Thermosetting resins and laminates

• US 6,306,963 B1
• Filed: 09/07/2000
• Issued: 10/23/2001
• Est. Priority Date: 05/08/2000
• Status: Expired due to Fees

• Current Assignee: GIL Technologies, Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company, GIL Technologies
• Inventors: Austill, Timothy W., Reis, David Peter, Guo, Hua, Chao, Herbert Shin-I, Devanathan, Narsi, Parrillo, David, Lane, Scott A., Rollen, Donald C., David, Benny, Zarnoch, Kenneth P.
• Primary Examiner(s): MULLIS, JEFFREY C
• Application Number:
  US09/657,648
• Time in Patent Office: 411 Days
• Field of Search: 525/68, 525/69, 525/242, 525/333.7
• US Class Current: 525/68
• CPC Class Codes: C08F 290/061 Polyesters; Polycarbonates
• CPC Class Codes: C08F 290/067 Polyurethanes; Polyureas
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 71/126 modified by chemical after-treatment
• CPC Class Codes: H05K 1/0353 consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement

Abstract

Thermosetting polymers and the electrical laminates made therefrom are disclosed. The laminate comprises a cross-linked product of: a) one or more ethylenically unsaturated aromatic monomers, with fire retardation being optionally contributed by one halogenated monomer, b) a vinyl-terminated polybutadiene or butadiene-styrene copolymer containing either a urethane or an ester group, and c) a chemically modified polyphenylene ether resin, preferably low molecular weight chemically modified polyphenylene ether resin. It has been discovered that an unexpected combination of thermal, electrical, and mechanical properties are obtained from the composition recited herein. Therefore, the composition is ideally suited as a matrix polymer for electrical substrate applications.

Claims

1. A thermosetting resin composition comprising:

(a) at least 50% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

wherein R¹ represents a hydrogen, an alkene group, or alkyl group, and n=1, or wherein R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group, and;

(b) from 1 to 50% by weight of a vinyl-terminated polymer having the formula;

wherein R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer, and k is on average less than 3, and;

(c) from 1 to 50% of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein all weight percentages are based on the combined weights of components (a), (b), and (c).

2. The composition of claim 1, wherein said ethylenically unsaturated monomer is selected from the group consisting of dibromostyrene, styrene, divinyl benzene, α

-methyl styrene, and mixtures comprising at least one of the foregoing.

3. The composition of claim 1, which further comprises an initiator.

4. The composition of claim 3, wherein said initiator is selected from the group consisting of t-butyl peroctoate, t-butyl peroxy benzoate, and dicumyl peroxide.

5. The composition of claim 1, wherein said vinyl-terminated polybutadiene homopolymer containing a urethane group is the reaction product of a polybutadiene polyol with a vinyl terminated isocyanate.

6. The composition of claim 1, wherein said vinyl-terminated polybutadiene homopolymer containing an ester group is the reaction product of a carboxyl-terminated polybutadiene homopolymer with a vinyl-terminated epoxide.

7. The composition of claim 1, wherein said vinyl-terminated butadiene-styrene copolymer containing an ester group is the reaction product of a carboxyl-terminated butadiene-styrene copoylmer with a vinyl-terminated epoxide.

8. The composition of claim 1, wherein said chemically modified polyphenylene ether resin has an intrinsic viscosity between about 0.08 and 0.14 dl/g as measured in chloroform at 30°

C.

9. The composition of claim 1, wherein said chemically modified polyphenylene ether resin comprises a chemically modified polyphenylene ether resin of the formula:

 

Q—

(J—

K)m

wherein Q is the residuum of a phenol;

J comprises recurring units of the following structure;

wherein R^5-8 independently is selected from hydrogen, alkyl, alkenyl, alkynoyl, aryl, mixed alkyl-aryl hydrocarbons, wherein such groups may contain a substituent selected from carboxylic acid, aldehyde, alcohol, and amino functionality;

K has the following structure;

wherein R^9-11 is a hydrogen or C_1-100 alkyl or aryl or mixed alkyl or aryl group;

X is an oxygen, and m ranges from 1-200.

10. The composition of claim 1, wherein said chemically modified polyphenylene ether resin comprises residual methacrylate moieties.

11. The composition of claim 1, wherein said chemically modified polyphenylene ether resin comprises a chemically modified polyphenylene ether resin having the formula:

wherein R⁵ represents CH₃ or H, R⁶ represents an alkylidene group, and i=1 to 6, and j<

30.

12. The composition of claim 1, wherein said chemically modified polyphenylene ether resin comprises substantially no residual phenolic hydroxyls.

13. The composition of claim 1, wherein vinyl-terminated polymer comprises:

14. The composition of claim 1, where in vinyl-terminated polymer comprises:

wherein x is from about 50 to 250.

15. A reaction product of a composition comprising:

(a) at least 50% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

where R¹ represents a hydrogen, an alkene group or alkyl groups and n=1, or where R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group, and;

(b) from 1 to 50% by weight of a vinyl-terminated polymer having the formula;

where R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer, and k is on average less than 3, and;

(c) from 1 to 50% of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein all weight percentages are based on the combined weights of components (a), (b), and (c).

16. The reaction product of claim 15, wherein said chemically modified polyphenylene ether resin has an intrinsic viscosity between about 0.08 and 0.14 dl/g as measured in chloroform at 30°

C.

17. The reaction product of claim 15, wherein said chemically modified polyphenylene ether resin comprises residual methacrylate moieties.

18. The reaction product of claim 15, wherein said chemically modified polyphenylene ether resin comprises substantially no residual phenolic hydroxyls.

19. The reaction product of claim 15, wherein said vinyl-terminated polymer comprises:

20. The reaction product of claim 15, wherein said vinyl-terminated polymer comprises:

wherein x is from about 50 to 250.

