Optical cable with filling material comprising an internal olefin oligomer

• US 6,278,824 B1
• Filed: 05/25/1999
• Issued: 08/21/2001
• Est. Priority Date: 06/05/1998
• Status: Expired due to Term

• Current Assignee: Prysmian CAVI E Sistemi Energia SRL (Prysmian SPA)
• Original Assignee: Pirelli Cavi e Sistemi S.P.A. (Prysmian SPA)
• Inventors: Locatelli, Emilio, Bosisio, Claudio
• Primary Examiner(s): Ullah, Akm E.
• Application Number:
  US09/317,642
• Time in Patent Office: 819 Days
• Field of Search: 385/100-110, 385/147, 174/107, 174/120.R, 585/18, 585/10
• US Class Current: 385/100
• CPC Class Codes: G02B 6/4433 Double reinforcement laying in straight line with optical transmission element
• CPC Class Codes: G02B 6/44384 the means comprising water blocking or hydrophobic materials G02B6/4439, G02B6/4479 take precedence

Abstract

The present invention relates to an optical fiber cable comprising a filling material and to the composition of said filling material. In particular, the filling composition according to the present invention comprises an internal polyolefin oligomer to provide an improved capacity for wetting the coating surfaces of the optical fibers which it comes into contact with, and provides better slip of the optical fibers embedded in the composition. The oligomers of the invention comprise internal polyolefins obtained by polymerizing two or more hydrocarbon monomeric units having at least one unsaturation distributed randomly along the whole hydrocarbon chain wherein a mixture of these monomeric units comprises a maximum of 10% of monomeric units having the double bond in the α-position.

Claims

1. An optical cable comprising at least one optical fiber and a filling material wherein said filling material comprises an internal polyolefin oligomer based on an internal olefin monomer comprising the product of polymerization of two or more hydrocarbon monomeric units, where said monomeric units comprise a hydrocarbon chain having at least one unsaturation distributed randomly along the whole of said hydrocarbon chain, and said two or more monomeric units comprise a maximum of 10% of monomeric units having a double bond in an α

-position.

2. Cable according to claim 1, characterized in that the filling composition comprises from 30% to 98% by weight of internal polyolefin.

3. Cable according to claim 1, wherein the filling composition comprises from approximately 45% to approximately 95% by weight of internal polyolefin.

4. Cable according to claim 1, characterized in that the filler is in contact with the said at least one optical fibre.

5. Cable according to claim 1, characterized in that the said internal polyolefin is produced by the polymerization of unsaturated hydrocarbon monomeric units, each containing from 10 to 20 carbon atoms.

6. Cable according to claim 5, wherein each of the said monomeric units contains from 12 to 18 carbon atoms.

7. Cable according to claim 5, wherein each of the said monomeric units contains from 15 to 16 carbon atoms.

8. Cable according to claim 5, wherein said internal polyolefin is an oligomer comprising from 2 to 4 unsaturated hydrocarbon monomeric units.

9. Optical cable according to claim 1 or 5, wherein said internal polyolefin is a mixture of polyolefins having different molecular weights.

10. Cable according to claim 9, characterized in that the said mixture of internal polyolefins is a mixture of oligomers, each comprising from 2 to 4 unsaturated hydrocarbon monomeric units.

11. Cable according to claim 1 or 2, characterized in that the said filler comprises a polymeric thickener.

12. Cable according to claim 11, characterized in that the said thickener is a block copolymer of the type which comprises styrene, propylene and ethylene units.

13. Cable according to claim 1 or 2, characterized in that the said filling mixture also comprises a mineral oil.

14. Cable according to claim 13, characterized in that the said mineral oil is a refined naphthenic oil.

15. Cable according to claim 14, characterized in that the said naphthenic oil has a viscosity in the range from 4 to 60 mPa.s, a viscosity in the range from 1.5 to 7 mPa.s at 100°

C., and a pour point in the range from −

60°

C. to −

25°

C.

16. Optical cable according to claim 13, wherein said mineral oil in the filling mixture replaces the quantity of internal polyolefin for a percentage by weight which varies from 0% to 70%.

17. A composition for filling material for optical cables, comprising an internal polyolefin oligomer based on an internal olefin monomer comprising the product of polymerization of two or more hydrocarbon monomeric units, where said monomeric units comprise a hydrocarbon chain having at least one unsaturation distributed randomly along the whole of said hydrocarbon chain, and said two or more monomeric units comprises a maximum of 10% of monomeric units having a double bond in an α

-position, said oligomer being combined with a polymeric thickener.

18. The composition of claim 17 wherein said thickener comprises a copolymer of styrene, propylene and ethylene.

19. The composition of claim 17 wherein said composition contains a mineral oil.

20. The composition of claim 18 wherein said composition contains a mineral oil.

21. The composition of any one of claims 17-20 and an antioxidant.