Membrane separator assembly and method of cleaning the assembly utilizing gas diffuser underneath the assembly

• US 6,280,626 B1
• Filed: 08/11/1999
• Issued: 08/28/2001
• Est. Priority Date: 08/12/1998
• Status: Expired due to Term

• Current Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Mitshubishi Rayon Engineering Company Limited, Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Inventors: Inoue, Noriko, Itakura, Masanori, Takashima, Takamitsu, Okazaki, Hiroyuki, Watari, Kenji, Kinoshita, Ikuo, Miyashita, Satoshi, Honjyo, Kenji, Kato, Osami
• Primary Examiner(s): Drodge, Joseph W.
• Application Number:
  US09/372,179
• Time in Patent Office: 748 Days
• Field of Search: 423/415.2, 423/417, 210/321.69, 210/321.78, 210/321.79, 210/321.8, 210/321.88, 210/321.89, 210/323.2, 210/332, 210/333.01, 210/500.23, 210/636, 210/639, 210/650, 210/791, 210/798
• US Class Current: 210/636
• CPC Class Codes: B01D 2313/025 Specific membrane holders
• CPC Class Codes: B01D 2321/168 Use of other chemical agents
• CPC Class Codes: B01D 2321/185 Aeration
• CPC Class Codes: B01D 2321/2075 Ultrasonic treatment
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 63/026 Wafer type modules or flat-surface type modules
• CPC Class Codes: B01D 63/043 with separate tube sheets
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation
• CPC Class Codes: B01F 2101/24 Mixing of ingredients for cleaning compositions
• CPC Class Codes: B01F 23/23123 consisting of rigid porous or perforated material
• CPC Class Codes: B01F 23/231265 being tubes, tubular elements, cylindrical elements or set of tubes

Abstract

A membrane separator assembly for separating solids from water includes opposing enclosure wall structures, a membrane module unit, and a gas diffuser disposed below the membrane module unit. The membrane module unit includes a plurality of membrane modules respectively having at least one separating membrane extending between at least two membrane fixing members. At least one of the membrane fixing members has a main passage which is in fluid communication with a membrane passageway. The membrane passageway is accessible to water via permeation through the separating membranes and is inaccessible to solids which are impermeable relative to the separating membranes. The membrane separator assembly is preferably used with a detergent containing percarbonate, preferably sodium percarbonate. The assembly also includes a gas diffuser with two opposing main pipes and branch pipes extending therebetween to avoid undesired pressure differentials when cleaning the assembly.

Claims

1. A membrane separator assembly for separating solids from water comprising:

a membrane module unit comprising a plurality of membrane modules, at least some of said membrane modules each respectively comprising;

at least two membrane fixing members, at least one of said membrane fixing members having a main passageway formed therethrough; and

one or more vertically oriented separating membranes extending between said membrane fixing members, said separating membranes collectively or individually defining one or more membrane passageways in fluid communication with said main passageway, said membrane passageways being accessible to water via permeation through said separating membranes and being inaccessible to solids which are impermeable relative to said separating membranes;

a gas diffuser disposed below said membrane modules, said gas diffuser comprising two opposing identical main pipes and branch pipes, said branch pipes extending between said main pipes and containing gas discharge ports, wherein a cross sectional area A2 of said branch pipes is less than a cross sectional area A1 of said main pipes; and

an enclosure subassembly constructed and arranged to permit the passage of liquid therethrough along a vertical direction, said enclosure subassembly comprising at least two opposing enclosure walls arranged parallel to said membrane modules and positioned with said membrane module unit therebetween, said two opposing enclosure walls respectively being spaced from separating membranes of outermost ones of said membrane modules.

2. The membrane separator assembly of claim 1, wherein said membrane fixing members collectively constitute from 30 to 100% of a side surface area of said membrane module unit.

3. The membrane separator assembly of claim 1, wherein said membrane fixing members contain slits having substantially rectangular cross sections, and further wherein said separating membranes comprise fabrics fixed in said slits, said fabrics comprising hollow fibers individually defining said membrane passageways.

4. The membrane separator assembly of claim 3, wherein said hollow fibers collectively form a yarn.

5. The membrane separator assembly of claim 1, further comprising at least one connecting structure fixing said enclosure walls relative to each other.

