Electrodes

• US 6,290,836 B1
• Filed: 09/27/1999
• Issued: 09/18/2001
• Est. Priority Date: 02/04/1997
• Status: Expired due to Fees

• Current Assignee: Caroline J. Davies, Christopher J. Davies, Christopher R. Eccles, Robert M.V. Beith
• Original Assignee: Caroline J. Davies, Christopher J. Davies, Christopher R. Eccles, Robert M.V. Beith
• Inventors: Eccles, Christopher Robert
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US09/355,783
• Time in Patent Office: 722 Days
• Field of Search: 205/636, 205/638, 205/210, 205/217, 205/218, 205/223, 204/290.01, 204/292, 204/293, 204/278
• US Class Current: 205/638
• CPC Class Codes: C25B 11/00 Electrodes; Manufacture thereof not otherwise provided for

Abstract

An electrode (1) having an active surface for contacting an electrolyte. The electrode (1) comprises first and second metallic materials (2, 3) arranged to provide a number of first metallic material to second metallic material interfaces at the active surface. The invention also relates to a method of making such an electrode (1) and to an electrolysis cell provided with such an electrode (1).

Claims

1. An electrode having an active surface for contacting and electrolyte comprising first and second metallic materials arranged to provide a plurality of first metallic material to second metallic material interfaces at said active surface, wherein said first metallic material comprises steel and said second metallic material comprises nickel.

2. An electrode according to claim 1, wherein said first metallic material comprises a substrate of the electrode and said second metallic material is an electroplated layer over regions of the substrate.

3. An electrode According to claim 2, wherein said substrate has an uneven surface with exposed, unplated raised portions and trough portions plated with said second metallic material, the unplated raised portions and plated second metallic material providing the said active surface.

4. An electrode according to claim 3, wherein the said raised portions of the substrate have an average spacing distribution of from 0.03 mm to 0.05 mm.

5. An electrode according to claim 1, wherein said first metallic material comprises mild steel.

6. An electrode according to claim 1, wherein said second metallic material comprises a matrix of nickel and chromium.

7. An electrode according to claim 1, wherein the electrode is generally flat and has an active surface on each of its opposite sides.

8. An electrolysis cell for obtaining the release of gaseous products by electrolysis, comprising an electrolyte, an anode and a cathode in the form of an electrode according to claim 1.

9. A cell according to claim 8, wherein the electrolyte comprises dilute sulphuric acid.

10. A cell according to claim 8, wherein the electrolyte comprises lithium sulphate monohydrate, nickel sulphate hexahydrate, chromium sulphate or palladous chloride.

11. A method of obtaining release of gas from an electrolysis cell according to claim 8, comprising applying a decomposition voltage of no more than 1 volt across the anode and cathode of the electrolysis cell.

12. The method of claim 11, wherein the step of applying the decomposition voltage comprises applying a decomposition voltage of no more than 0.8 volts.

13. The method of claim 11, wherein the step of applying the decomposition voltage comprises applying a decomposition voltage between the values of 0.2 to 0.6 volts.

14. A method of making an electrode having an active surface for contacting an electrolyte, comprising plating a substrate of a first metallic material with a second metallic material, wherein the first metallic material comprises steel and the second metallic material comprises nickel and in that regions of the plated second metallic material are removed to create said active surface with a plurality of first metallic material to second metallic material interfaces.

15. A method according to claim 14, wherein the surface or surfaces of the substrate onto which the second metallic material is plated is or are made uneven to create raised portions and trough portions onto which the second metallic material is plated.

16. The method according to claim 15, wherein the surface or surfaces of the substrate is or are made uneven by etching.

17. A method according to claim 14, wherein the said regions of plated metallic material are removed by machining.

18. A method according to claim 17, wherein the regions of plated metallic material are machined from said plated raised portions of the substrate.

19. A method according to claim 14, wherein said first metallic material comprises mild steel.

20. A method according to claim 14, wherein said second metallic material comprises a matrix of nickel and chromium.

21. An electrode having an active surface for contacting an electrolyte comprising first and second metallic materials arranged to provide a plurality of first metallic material to second metallic material interfaces at said active surface, wherein said first metallic material comprises steel.

22. An electrode having an active surface for contacting an electrolyte comprising first and second metallic materials arranged to provide a plurality of first metallic material to second metallic material interfaces at said active surface, wherein said second metallic material comprises nickel.