Ferrofluid composition and process

• US 6,277,298 B1
• Filed: 10/28/1999
• Issued: 08/21/2001
• Est. Priority Date: 10/28/1999
• Status: Expired due to Term

• Current Assignee: Ferrotec Corporation (Ferrotec Holdings Corporation)
• Original Assignee: Ferrotec Corporation (Ferrotec Holdings Corporation)
• Inventors: Tsuda, Shiro, Hirota, Yasutake, Borduz, Lucian
• Primary Examiner(s): Koslow, C. Melissa
• Application Number:
  US09/429,189
• Time in Patent Office: 663 Days
• Field of Search: 252/62.52, 252/62.54, 252/62.51 R
• US Class Current: 252/62.52
• CPC Class Codes: H01F 1/44 of magnetic liquids, e.g. ferrofluids particles in a bonding agent H01F1/28, H01F1/36, H01F1/37

Abstract

The invention relates to a composition and process for producing a chemically stable magnetic fluid comprising a plurality of magnetic particles covered first with a small molecular weight surface modifier, which is a nondispersant and acts as a surfactant-accepting layer, and then with at least one surfactant. The surface modifier/surfactant coated magnetic particles are then suspended in a silicone oil-based, hydrocarbon oil-based or an ester oil-based carrier liquid.

Claims

1. An improved ferrofluid composition comprising:

a plurality of magnetic particles;

a silane-based surface modifier adsorbed on said plurality of magnetic particles as a surfactant-accepting layer, said surface modifier having a small enough molecular weight sufficient to be a nondispersant and having little or no individuality compared to the individuality of a surfactant;

at least one surfactant coating over said silane-based surface modifier in the outer layers of said plurality of magnetic particles; and

a carrier liquid.

2. The composition of claim 1 wherein said silane-based surface modifier has a functional group of one to eight carbon atoms.

3. The composition of claim 2 wherein said silane-based surface modifier has a functional group of one to six carbon atoms.

4. The composition of claim 3 wherein said silane-based surface modifier has a functional group of one to four carbon atoms.

5. The composition of claim 1 wherein said silane-based surface modifier is represented by the formula

wherein R¹ denotes one to three similar functional groups where each group is an alkyl radical having one to eight carbon atoms, R² denotes a hydrolyzable radical of one to three atoms, and n is 1, 2 or 3.

6. The composition of claim 5 wherein said hydrolyzable radical is chosen from the group consisting of alkoxides of one to three carbon atoms.

7. The composition of claim 5 wherein said hydrolyzable radical is chloride.

8. The composition of claim 1 wherein said silane-based surface modifier is selected from the group consisting of isobutyltrimethoxysilane, isobutyltriethoxysilane, dimethyidimethoxysilane, dimethydiethoxysilane, trimethylmethoxysilane, n-propyltrimethoxysilane, n-butyltrimethoxysilane, and isobutyltrichlorosilane.

9. The composition of claim 1 wherein said surfactant is chosen from the class of surfactants consisting of cationic surfactants, anionic surfactants and nonionic surfactants and has a molecular weight of at least 150.

10. The composition of claim 1 wherein said carrier fluid is an organic molecule compatible with at least one surfactant.

11. The composition of claim 10 wherein said carrier fluid is one of a silicone-based carrier fluid, a hydrocarbon-based carrier fluid and an ester-based carrier fluid.

12. The composition of claim 1 wherein said carrier fluid is a silicone oil-based carrier fluid, a hydrocarbon oil-based carrier fluid or an ester oil-based carrier fluid.

13. The composition of claim 1 wherein said silane-based surface modifier is an alkyl alkoxy silane surface modifier or an alkyl chloro silane surface modifier.

14. The composition of claim 1 further comprising an antioxidant in said improved ferrofluid composition.

19. The composition of claim 1 wherein said silane-based surface modifier is represented by the formula

wherein R¹ denotes one to three similar functional groups where each group is an alkyl radical having one to eight carbon atoms, R² denotes a hydrolyzable radical of one to three atoms, and n is 1, 2 or 3.

20. The magnetic fluid of claim 19 wherein said hydrolyzable radical is chosen from the group consiting of alkoxides of one to three carbon atoms.

21. The magnetic fluid of claim 19 wherein said hydrolyzable radical is chloride.

15. A magnetic fluid obtained by the process comprising:

adsorbing a silane-based surface modifier onto a plurality of magnetic particles as a surfactant-accepting layer, said surface modifier having a sufficiently small molecular weight to be a nondispersant and having little or no individuality compared to the individuality of a surfactant;

coating at least one surfactant over said silane-based surface modifier in the outer layers of said plurality of magnetic particles; and

suspending said plurality of magnetic particles into a carrier liquid.

