Appliance windows coated with thermochromic polymer dispersed liquid crystal

• US 6,294,258 B1
• Filed: 05/18/2000
• Issued: 09/25/2001
• Est. Priority Date: 05/18/1999
• Status: Expired due to Fees

• Current Assignee: Tutco, Inc.
• Original Assignee: Tutco, Inc.
• Inventors: Gentile, Michael
• Primary Examiner(s): Boykin, Terressa M.
• Application Number:
  US09/573,391
• Time in Patent Office: 495 Days
• Field of Search: 428/412, 219/635, 219/678
• US Class Current: 428/412
• CPC Class Codes: G02F 1/132 Thermal activation of liquid crystals exhibiting a thermo-optic effect
• CPC Class Codes: G02F 1/1334 based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
• CPC Class Codes: G02F 1/13756 the liquid crystal selectively assuming a light-scattering state G02F1/1334, G02F1/13718 take precedence
• CPC Class Codes: Y10T 428/31507 Of polycarbonate

Abstract

An appliance window coated with a thermochromic, polymer-dispersed liquid crystal (PDLC) material allows users of appliances containing such window to view the inside chamber of the appliance without opening the appliance door. The thermochromic material on the coated window also does not detract from the overall appearance of the appliance and is composed of phase-separated droplets of liquid crystal in a light-transmissive resin matrix. The liquid crystal has an optical index of refraction in the isotropic phase that is similar to the refractive index of the resin and an index of refraction in the liquid crystalline phase that is mismatched with the refractive index of the resin. The thermochromic coating is activated by the thermal energy released by the appliance during operation. The thermal energy raises the temperature of the coating to a sufficient value so as to cause the coating to switch from an opaque state to a clear state. When the temperature is reduced below a critical value, the coating switches back to the opaque state.

Claims

1. A window for use in an appliance, the window being coated with a thermochromic polymer-dispersed liquid crystal material comprising phase-separated droplets of a liquid crystal in a light-transmissive resin matrix, wherein said liquid crystal has an optical index of refraction in an isotropic phase that is similar to the refractive index of the resin and an index of refraction in an liquid crystalline phase that is mismatched with the refractive index of the resin, said thermochromic material being capable of being thermally activated to cause the material to be reversibly switched between a light-scattering mode and a light-transmissive mode.

2. A window according to claim 1, wherein said liquid crystal comprises a dye sufficient to render the liquid crystalline phase of the thermochromic material the same color as the appliance.

3. A window according to claim 1, wherein the liquid crystal is nematic.

4. A window according to claim 1, wherein the liquid crystal comprises a cyanobiphenyl.

5. A window according to claim 1, wherein the resin is selected from the group consisting of epoxy, polyurethane, vinyl, acrylic, polycarbonate, polyester, polyamide, hydrocarbyl, and cellulosic polymers and copolymers.

6. A window according to claim 1, wherein the window comprises a glass substrate on which said thermochromic material is disposed.

7. A window according to claim 1, wherein the window comprises a clear plastic substrate on which said thermochromic material is disposed.

8. A window according to claim 1, wherein the window comprises a plurality of transparent glass and/or plastic layers, wherein the thermochromic material is disposed between two or more of said layers.

9. A window according to claim 1, wherein the appliance is selected from the group consisting of baking ovens, toasters, clothes dryers and washing machines.

10. An appliance containing a window coated with a thermochromic polymer-dispersed liquid crystal material comprising phase-separated droplets of a liquid crystal in a light-transmissive resin matrix, wherein said liquid crystal has an optical index of refraction in an isotropic phase that is similar to the refractive index of the resin and an index of refraction in an liquid crystalline phase that is mismatched with the refractive index of the resin, said thermochromic material being capable of being thermally activated to cause the material to be reversibly switched between a light-scattering mode and a light-transmissive mode.

11. An appliance according to claim 10, wherein said liquid crystal comprises a dye sufficient to render the liquid crystalline phase of the thermochromic material the same color as the appliance.

12. An appliance according to claim 10, wherein the liquid crystal is nematic.

13. An appliance according to claim 10, wherein the liquid crystal comprises a cyanobiphenyl.

14. An appliance according to claim 10, wherein the resin is selected from the group consisting of epoxy, polyurethane, vinyl, acrylic, polycarbonate, polyester, polyamide, hydrocarbyl, and cellulosic polymers and copolymers.

15. An appliance according to claim 10, wherein the window comprises a glass substrate on which said thermochromic material is disposed.

16. An appliance according to claim 10, wherein the window comprises a clear plastic substrate on which said thermochromic material is disposed.

17. An appliance according to claim 10, wherein the window comprises a plurality of transparent glass and/or plastic layers, wherein the thermochromic material is disposed between two or more of said layers.

18. An appliance according to claim 10, wherein the appliance is selected from the group consisting of baking ovens, toasters, clothes dryers and washing machines.