 to about 50 pounds per cubic foot.

80. A method of supporting a mine ceiling, the mine also having a floor, comprising installing between the ceiling and the floor of the mine a support member comprising a cured product of about 50% to about 85% by weight Class F fly-ash;

about 1% to about 20% by weight fluidized bed combustion (FBC) ash;

about 5% to about 30% by weight cementitious material;

about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof;

about 22 parts to about 35 parts by weight water per 100 parts combined weight of the Class F fly-ash, the FBC ash, the cementitious material and the fibers; and

a density reducer;

the cured product having a density of from about 50 to about 100 pounds per cubic foot.

81. A method of supporting a mine ceiling, the mine also having a floor, comprising installing between the ceiling and the floor of the mine a support member comprising a cured product of about 10% to about 20% by weight Class F fly-ash;

about 50% to about 85% by weight fluidized bed combustion (FBC) ash;

about 5% to about 30% by weight cementitious material;

about 0.5-1.5% by volume fibers selected from the group consisting of cellulose, wool, cotton, hair, hemp, ramie, metal, carbon, boron, and polymeric fibers, and blends thereof;

about 30 parts to about 45 parts by weight water per 100 parts combined weight of the Class F fly-ash, the FBC ash, the cementitious material and the fibers; and

a density reducer;

the cured product having a density of from about 20 to about 50 pounds per cubic foot.