6. The membrane separator assembly of claim 5, wherein said connecting structure is rod shaped and passes through said enclosure walls.

7. The membrane separator assembly of claim 6, wherein said connecting structure comprises a comprises a collection passageway constructed and arranged to collect filtrate from said membrane modules, and further wherein said separating membranes comprise hollow yarn.

8. The membrane separator assembly of claim 1, wherein said gas discharge ports are arranged in a lowest portion of said branch pipes.

9. The membrane separator assembly of claim 1, wherein said gas diffuser further comprises a plurality of conduit members inserted through and associated with respective ones of said gas discharge ports, said conduit members having one or more openings positioned outside of said branch pipes and one or more openings positioned inside of said branch pipes, wherein said openings positioned outside of said branch pipes have a collective cross-sectional area A_out that is less than a collective cross-sectional area A_in of said openings positioned inside of said branch pipes.

10. The membrane separator assembly of claim 1, wherein said gas diffuser further comprises covers having a plurality of through holes, said covers being disposed within said branch pipes and each positioned to cover an associated one of said gas discharge ports of said branch pipes, wherein a cross-sectional area of any one of said gas discharge ports is smaller than a collective cross-sectional area of all of said through holes of said associated one of said covers.

11. The membrane separator assembly of claim 1, wherein each of said membrane modules respectively comprise two of said vertically oriented separating membranes in spaced relation so as to collectively define one of said membrane passageways therebetween.

12. The membrane separator assembly of claim 1, wherein said enclosure walls define one or more passageways through which water is flowable.

13. The membrane separator assembly of claim 12, wherein said passageways comprise 1-60% by volume of the total surface area of at least one of said enclosure walls.

14. The membrane separator assembly of claim 12, wherein said membrane fixing members collectively constitute from 30 to 100% of a side surface area of said membrane module unit.

15. The membrane separator assembly of claim 12, wherein said membrane fixing members contain slits having substantially rectangular cross sections, and further wherein said separating membranes comprise fabrics fixed in said slits, said fabrics comprising hollow fibers individually defining said membrane passageways.

16. The membrane separator assembly of claim 15, wherein said hollow fibers collectively form a yarn.

17. The membrane separator assembly of claim 12, further comprising at least one connecting structure fixing said enclosure walls to each other.

18. The membrane separator assembly of claim 17, wherein said connecting structure is rod shaped and passes through said enclosure walls.

19. The membrane separator assembly of claim 18, further comprising connecting structure collection passageway constructed and arranged to collect filtrate from said membrane modules, and further wherein said separating membranes comprise hollow yarn.

20. The membrane separator assembly of claim 12, wherein each of said membrane modules respectively comprise two of said vertically oriented separating membranes in spaced relation so as to collectively define one of said membrane passageways therebetween.

21. A method of cleaning separating membranes, comprising the steps of providing the membrane separator assembly of claim 13 and contacting said separating membranes of said membrane separator assembly of claim 13 with a solution comprising a percarbonate-containing detergent.

22. The method of claim 21, further comprising discharging gas from said gas diffuser at 10 to 150 Nm³/m²/hr per horizontal cross-sectional area of said membrane module unit.

23. The method of claim 21, generating a vertical flow of a gas-liquid mixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

24. The method of claim 21, generating a horizontal flow of a gas-liquid ixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

25. The membrane separator assembly of claim 1, wherein said gas discharge ports are arranged in a lowest portion of said branch pipes.

26. A method of cleaning separating membranes, comprising the step of providing the membrane separator assembly of claim 1 and contacting said separating membranes of said membrane separator assembly of claim 1 with a solution comprising a percarbonate-containing detergent.

27. The method of claim 26, further comprising discharging gas from said gas diffuser at 10 to 150 Nm³/m²/hr per horizontal cross-sectional area of said membrane module unit.

28. The method of claim 26, generating a vertical flow of a gas-liquid mixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

29. The method of claim 26, generating a horizontal flow of a gas-liquid mixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

42. A method of cleaning separating membranes, comprising the steps of providing the membrane separator assembly of claim 26 and contacting said separating membranes of said membrane separator assembly of claim 30 with a solution comprising a percarbonate-containing detergent.

