Ceramer compositions and antistatic abrasion resistant ceramers made therefrom

• US 6,299,799 B1
• Filed: 05/27/1999
• Issued: 10/09/2001
• Est. Priority Date: 05/27/1999
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Craig, Bradley D., Bilkadi, Zayn
• Primary Examiner(s): KOPEC, MARK T
• Application Number:
  US09/318,547
• Time in Patent Office: 866 Days
• Field of Search: 252/500, 428/357, 428/922, 501/133
• US Class Current: 252/500
• CPC Class Codes: C08G 61/122 derived from five- or six-membered heterocyclic compounds, other than imides
• CPC Class Codes: C08G 61/126 with a five-membered ring containing one sulfur atom in the ring
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: Y10S 428/922 Static electricity metal bleed-off metallic stock

Abstract

The present invention relates to ceramer compositions capable of being cured to form antistatic, abrasion resistant ceramers. The ceramer compositons comprise a plurality of colloidal silica particles, a binder precursor, and an electrically conductive organic polymer, for example, polythiophene. The present invention also relates to ceramer articles, for example, ceramer coatings and shaped ceramer particles made from the ceramer compositions and to methods of making the ceramer compositions and ceramer articles.

Claims

1. A ceramer composition comprising:

a plurality of colloidal silica particles;

a binder precursor;

a dispersion of an electrically conductive organic polymer; and

an amide containing compound.

2. The ceramer composition of claim 1, further comprising a curing agent.

3. The ceramer composition of claim 1, further comprising a coupling agent.

4. The ceramer composition of claim 3, wherein the coupling agent is selected from the group consisting of monofunctional organosilicon compounds, polyfunctional organosilicon compounds, and combinations thereof.

5. The ceramer composition of claim 3, wherein the coupling agent comprises 3-(trimethoxysilyl)propylmethacrylate, 3-(triethoxysilyl)propylmethacrylate, or a mixture thereof.

6. The ceramer composition of claim 3, wherein the coupling agent comprises about 1 to about 15 weight percent of the ceramer composition.

7. The ceramer composition of claim 1, further comprising a plurality of colloidal inorganic oxide particles selected from the group consisting of alumina particles, titania particles, zirconia particles, ceria particles, antimony oxide particles, and combinations thereof.

8. The ceramer composition of claim 1, wherein the electrically conductive organic polymer is selected from the group consisting of polypyrroles, polythiophenes, and polyanilines.

9. The ceramer composition of claim 1, wherein the electrically conductive organic polymer comprises 3,4-polyethylenedioxythiophene.

10. The ceramer composition of claim 9, wherein the 3,4-polyethylenedioxythiophene is stabilized with polystyrene sulfonate.

11. The ceramer composition of claim 1, wherein the electrically conductive organic polymer comprises about 0.05 to about 10 weight percent of the ceramer composition.

12. The ceramer composition of claim 1, wherein the colloidal silica particles range in size from about 5 to about 100 nm.

13. The ceramer composition of claim 1, wherein the colloidal silica particles range in size from about 10 to about 50 nm.

14. The ceramer composition of claim 1, wherein the colloidal silica particles comprise from about 10 to about 50 weight percent of the composition.

15. The ceramer composition of claim 1, wherein the amide-containing compound is selected from the group consisting of N,N-disubstituted acetamides, N,N-disubstituted formamides, N,N-disubstituted acrylamides, N-substituted pyrolidinones, N-substituted formamides, N-substituted caprolactams, and combinations thereof.

16. The ceramer composition of claim 1, wherein the amide-containing compound is selected from the group consisting of N,N-dimethyl acetamide, 1-vinyl-2-pyrrolidinone, N-methylpyrrolidinone, N-vinyl caprolactam, N-vinyl formamide, N,N-dimethylacrylamide, and combinations thereof.

17. The ceramer composition of claim 1, wherein the amide-containing compound comprises about 1 to about 90 weight percent of the composition.

