Method for thermally spraying crack-free mullite coatings on ceramic-based substrates

• US 6,296,909 B1
• Filed: 05/11/2000
• Issued: 10/02/2001
• Est. Priority Date: 12/22/1998
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Wang, Hongyu, Spitsberg, Irene T., Heidorn, Raymond W.
• Primary Examiner(s): Bareford, Katherine A.
• Application Number:
  US09/569,289
• Time in Patent Office: 509 Days
• Field of Search: 427/452, 427/453, 427/454
• US Class Current: 427/452
• CPC Class Codes: C04B 35/565 based on silicon carbide
• CPC Class Codes: C04B 35/806 The matrix of the ceramic products consisting of non-oxides only
• CPC Class Codes: C04B 41/0072 Heat treatment
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4527 Plasma spraying deposition from the gas phase using plasma C04B41/4533
• CPC Class Codes: C04B 41/5037 Clay, Kaolin
• CPC Class Codes: C04B 41/87 Ceramics
• CPC Class Codes: C23C 4/11 Oxides

Abstract

A process for depositing a mullite coating on a silicon-based material, such as those used to form articles exposed to high temperatures and including the hostile thermal environment of a gas turbine engine. The process is generally to thermally spray a mullite powder to form a mullite layer on a substrate, in which the thermal spraying process is performed so that the mullite powder absorbs a sufficient low level of energy from the thermal source to prevent evaporation of silica from the mullite powder. Processing includes deposition parameter adjustments or annealing to maintain or reestablish phase equilibrium in the mullite layer, so that through-thickness cracks in the mullite layer are avoided.

Claims

1. A method comprising the steps of:

thermal spraying a mullite powder to form a mullite layer on a substrate, the thermal spraying step being performed so that the mullite powder is heated to a deposition temperature between the peritectic and liquidus temperatures of mullite, by which the mullite powder melts to form a silica-rich liquid phase and solid alumina phases, and the mullite layer is deposited to contain alumina phases in a silica-rich mullite matrix;

following deposition of the mullite layer but before the mullite layer cools from the deposition temperature to a temperature at which cracks form in the mullite layer, heating the mullite layer in-situ for a duration and at a temperature sufficient to convert the alumina phases to mullite and thereby substantially achieve phase equilibrium within the mullite layer; and

then

cooling the mullite layer to room temperature, the mullite layer being substantially free of alumina phases and silica-rich phases and free of through-thickness cracks.

2. A method as recited in claim 1, wherein the thermal spraying step is a process chosen from the group consisting of air plasma spraying and low pressure plasma spraying.

3. A method as recited in claim 1, wherein the thermal spraying step is performed with a plasma gun, and the in-situ heating step is performed using a plasma flame generated by the plasma gun.

4. A method as recited in claim 1, wherein the in-situ heating step is performed using at least one heat source selected from the group consisting of lasers, infrared lights, and electron beams.

5. A method as recited in claim 1, further comprising the step of depositing a ceramic coating on the mullite layer.

6. A method as recited in claim 1, wherein the substrate is a silicon-based monolithic or composite ceramic.

7. A method as recited in claim 1, wherein the substrate is chosen from the group consisting of silicon carbide particles dispersed in a matrix material, composites having a silicon carbide matrix, and composites having silicon carbide reinforcement in a silicon carbide matrix.

8. A method as recited in claim 1, the method further comprising at least one additional thermal spraying step followed by at least one additional heating step prior to the cooling step so that multiple mullite layers are deposited on the substrate, each of the mullite layers being substantially free of alumina phases and silica-rich phases following the heating steps.

9. A method as recited in claim 1, wherein the substrate is a component of a gas turbine engine.