21. A laminate comprising:

(i) a reaction product of a composition comprising;

(a) from 20 to 90% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

where R¹ represents a hydrogen, an alkene group or alkyl groups and n=1, or where R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group;

(b) from 1 to 50% by weight of a vinyl-terminated polymer having the formula;

where R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer; and

k is on average less than 3, and

(c) from 1 to 50% by weight of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein the weight percentages of components (a), (b), and (c) are based on the combined weights of components (a), (b), and (c);

(ii) from 5 to 60% by weight of a woven fabric based on the combined weights of components (i) and (ii).

22. The laminate of claim 21, wherein said chemically modified polyphenylene ether resin has an intrinsic viscosity between about 0.08 and 0.14 dl/g as measured in chloroform at 30°

C.

23. The laminate of claim 21, wherein said composition further comprises an initiator.

24. The laminate of claim 22, wherein said initiator wherein said initiator is selected from the group consisting of t-butyl peroctoate, t-butyl peroxy benzoate, and dicumyl peroxide.

25. The laminate of claim 21, wherein said ethylenically unsaturated aromatic monomer is selected from the group consisting of styrene, dibromostyrene, divinyl benzene, α

-methyl styrene, and mixtures comprising at least one of the foregoing.

26. The laminate of claim 21, wherein said laminate is clad with metal foil on one or both sides.

27. The laminate of claim 26, wherein said metal foil is copper foil.

28. The laminate of claim 21, wherein said laminate has a thickness between about 0.002 to about 0.120 inches.

29. The laminate of claim 21, wherein said laminate has a dissipation factor of less than about 0.004 at 10 GHz.

30. The laminate of claim 21, wherein said laminate comprises a microwave circuit substrate.

31. The laminate of claim 21, wherein said vinyl-terminated polymer comprises:

32. The laminate of claim 21, wherein said vinyl-terminated polymer comprises:

wherein x is from about 50 to 250.

33. A laminate comprising:

(i) a reaction product of a composition comprising;

(a) from 20 to 90% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

where R¹ represents a hydrogen, an alkene group or alkyl groups and n=1, or where R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group;

(b) from 1 to 50% by weight of a vinyl-terminated polymer having the formula;

where R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer; and

k is on average less than 3, and

(c) from 1 to 50% by weight of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein the weight percentages of components (a), (b), and (c) are based on the combined weights of components (a), (b), and

(ii) from 5 to 60% by weight of a woven fabric and from 1 to 25% by weight of one or more inorganic fillers, based on the combined weights of components (i) and (ii).

34. The laminate of claim 33, wherein said chemically modified polyphenylene ether resin has an intrinsic viscosity between about 0.08 and 0.14 dl/g as measured in chloroform at 30°

C.

35. The laminate of claim 33, wherein said chemically modified polyphenylene ether resin comprises residual methacrylate moieties.

36. The laminate of claim 33, wherein said chemically modified polyphenylene ether resin comprises substantially no residual phenolic hydroxyls.

37. The laminate of claim 33, wherein said composition further comprises an initiator.

38. The laminate of claim 37, wherein said initiator wherein said initiator is selected from the group consisting of t-butyl peroctoate, t-butyl peroxy benzoate, and dicumyl peroxide.

39. The laminate of claim 33, wherein said ethylenically unsaturated aromatic monomer is selected from the group consisting of styrene, dibromostyrene, divinyl benzene, α

-methyl styrene, and mixtures comprising at least one of the foregoing.

40. The laminate of claim 33, wherein said laminate is clad with metal foil on one or both sides.

41. The laminate of claim 40, wherein said metal foil is copper foil.

42. The laminate of claim 33, wherein said laminate has a thickness between about 0.002 to about 0.120 inches.

43. The laminate of claim 33, wherein said laminate has a dissipation factor of less than about 0.004 at 10 GHz.

44. The laminate of claim 33, wherein said laminate comprises a microwave circuit substrate.

45. The laminate of claim 33, wherein said inorganic filler is selected form the group consisting of silica, quartz, wollostonite, alumina, boron nitride, magnesium aluminum silicate, kaolin, calcined kaolin, and mixture containing at least one of the foregoing.

46. The laminate of claim 33, wherein said vinyl-terminated polymer comprises:

47. The laminate of claim 33, wherein said vinyl-terminated polymer comprises:

wherein x is from about 50 to 250.

48. A thermosetting resin composition comprising:

about 1 to 99% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

wherein R¹ represents a hydrogen, an alkene group, or alkyl group, and n=1, or wherein R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group, and;

(b) from 1 to 99% by weight of a vinyl-terminated polymer having the formula;

wherein R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer, and k is on average less than 3, and;

(c) from 1 to 99% of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein all weight percentages are based on the combined weights of components (a), (b), and (c).

49. The composition of claim 48, which further comprises an initiator.

50. The composition of claim 48, which further comprises one or more fillers, reinforcing agents, or fillers and reinforcing agents.

51. A reaction product of a composition comprising:

(a) about 1 to 99% by weight of one or more ethylenically unsaturated aromatic monomers having the formula;

wherein R¹ represents a hydrogen, an alkene group, or alkyl group, and n=1, or wherein R¹ represents halogen atoms n=1 to 3, and R² represents a hydrogen atom or an alkyl group, and;

(b) from 1 to 99% by weight of a vinyl-terminated polymer having the formula;

wherein R³ represents CH₃ or H, R⁴ is an urethane or ester residue, and Q represents a polybutadiene homopolymer or a butadiene-styrene copolymer, and k is on average less than 3, and;

(c) from 1 to 99% of a chemically modified polyphenylene ether resin comprising aliphatic unsaturation;

wherein all weight percentages are based on the combined weights of components (a), (b), and (c).