43. The method of claim 42, further comprising discharging gas from said gas diffuser at 10 to 150 Nm³/m²/hr per horizontal cross-sectional area of said membrane module unit.

44. The method of claim 42, generating a vertical flow of a gas-liquid mixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

45. The method of claim 42, generating a horizontal flow of a gas-liquid mixture in said membrane module unit at an average flow rate of from 0.01 to 1.5 m/sec.

30. A membrane separator assembly for separating solids from water comprising:

a plurality of membrane module units, each of which comprises a respective plurality of membrane modules, at least some of said membrane modules each respectively comprising;

at least two membrane fixing members, at least one of said membrane fixing members having a main passageway formed therethrough; and

one or more vertically oriented separating membranes extending between said membrane fixing members and in parallel relation to each other yet spaced from each other at regular intervals W, said separating membranes collectively or individually defining one or more membrane passageways in fluid communication with said main passageway, said membrane passageway being accessible to water via permeation through said separating membranes and being inaccessible to solids which are impermeable relative to said separating membranes;

a gas diffuser disposed below said membrane modules, said gas diffuser comprising two opposing identical main pipes and branch pipes, said branch pipes extending between said main pipes and containing gas discharge ports, wherein a cross sectional area A2 of said branch pipes is less than a cross sectional area A1 of said main pipes; and

an enclosure subassembly constructed and arranged to permit the passage of liquid therethrough along a vertical direction, said enclosure subassembly comprising at least two opposing enclosure walls arranged parallel to said membrane modules and positioned with said membrane module unit therebetween, said two opposing enclosure walls respectively being spaced from separating membranes of outermost ones of said membrane modules,

wherein said membrane module units each have at least one side of length A extending parallel to vertically oriented membranes,

wherein said membrane units are arranged in series so that vertically oriented membranes of adjacent ones of said membrane units are arranged parallel to one another, with opposing outermost membranes of adjacent ones of said membrane units being spaced by a clearance which is 1.2 to 5 times as large as said regular intervals W.

31. The membrane separator assembly of claim 30, further comprising one or more partition plates arranged parallel to said vertically oriented membranes, at least one of said partition plates being disposed in each said clearance.

32. The membrane separator assembly of claim 30, wherein said membrane fixing members collectively constitute from 30 to 100% of a side surface area of said membrane module unit.

33. The membrane separator assembly of claim 30, wherein said membrane fixing members contain slits having substantially rectangular cross sections, and further wherein said separating membranes comprise fabrics fixed in said slits, said fabrics comprising hollow fibers individually defining said membrane passageways.

34. The membrane separator assembly of claim 33, wherein said hollow fibers collectively form a yarn.

35. The membrane separator assembly of claim 34 wherein said connecting structure is rod shaped and passes through said enclosure walls.

36. The membrane separator assembly of claim 35, further comprising connecting structure comprises a collection passageway constructed and arranged to collect filtrate from said membrane modules, and further wherein said separating membranes comprise hollow yarn.

37. The membrane separator assembly of claim 30, further comprising at least one connecting structure fixing said enclosure walls to each other.

38. The membrane separator assembly of claim 30, wherein said gas discharge ports are arranged in a lowest portion of said branch pipes.

39. The membrane separator assembly of claim 31, wherein said gas diffuser further comprises a plurality of conduit members inserted through and associated with respective ones of said gas discharge ports, said conduit members having one or more openings positioned outside of said branch pipes and one or more openings positioned inside of said branch pipes, wherein said openings positioned outside of said branch pipes have a collective cross-sectional area A_out that is less than a collective cross-sectional area A_in of said openings positioned inside of said branch pipes.

40. The membrane separator assembly of claim 31, wherein said gas diffuser further comprises covers having a plurality of through holes, said covers being disposed within said branch pipes and each positioned to cover an associated one of said gas discharge ports of said branch pipes, wherein a cross-sectional area of any one of said gas discharge ports is smaller than a collective cross-sectional area of all of said through holes of said associated one of said covers.

41. The membrane separator assembly of claim 30, wherein each of said membrane modules respectively comprise two of said vertically oriented separating membranes in spaced relation so as to collectively define one of said membrane passageways therebetween.