Flame-retardant UV curable silicone compositions

• US 6,281,261 B1
• Filed: 11/20/2000
• Issued: 08/28/2001
• Est. Priority Date: 06/01/1998
• Status: Expired due to Fees

• Current Assignee: Henkel Loctite Corporation (Henkel AG & Co KGaA)
• Original Assignee: Loctite Corporation (Henkel AG & Co KGaA)
• Inventors: Bennington, Lester D.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): MCCLENDON, SANZA L
• Application Number:
  US09/700,778
• Time in Patent Office: 281 Days
• Field of Search: 522/18, 522/29, 522/77, 522/81, 522/83, 522/99, 524/860, 524/858, 524/430, 524/91, 524/92, 524/262, 524/398
• US Class Current: 522/99
• CPC Class Codes: C08F 283/12 on to polysiloxanes
• CPC Class Codes: C08F 290/068 Polysiloxanes
• CPC Class Codes: C08F 299/08 from polysiloxanes
• CPC Class Codes: C08K 5/0066 Flame-proofing or flame-retarding additives
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C08L 83/06 containing silicon bound to oxygen-containing groups C08L83/12 takes precedence

Abstract

The present invention is directed to silicone formulations which are capable of being rapidly cured to tough elastomeric materials through exposure to UV radiation. The cured products demonstrate high resistance to flammability and combustibility.

Claims

1. A flame-resistant silicone composition curable by UV irradiation to an elastomer comprising:

(a) a reactive silicone resin component comprising a reactive polyorganosiloxane having at least one carboxylate-containing functional group

(b) optionally, an inorganic filler component;

(c) a photoinitiator component; and

(d) a flame-retardant component in an amount effective to enhance the resistance of said composition to flammability, wherein the flame-retardant component is the combination of hydrated alumina and a member selected from the group consisting of organo ligand complexes of transition metals, organosiloxane ligand complexes of transition metals, and combinations thereof.

2. The composition according to claim 1, further comprising a triazole component.

3. The composition according to claim 1, further comprising a reactive diluent component.

4. The composition according to claim 1, wherein the reactive silicone resin is within the formula:

wherein R¹, R² and R³ may be the same or different and are organo groups selected from the group consisting of alkyl, halo alkyls, substituted or unsubstituted aryl, vinyl, methacryloxypropyl, mercaptopropyl, hydrogen and benzoin;

R⁴ is H or C_1-5 alkyl;

R⁵ is C_1-8 alkylene; and

n is at least 80.

5. The composition according to claim 1, wherein the inorganic filler component is a fumed hydrophobic silica filler.

6. The composition according to claim 5, wherein the fumed silica filler is a member selected from the group consisting of dimethyldichlorosilane-treated silica, hexamethyldisilazane-treated silica, and combinations thereof.

7. The composition according to claim 5, wherein the fumed silica filler is present at a level in range of about 4 to about 10 weight percent.

8. The composition according to claim 1, wherein the flame-retardant component is an organometallic one selected from the group consisting of organo ligand complexes of transition metals, organosiloxane ligand complexes of transition metals, and combinations thereof.

9. The composition according to claim 1, wherein the transition metals are selected from the group consisting of platinum, ruthenium, rhodium, and palladium. ligand complexes of transition metals, and combinations thereof.

10. The composition according to claim 2, wherein the triazole component is a member selected from the group consisting of benzotriazole and derivatives thereof.

11. The composition according to claim 3, wherein the reactive diluent is (meth)acrylate-terminated-dimethoxypropyldimethyl siloxane.

12. Reaction products of the composition according to claim 1.

13. A process for preparing a composition in accordance with claim 1, the steps of which comprise:

providing and mixing together (a) a reactive silicone resin component comprising a reactive polyorganosiloxane having at least one carboxylate-containing functional group;

(b) an inorganic filler component;

(c) a photoinitiator component; and

(d) a flame-retardant component in an amount effective to enhance the resistance of said composition to flammability.

14. A process for curing a composition in accordance with claim 1, the steps of which comprise:

exposing the composition to radiation in the UV region of the electromagnetic spectrum for a time sufficient to effect cure.

15. The composition according to claim 1, wherein the carbroxylate containing functional group is a member selected from the group consisting of (meth)acrylate, maleate, cinnamate and combinations thereof.

16. The composition according to claim 14, wherein the carboxylate-containing functional group selected from the group consisting of (meth)acrylate, maleate, cinnamate and combinations thereof.