Downhole chemical delivery system for oil and gas wells

• US 6,279,656 B1
• Filed: 11/03/1999
• Issued: 08/28/2001
• Est. Priority Date: 11/03/1999
• Status: Expired due to Fees

• Current Assignee: Santrol, Inc. (Covia Holdings LLC), ASMO Company Limited (DENSO Corporation)
• Original Assignee: Santrol, Inc. (Covia Holdings LLC)
• Inventors: Smith, S. Byron, Sinclair, A. Richard
• Primary Examiner(s): Neuder, William
• Assistant Examiner(s): BATES, ZAKIYA W
• Application Number:
  US09/433,178
• Time in Patent Office: 664 Days
• Field of Search: 166/304, 166/309, 166/310, 166/311, 166/312, 166/296, 166/371, 166/376, 166/205, 166/227, 166/902, 507/903, 507/939
• US Class Current: 166/310
• CPC Class Codes: C09K 8/516 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/92 characterised by their form or by the form of their components, e.g. encapsulated material C09K8/70 takes precedence
• CPC Class Codes: Y10S 166/902 for inhibiting corrosion or coating
• CPC Class Codes: Y10S 507/903 Crosslinked resin or polymer
• CPC Class Codes: Y10S 507/939 Corrosion inhibitor

Abstract

The invention is the method of treating of a well, a formation, or both, with the solids, liquids, or apparatuses, by 1) encasing the solids, liquids, or apparatuses in a water-soluble shell, 2) conveying the encased solids, liquids, or gases to the predetermined location in the well, and then 3) allowing the water-soluble shell to dissolve in the aqueous phase in the wellbore. The shell is preferably made of water-soluble polymers such as collagen, a crosslinking agent such as zolidine, optionally a hydrophobic compound such as a processed oil, and water used in processing. Other modifying or conditioning compounds, for example glycerin and other polymeric additives, may be incorporated to extend the strength or temperature range of the shell. The shell encases a variety of solids, liquids, or combinations thereof, where the solids or liquids are useful in the treatment of the well or of the producing formation. Illustrative encased material includes soap, acid, corrosion inhibitors, chelating agents, scale inhibitors, mutual solvents, paraffin inhibitors, paraffin dissolvers, clay stabilizers, and tracer materials. The encased materials may also be apparatuses, such as a prefabricated screen completion or a prefabricated sand-pack.

Claims

1. An apparatus for treating wells comprising:

a) a material useful for treating wells; and

b) a water-soluble shell substantially encasing the material, said shell comprising a water-soluble polymer and a cross-linking agent, wherein at least a portion of the water-soluble polymer is cross-linked with the proviso that the cross-linking agent is not a chromic carboxylate complex.

2. The apparatus of claim 1 wherein the water-soluble shell dissolves in the water in the well in a period of time ranging from about 1 hour to about 2 weeks.

3. The apparatus of claim 1 wherein the water-soluble polymer comprises collagen.

4. The apparatus of claim 1 wherein the water-soluble polymer comprises polysaccharide gum.

5. The apparatus of claim 1 wherein the water-soluble polymer comprises hydroxyethyl starch, hydroxypropyl starch, or a mixture thereof.

6. The apparatus of claim 1 wherein the water-soluble polymer comprises methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxyethylmethyl cellulose, hydroxypropylmethyl cellulose, hydroxybutylmethyl cellulose, ethylhydroxyethyl cellulose, hydroxypropyl-hydroxyethyl cellulose, sodium cellulose sulfate, sodium carboxymethyl hydroxyethyl cellulose, diethylammoniumchloride hydroxyethyl cellulose, hydroxypropyl trimethyl ammonium chloride hydroxyethyl cellulose, diethyl aminoethyl cellulose, or a mixture thereof.

7. The apparatus of claim 1 wherein the water-soluble polymer comprises gum arabic, carrageenan gum, karaya gum, xanthan gum, carboxymethyl hydroxypropyl guar, cationic guar, or a mixture thereof.

8. The apparatus of claim 1 wherein the water-soluble polymer comprises from about 10 to about 50 percent by weight of the water-soluble shell.

9. The apparatus of claim 1 wherein the cross-linking agent comprises oxazole, an oxazolidine, or a mixture thereof.

10. The apparatus of claim 1 wherein the cross-linking agent comprises zoldine.

11. The apparatus of claim 1 wherein the cross-linking agent comprises hexamethoxy-methylmelamine, methylated melamines, partially methylated melamine-formaldehyde, methylated urea-formaldehyde, butylated urea-formaldehydes, poly (vinyl amines), cationic urea-formaldehyde resins, or mixtures thereof.

12. The apparatus of claim 1 wherein the cross-linking agent comprises glutaraldehyde, glyoxal-urea resins, dimethylaminomethyl phenols, cationic polyamide-epichlorohydrins, oxazolidines, or mixtures thereof.