16. The magnetic fluid of claim 15 wherein said silane-based surface modifier has a functional group of one to eight carbon atoms.

17. The magnetic fluid of claim 16 wherein said silane-based surface modifier has a functional group of one to six carbon atoms.

18. The magnetic fluid of claim 17 wherein said silane-based surface modifier group of one to four carbon atoms.

22. The magnetic fluid of claim 15 wherein said silane-based surface modifier is selected from the group consisting of isobutyltrimethoxysilane, isobutyltriethoxysilane, dimethyidimethoxysilane, dimethydiethoxysilane, trimethylmethoxysilane, n-propyltrimethoxysilane, n-butyltrimethoxysilane, and isobutyltrichlorosilane.

23. The magnetic fluid of claim 15 wherein said surfactant is selected from the group of surfactants consisting of cationic surfactants, anionic surfactants and nonionic surfactants and wherein said surfactant has a molecular weight of at least 150.

24. The magnetic fluid of claim 15 wherein said carrier fluid is an organic molecule compatible with at least one surfactant.

25. The magnetic fluid of claim 24 wherein said carrier fluid is a silicone oil-based carrier fluid, a hydrocarbon oil-based carrier fluid or an ester oil-based carrier fluid.

26. The magnetic fluid of claim 15 awherein said silane-based surface modifier is an alkyl alkoxy silane surface modifier or an alkyl chloro silane surface modifier.

27. The magnetic fluid of claim 15 further comprising adding an antioxidant to said magnetic fluid.

37. The method of claim 26 wherein said oil-based carrier liquid suspending step further includes adding a predetermined amount of said carrier liquid to said plurality of surfactant-coated magnetic particles and removing said second solvent.

38. The method of claim 37 further comprising adding a sufficient amount of said carrier liquid after removal of said second solvent to obtain a magnetic fluid having a predetermined saturation magnetization.

39. The method of claim 25 wherein said surfactant-coating step further includes adding said at least one surfactant to a second solvent forming a surfactant mixture and heating said surfactant mixture to a temperature above ambient temperature and below the boiling point of said second solvent.

40. The method of claim 39 further comprising combining said surfactant mixture with said plurality of magnetic particles having said surface modifier adsorbed thereon forming a combined mixture and stirring said combined mixture for a predetermined time.

41. The method of claim 40 further comprising placing said combined mixture over a magnet for a predetermined time.

42. The method of claim 41 further comprising removing a top liquid portion of said combined mixture, adding a predetermined amount of said carrier liquid and said surfactant to said top liquid portion and then removing said second solvent.

43. The method of claim 42 further comprising adding a sufficient amount of said carrier liquid after removal of said second solvent to obtain a magnetic fluid having a predetermined saturation magnetization.

28. A method of making an improved ferrofluid composition, said method comprising:

obtaining a plurality of magnetic particles suspended in a first solvent;

adsorbing a small molecular weight silane-based surface modifier on said plurality of magnetic particles, said surface modifier having a small enough molecular weight sufficient to be a nondispersant and having little or no individuality compared to the individuality of a surfactant;

coating said plurality of said surface-modifier adsorbed particles with at least one surfactant; and

suspending said plurality of coated magnetic particles in an oil-based carrier liquid.

29. The method of claim 28 wherein said step of obtaining said plurality of magnetic particles further includes heating said plurality of magnetic particles to a temperature above ambient temperature and below the boiling point of said first solvent.

30. The method of claim 29 wherein said heating is at a temperature of about 50°

C to about 60°

C.

31. The method of claim 28 wherein said surface modifier absorbing step further includes adding said surface modifier to said plurality of magnetic particles in said first solvent.

32. The method of claim 31 further comprising stirring said solvent at sufficiently high speed to precipitate said plurality of magnetic particles.

33. The method of claim 32 further comprising separating said first solvent from said plurality of magnetic particles and suspending said plurality of magnetic particles in a first portion of a second solvent.

34. The method of claim 33 further comprising heating said plurality of magnetic particles suspended in said first portion of said second solvent to a temperature above ambient and be low the boiling point of said second solvent.

35. The method of claim 28 wherein said surfactant-coating '"'"'step further includes adding said at least one surfactant to a second portion of said second solvent forming a surfactant mixture and heating said surfactant mixture to a temperature above ambient temperature and below the boiling point of said second solvent.

36. The method of claim 35 further comprising combining said surfactant mixture with said plurality of magnetic particles having said surface modifier adsorbed thereon.

44. The method of claim 28 further comprising adding an antioxidant to said improved ferrofluid composition.