Interactive electrochemical displays

• US 6,285,492 B1
• Filed: 07/01/1999
• Issued: 09/04/2001
• Est. Priority Date: 07/02/1998
• Status: Expired due to Fees

• Current Assignee: Wisconsin Label Corporation (Multi-Color Corporation)
• Original Assignee: Timer Technologies, LLC
• Inventors: Parker, Robert, Mitchell, Chauncey T. Jr., Verschuur, Gerrit L., Shadle, Mark A., Good, David M.
• Primary Examiner(s): Lester, Evelyn A
• Application Number:
  US09/340,235
• Time in Patent Office: 796 Days
• Field of Search: 429/8, 429/90, 429/92, 429/67, 429/110, 429/124, 324/425, 324/435, 324/444, 430/13, 361/500, 204/225, 204/224, 359/297
• US Class Current: 359/297
• CPC Class Codes: H01M 6/12 with flat electrodes
• CPC Class Codes: H01M 6/30 Deferred-action cells
• CPC Class Codes: H01M 6/38 by mechanical means
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries

Abstract

Electrochemical displays have electronic or ionic pathways between electrodes interrupted to control activation. Electrochemical erosion of one of the electrodes reveals an underlying graphic image. Game assemblies are constructed by dividing electrochemical components between a main substrate and one or more mounting pieces that can be assembled on the main substrate to activate the display cells.

Claims

1. An interactive electrochemical display assembly comprising:

first and second electrode layers interconnected by an ionically conductive pathway and an electronically conductive pathway;

a graphic image obscured from view by said first electrode layer;

a plurality of switches having open and closed states;

said open states of the switches interrupting at least one of said ionically and electronically conductive pathways;

said closed states of the switches completing portions of at least one of said ionically and electronically conductive pathways; and

said switches being closable in a pattern that triggers an electrochemical reaction that erodes at least one portion of said first electrode layer and reveals at least one portion of said graphic image.

2. The display assembly of claim 1 in which said at least one conductive pathway is arranged as a logical network interrelating combinations of said open and closed states of the switches.

3. The display assembly of claim 2 in which said electronically conductive pathway is interrupted by at least two of said switches in series so that closing both of said switches is required to complete said electronically conductive pathway between the electrode layers.

4. The display assembly of claim 1 in which a first portion of a thin metal film forms at least a portion of said first electrode layer, and a second portion of the same thin metal film forms at least a portion of said electronically conductive pathway.

5. The display assembly of claim 4 in which one of said switches bridges said first and second portions of the thin metal film.

6. The display assembly of claim 5 in which another of said switches bridges said second portion of the thin metal film and said second electrode layer.

7. The display assembly of claim 1 in which each of said switches includes a pair of contacts and a switch arm, said pairs of contacts and both of said electrode layers are mounted on a common substrate, and said switch arms are mounted on different substrates.

8. The display assembly of claim 7 in which said switch arms include conductive layers for completing portions of the conductive pathways.

9. The display assembly of claim 8 in which said conductive layers of the switch arms have adhesive properties for permanently closing said switches.

10. The display assembly of claim 9 further comprising release layers covering said conductive layers of the switch arms for protecting said conductive layers prior to use.

11. The display assembly of claim 1 in which said ionically conductive pathway is formed at least in part by an electrolyte layer.

12. The display assembly of claim 11 in which said electrolyte layer overlaps said first and second electrode layers, said second electrode layer overlaps said first electrode layer, and said second electrode layer includes openings for exposing portions of said first electrode layer to the electrolyte layer for completing the ionically conductive pathway between the electrode layers.

13. The display assembly of claim 1 in which said first electrode layer is divided into different portions, said ionically conductive pathway is one of a plurality of ionically conductive pathways connecting said different portions of said first electrode layer to said second electrode layer, and said electronically conductive pathway is one of a plurality of electronically conductive pathways connecting said different portions of said first electrode layer to said second electrode layer.

14. The display assembly of claim 13 in which said ionically conductive pathways are physically separated from each other.

15. The display assembly of claim 13 in which said ionically conductive pathways also interconnect said different portions of said first electrode layer.

16. The display assembly of claim 1 in which said electrode layers have different electrode potentials.

17. An interactive compound display assembly comprising:

a plurality of mounting pieces;

a main substrate having prescribed locations for receiving said mounting pieces;

said mounting pieces including portions of electrochemical display cells that undergo electrochemical reactions for changing between display states;

said main substrate including remaining portions of said electrochemical display cells at said prescribed locations; and

said mounting pieces being receivable in said prescribed locations on the substrate for changing the display states of the display cells.