13. The apparatus of claim 1 wherein the cross-linking agent comprises poly (N,N-dimethylacrylamide), poly (2-acrylamido-2-methyl propane sulfonic acid), poly (methylene-guanidine) hydrochloride, poly (N,N-dimethyl-3,5 dimethylene piperidinium chloride), acrylamide polymers, poly (ethylene imine), poly (ethylene imine) epichlorohydrin, or a mixture thereof.

14. The apparatus of claim 1 wherein the water-soluble shell further comprises a modifying compound.

15. The apparatus of claim 14 wherein the modifying compound is oil.

16. The apparatus of claim 14 wherein the modifying compound is glycerin.

17. The apparatus of claim 14 wherein the modifying compound is a polymeric additive.

18. The apparatus of claim 1 wherein the material useful for treating wells comprises soap, acid, corrosion inhibitors, chelating agents, scale inhibitors, mutual solvents, paraffin inhibitors, paraffin dissolvers, clay stabilizers, tracer materials, or mixtures thereof.

19. The apparatus of claim 1 wherein the material useful for treating wells comprises soap.

20. The apparatus of claim 1 wherein the material useful for treating wells comprises corrosion inhibitors.

21. The apparatus of claim 1 wherein the material useful for treating wells comprises a prefabricated mechanical device.

22. The apparatus of claim 21 wherein the prefabricated mechanical device is a prefabricated screen completion.

23. The apparatus of claim 21 wherein the prefabricated mechanical device is a prefabricated sand-pack, wherein said sand-pack includes resin coated screens, resin coated proppant, or both.

24. The apparatus of claim 23 wherein the prefabricated sand-pack is built around the outside of an encased pipe, wherein said pipe has a connector to attached near the upward end, and wherein said pipe has a dissolvable shell between the pipe and the sand-pack.

25. The apparatus of claim 1 wherein the shell is between about 1 to about 25 millimeters in thickness.

26. The apparatus of claim 1 wherein the shell comprises multiple layers encasing the material.

27. The apparatus of claim 1 further comprising a wax layer between the material and the shell.

28. The apparatus of claim 1 further comprising a wax layer, wherein said wax layer substantially encases the shell, and wherein said wax layer will melt at the temperature below that temperature of the well at which the encased material is intended to be released.

29. The apparatus of claim 1 wherein the material is a scale inhibitor.

30. The apparatus of claim 29 wherein the scale inhibitor is dispersed throughout the shell.

31. The apparatus of claim 30 wherein the scale inhibitor is encased in a plurality of cavities within the shell, wherein the cavities are less than about 0.5 inches in diameter.

32. The apparatus of claim 1 further comprising a weighing agent, wherein the quantity of the weighing agent is sufficient to give the apparatus an overall density of greater than about 1.5 grams per cubic centimeter.

33. The apparatus of claim 1 further comprising a weighing agent, wherein the quantity of the weighing agent is sufficient to give the apparatus an overall density of greater than about 2 grams per cubic centimeter.

34. The apparatus of claim 1, wherein the material useful for treating wells comprises soap, corrosion inhibitor, or a mixture thereof, wherein the water-soluble polymer comprises collagen, wherein the cross-linking agent comprises zoldine, glutaraldehyde, or a mixture thereof, and wherein the water-soluble shell further comprises glycerin and oil.

35. A method of treating a well comprising:

a) substantially encasing a material useful for treating wells in a water soluble shell, wherein said shell comprises a water-soluble polymer and a cross-linking agent, and wherein at least a portion of the water-soluble polymer is cross-linked with the proviso that the cross-linking agent is not a chromic carboxylate complex;

b) inserting the substantially encased material into the well;

c) transporting said encased material to the desired depth in the well; and

d) leaving the material at the desired depth for a time sufficient for the water-soluble shell to dissolve, thereby exposing the material to fluids in the well.

36. The method of claim 35 wherein said shell further comprises oil, glycerin, or mixtures thereof.

37. The method of claim 35 wherein said time sufficient for the water-soluble shell to dissolve ranges from about 1 hour to about 2 weeks.

38. An apparatus for treating wells comprising:

a) a material useful for treating wells; and

b) a water-soluble shell substantially encasing the material, said shell comprising a water-soluble polymer containing collagen, and a cross-linking agent, wherein at least a portion of the water-soluble polymer is cross-linked.

39. A method of treating a well comprising:

a) substantially encasing a material useful for treating wells in a water soluble shell, wherein said shell comprises a water-soluble polymer containing collagen, and a cross-linking agent, and wherein at least a portion of the water-soluble polymer is cross-linked;

b) inserting the substantially encased material into the well;

c) transporting said encased material to the desired depth in the well; and

d) leaving the material at the desired depth for a time sufficient for the water-soluble shell to dissolve, thereby exposing the material to fluids in the well.