Polymeric powders and method of preparation

• US 6,294,595 B1
• Filed: 08/30/1999
• Issued: 09/25/2001
• Est. Priority Date: 08/30/1999
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: NEXPRESS SOLUTIONS LLC
• Inventors: DiPrima, Donna A., Tyagi, Dinesh
• Primary Examiner(s): Cain, Edward J.
• Application Number:
  US09/385,567
• Time in Patent Office: 757 Days
• Field of Search: 523/333, 523/334
• US Class Current: 523/333
• CPC Class Codes: C08J 3/14 by precipitation from solutions C08J3/122 takes precedence

Abstract

Polymeric powders of small particle size and size distribution and of irregular morphology are prepared by a limited coalescence procedure wherein a polymer in an organic solvent is dispersed by high shear agitation in an aqueous phase containing colloidal stabilizer particles having opposite electrostatic charges. The organic solvent is evaporated and the polymer particles are recovered from the aqueous medium. The particles are of irregular shape and narrow particle size distribution and have superior electrostatic transfer properties when used as electrostatographic dry toners.

Claims

1. The method for preparing polymeric powders of irregular particle shape which comprises

forming an organic phase comprising an organic polymer dissolved in a water-immiscible organic solvent,

forming an aqueous phase comprising water, solid colloidal stabilizer particles having a positive electrostatic charge and solid colloidal stabilizer particles having a negative electrostatic charge,

mixing said aqueous phase and said organic phase and homogenizing the resulting mixture by high shear agitation, thereby forming a suspension of small particles of said polymer in the water, said particles having a thin coating of said positively charged and negatively charged stabilizer particles on their surfaces, and

separating the water-immiscible solvent from the polymer to obtain a powder of stabilizer-coated polymer particles, of non-spherical, irregular shape.

2. The method according to claim 1 wherein the solvent is removed from the polymer by evaporation.

3. The method according to claim 2 for making an electrostatographic toner wherein toner additives, including pigment and charge control agent, are mixed with the organic phase before mixing with the aqueous phase.

4. The method according to claim 1 where said colloidal stabilizer particles are colloidal silica particles.

5. The method according to claim 1 wherein said colloidal stabilizer particles are latex particles.

6. The method according to claim 4 wherein silica is removed by washing the polymer particles with an alkaline solution.

7. The method according to claim 6 wherein the polymer particles are dried after washing with the alkaline solution to obtain a monodisperse toner powder of non-spherical polymer particles having particle size in the range from 2 to 20 μ

m.

8. The method according to claim 1 which further comprises adjusting the solution conditions to cause both the positively-charged and the negatively-charged stabilizer particles to deposit on the polymer particles.

9. The method according to claim 4 wherein the aqueous phase contains a water-soluble promoter.