18. The assembly of claim 17 in which said electrochemical display cells are voltaic cells.

19. The assembly of claim 18 in which said mounting pieces include a conductive adhesive for supporting flows of current through said display cells.

20. The assembly of claim 19 in which said mounting pieces also include a release layer for protecting said conductive adhesive prior to use.

21. The assembly of claim 20 in which said display undergoes an irreversible change between states in response to the flow of current.

22. The assembly of claim 17 in which each of said electrochemical display cells includes two electrode layers and an electrolyte layer.

23. The assembly of claim 22 in which each of said mounting pieces includes said electrolyte layer.

24. The assembly of claim 23 in which said electrolyte layer is formed by an electrolytic adhesive for bonding the mounting pieces to the prescribed locations on the substrate.

25. The assembly of claim 24 in which each of said mounting pieces also includes one of said electrode layers.

26. The assembly of claim 25 in which said electrode layer of the mounting pieces includes an opening for viewing the changes in the display states.

27. The assembly of claim 25 in which said mounting pieces also include an electronically conductive adhesive for completing an electronically conductive pathway between the electrode layers.

28. The assembly of claim 22 in which said substrate includes one of said electrode layers of the display cells at the prescribed locations.

29. The assembly of claim 28 in which the display cells share a common electrode layer on said substrate.

30. The assembly of claim 28 in which said substrate includes a graphics layer that is hidden by said one electrode layer at the prescribed locations.

31. The assembly of claim 30 in which said one electrode layer is erodable by the electrochemical reactions for revealing said graphics layer at the prescribed locations on the substrate.

32. A printed display assembly comprising:

a plurality of mounting pieces;

a substrate having prescribed locations for receiving said plurality of mounting pieces;

at least one irreversible electrochemical display being layered on said substrate;

at least one pair of switch contacts being layered on said substrate in said prescribed locations;

a conductive pattern also being layered on said substrate interconnecting said electrochemical display with said switch contacts;

each of said mounting pieces including a conductive medium for completing a conductive path through said switch contacts;

said at least one irreversible electrochemical display supporting an electrochemical reaction for irreversibly changing between display states; and

said at least one electrochemical display being arranged to irreversibly change between said display states in response to said mounting pieces being mounted in at least one of said prescribed locations on the substrate.

33. The assembly of claim 32 in which said conductive pattern provides a series connection between pairs of switch contacts for requiring more than one of said mounting pieces to be mounted in said prescribed locations for changing display states of said at least one display.

34. The assembly of claim 32 in which said conductive pattern provides a parallel connection between pairs of switch contacts and said at least one display for changing display states of said at least one display in response to mounting said mounting pieces in more than one of said prescribed locations.

35. The assembly of claim 32 in which said electrochemical display includes an electrode that is erodable for producing the irreversible change.

36. The assembly of claim 32 in which a graphic image is revealed by the erosion of the electrode.

37. An interactive electrochemical display assembly including three electrochemical cell layers, two of said electrochemical cell layers are electrode layers, one of said electrochemical cell layers is an electrolyte layer, and at least two of said electrochemical cell layers are mounted together on a common substrate;

a graphic image is overlapped by one of said two electrode layers; and

said two electrochemical cell layers are combined with a third of said electrochemical cell layers in a manner that completes an ionically conductive pathway between said two electrode layers and that initiates an electrochemical reaction that clears said overlapping electrode layer to reveal said graphic image.

38. The assembly of claim 37 in which said third electrochemical cell layer is said electrolyte layer.

39. The assembly of claim 38 in which said electrolyte layer is formed by an electrolytic adhesive.

40. The assembly of claim 39 further comprising a release layer that covers said electrolyte layer prior to combining with said two electrode layers.

41. The assembly of claim 37 in which said third electrochemical cell layer is one of said two electrode layers.

42. The assembly of claim 41 further comprising a conductive layer for electronically interconnecting said two electrode layers.

