Wound battery and method for making it

• US 6,280,873 B1
• Filed: 04/08/1999
• Issued: 08/28/2001
• Est. Priority Date: 04/08/1999
• Status: Expired due to Fees

• Current Assignee: Quallion, LLC (EnerSys)
• Original Assignee: Quallion, LLC (EnerSys)
• Inventors: Tsukamoto, Hisashi
• Primary Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US09/289,071
• Time in Patent Office: 873 Days
• Field of Search: 429/94, 429/210, 429/127, 429/231.95
• US Class Current: 429/94
• CPC Class Codes: H01M 10/0431 Cells with wound or folded electrodes H01M10/045 takes precedence
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 4/02 Electrodes composed of, or comprising, active material
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 4/668 Composites of electroconductive material and synthetic resins
• CPC Class Codes: H01M 50/414 Synthetic resins, e.g. thermoplastics or thermosetting resins
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A lithium battery made with a bipolar polyimide membrane with metal layers on each side, including one embodiment where the polyimide has a gold layer on each side. Different formulations for the positive electrode active material are used. The positive electrode active materials are essentially three substances: first, a lithium compound selected from the group consisting of LiCoO₂, LiNiO₂, and LiMn₂O₄; second, a powder selected from the group consisting of AB (acetylene black powder) and graphite; and third, PVDF (polyvinyldifluoride). The negative electrode active material consists essentially of two substances: the first is graphite powder; the second is PVDF (polyvinyldifluoride). The positive electrode metals include gold and aluminum. The negative electrode materials include gold, copper, nickel, titanium and iron. A separator layer of polyethylene is used so the battery layers can be wound. Because of the strength of the polyimide, the battery can be tightly wound. The energy density of the battery is about 300 Watt-hours per cubic centimeter.

Claims

1. A lithium battery comprising:

a flexible multilayer strip defining orthogonal width and length dimensions, said strip being tightly wound around an axis oriented parallel to the width of said strip, said strip including;

a flexible plastic substrate defining first and second parallel surfaces;

a positive electrode conductive layer formed on said substrate first surface continuously extending along the length of said substrate;

a negative electrode conductive layer formed on said substrate second surface continuously extending along the length of said substrate;

a positive active material layer carried by and continuously extending along the length of said positive electrode layer, said positive active material layer including a lithium metal oxide;

a negative active material layer carried by and continuously extending along the length of said negative electrode layer; and

a separator layer formed on and continuously extending along the length of at least one of said active material layers for separating said positive and negative active material layers when said strip is tightly wound.

2. The battery of claim 1 wherein said plastic substrate comprises polyimide.

3. The battery of claim 1 wherein said plastic substrate has a thickness of between 0.3 μ

m and 50 μ

m.

4. The battery of claim 1 wherein said positive electrode conductive layer is comprised of a material selected from the group consisting of gold and aluminum.

5. The battery of claim 1 wherein said positive electrode conductive layer has a thickness of between 0.3 μ

m and 3.0 μ

m.

6. The battery of claim 1 wherein said positive active material layer has a thickness of between 20 μ

m and 100 μ

m.

7. The battery of claim 1 wherein said negative electrode conductive layer is comprised of a material selected from the group consisting of gold, copper, nickel, titanium and iron.

8. The battery of claim 1 wherein said negative electrode conductive layer has a thickness of between 0.03 μ

m and 3.0 μ

m.

9. The battery of claim 1 wherein said negative active material layer has a thickness of between 20 μ

m and 100 μ

m.

10. The battery of claim 1 wherein said separator layer comprises a polyethylene sheet having a thickness of between 20 μ

m and 30 μ

m.

11. The battery of claim 1 wherein at least one of said conductive layers is sputtered onto said substrate.

12. The battery of claim 1 wherein at least one of said conductive layers is electroplated onto said substrate.

13. The battery of claim 1 wherein at least one of said conductive layers is formed on said substrate by vapor deposition.

14. The battery of claim 1 wherein said positive active material layer includes a lithium metal oxide selected from the group consisting LiCoO₂, LiNiO₂, and LiMn₂O₄.

15. The battery of claim 1 wherein said negative active material layer is comprised of graphite powder and PVDF.