18. The ceramer composition of claim 1, wherein the binder precursor is selected from the group consisting of ethylenically unsaturated monomers, oligomers, or combinations thereof.

19. The ceramer composition of claim 1, wherein the binder precursor comprises a (meth)acrylic acid, a (meth)acrylic acid ester, an amide or a combination thereof.

20. The ceramer composition of claim 19, wherein the binder precursor is selected from the group consisting of N,N-dimethylacrylamide, pentaerythritol triacrylate, 2-hydroxyethylacrylate, 2-hydroxymethyl acrylate, N-vinyl pyrrolidinone, N-vinyl formamide and combinations thereof.

21. The ceramer composition of claim 1, wherein the binder precursor comprises about 5 to about 80 weight percent of the ceramer composition.

22. The ceramer composition of claim 1, wherein the colloidal silica particles are prepared from a silica sol having a pH in the range of about 2 to about 6.

23. A ceramer prepared from the ceramer composition of claim 1.

24. The ceramer of claim 23, wherein the ceramer is transparent.

25. The ceramer of claim 23, wherein the ceramer has a surface resistivity in the range of about 10⁴ to about 10¹² ohms/square.

26. The ceramer of claim 23, wherein the ceramer is provided in the form a coating adhered to a substrate.

27. The ceramer of claim 26, wherein the ceramer coating has a thickness in the range of about 1 to about 30 micrometers.

28. The ceramer of claim 26, wherein the substrate is selected from the group consisting of storage containers for electronic devices, abrasive articles, faces of electronic display devices, packaging material, floor coverings, wall coverings, window coverings, and pressure sensitive adhesive tapes.

29. A ceramer composition comprising:

a plurality of colloidal silica particles;

a binder precursor;

a dispersion of an electrically conductive organic polymer; and

a plurality of colloidal inorganic oxide particles selected from the group consisting of alumina particles, titania particles, zirconia particles, ceria particles, antimony oxide particles, and combinations thereof.

30. The ceramer composition of claim 29, further comprising a curing agent.

31. The ceramer composition of claim 29, further comprising a coupling agent.

32. The ceramer composition of claim 29, wherein the electrically conductive organic polymer is selected from the group consisting of polypyrroles, polythiophenes, and polyanilines.

33. The ceramer composition of claim 29, wherein the electrically conductive organic polymer comprises 3,4-polyethylenedioxythiophene.

34. The ceramer composition of claim 29, wherein the binder precursor is selected from the group consisting of ethylenically unsaturated monomers, oligomers, or combinations thereof.

35. A ceramer prepared from the ceramer composition of claim 29.

36. The ceramer of claim 35, wherein the ceramer has a surface resistivity in the range of about 10⁴ to about 10¹² ohms/square.

37. The ceramer of claim 36, wherein the ceramer is provided in the form a coating adhered to a substrate.

38. A method of making a ceramer composition capable of producing a transparent ceramer, said method comprising the steps of:

a) combining an aqueous silica sol with a binder precursor to form a mixture;

b) drying the mixture of step a);

c) mixing an amide-containing compound with an electrically conductive organic polymer to form an electrically conductive organic dispersion; and

d) combining the dispersion of electrically conductive organic polymer of step c) with the mixture of step b) to form the ceramer composition capable of producing a transparent ceramer.

39. The method of claim 38, wherein step a) includes combining the aqueous silica sol with a coupling agent and the binder precursor to form the mixture.

40. The method of claim 38, wherein the electrically conductive organic polymer of step c) is associated with a counter-ion.

41. The method of claim 38, wherein the counter-ion is a sulfonic acid.

42. A method of making an antistatic ceramer, said method comprising the steps of:

a) combining an aqueous silica sol with a binder precursor to form a mixture;

b) drying the mixture of step a);

c) mixing an amide-containing compound with an electrically conductive organic polymer to form an electrically conductive organic dispersion;

d) combining the dispersion of electrically conductive organic polymer of step c) with the mixture of step b) to form a ceramer composition; and

e) curing the ceramer composition of step d) to form an antistatic ceramer.