43. The assembly of claim 41 in which said third electrochemical cell layer is said overlapping electrode layer.

44. The assembly of claim 37 in which one of said two electrochemical cell layers is said overlapping electrode layer.

45. The assembly of claim 44 in which said graphic image is formed on said common substrate.

46. An interactive electrochemical display assembly comprising:

two electrode layers having different electrode potentials;

an ionically conductive pathway between said two electrode layers;

and electronically conductive pathway between said two layers;

one of said electrode layers overlapping a graphic image;

said two electrode layers and said two pathways being distributed between at least two disconnected substrates interrupting at least one of said two pathways; and

said two disconnected substrates being connectable for completing the interrupted pathway and for producing an electrochemical reaction that erodes said overlapping electrode and reveals said graphic image.

47. The assembly of claim 46 in which said ionically conductive pathway is formed by an electrolyte layer that is mounted on one of said substrates out of contact with at least one of said two electrode layers mounted on another of said substrates.

48. The assembly of claim 47 in which said electrolyte layer is mounted out of contact with both of said electrode layers.

49. The assembly of claim 46 in which said electrolyte layer is formed by an electrolytic adhesive for bonding the substrates together.

50. The assembly of claim 46 in which said electronically conductive pathway is divided between said disconnected substrates.

51. The assembly of claim 50 in which switch contacts of said electronically conductive pathway are mounted on one of said substrates, and switch arms for completing said electronically conductive pathway are mounted on another of said substrates.

52. The assembly of claim 50 in which said switch arms have adhesive properties for permanently closing said switches.

53. An interactive display cell comprising:

two electrode layers and a graphic image overlapped by one of said electrode layers;

an opening that exposes the two electrode layers for contact with an electrolyte; and

said display cell being activatable by adding the electrolyte through said opening and triggering an electrochemical reaction that clears said overlapping electrode layer to reveal said graphic image.

54. The display cell of claim 53 in which said overlapping electrode is oxidized in response to an electrochemical reaction supported by the electrolyte.

55. The display cell of claim 54 in which erosion of the electrode reveals said image.

56. The display cell of claim 53 in which said electrochemical display includes two electrodes that generate an electropotential in the presence of the electrolyte added through said opening in the substrate.

57. The display cell of claim 53 in which said electrolyte is safe for human consumption.

58. The display cell of claim 53 in which said two electrode layers are stacked together between top and bottom substrates, and said opening is formed through said top substrate.

59. The display cell of claim 58 in which said two electrodes are separated by a porous spacer in fluid communication with said opening through the top substrate.

60. The display cell of claim 59 in which said top substrate is transparent to provide a window for viewing said graphic image, and said graphic image is offset from said opening through the top substrate.

61. An interactive electrochemical display cell comprising:

two electrodes having different electrode potential and an electrolyte layer mounted on a common substrate;

a graphic image overlapped by one of said electrodes;

a pair of electrical contacts interrupting an electronically conductive pathway between said electrodes; and

said electrodes being exposed so that said common substrate can be folded together to complete the electronically conductive pathway in support of an electrochemical reaction that erodes said overlapping electrode and reveals said graphic image.

62. The display cell of claim 61 further comprising a conductive adhesive applied to one of said contacts.

63. The display cell of claim 62 further comprising a release layer covering said conductive adhesive.

64. A series of printed indicators made by an in-line process comprising:

a flexible web having a length;

a series of irreversible electrochemical displays that upon activation evolve from a first state to a second state;

a series of switches for activating said electrochemical displays; and

said electrochemical displays and said switches being printed in layers along said length of the web.

65. The indicators of claim 64 in which said electrochemical displays include first and second electrodes, ionically conductive pathways between said first and second electrodes, and electronically conductive pathways between said first and second electrodes.

66. The indicators of claim 65 in which said switches have open and closed states, said open states interrupting one of said ionically and electronically conductive pathways and said closed state completing one of said ionically and electronically conductive pathways for activating said electrochemical displays.

67. The indicators of claim 66 in which said switches are part of said ionically conductive pathways.

68. The indicators of claim 67 in which said open state of the switches confines electrolyte, and said closed state of the switches releases electrolyte for completing said ionically conductive pathways.

69. The indicators of claim 66 in which said switches are part of said electronically conductive pathways.

70. The indicators of claim 69 in which said electronically conductive pathways connect each of said electrochemical displays with more than one of said switches.

71. The indicators of claim 70 in which said electronically conductive pathways are logical networks relating combinations of said conductive states of the switches to the display states of the electrochemical displays.

72. The indicators of claim 65 in which one of said electrodes is eroded for providing the irreversible change between display states.

73. The indicators of claim 72 in which said one electrode is a thin film that is eroded to reveal a graphic image.