Method for reducing hydrogen sulfide level in water containing sulfate-reducing bacteria and hydrogen sulfide-metabolizing bacteria

• US 6,309,597 B1
• Filed: 01/12/1999
• Issued: 10/30/2001
• Est. Priority Date: 05/12/1997
• Status: Expired due to Term

• Current Assignee: Arkion Life Sciences
• Original Assignee: Arkion Life Sciences
• Inventors: Knauer, Robert F., Burger, Edward D., Ballinger, Kenneth E. Jr.
• Primary Examiner(s): MCKANE, ELIZABETH L
• Application Number:
  US09/228,385
• Time in Patent Office: 1,022 Days
• Field of Search: 422/16, 422/14, 422/5, 422/28, 210/764
• US Class Current: 422/28
• CPC Class Codes: A01N 31/06 Oxygen or sulfur directly attached to a cycloaliphatic ring system
• CPC Class Codes: A01N 35/06 containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
• CPC Class Codes: C02F 1/50 by addition or application of a germicide or by oligodynamic treatment C02F1/4606, C02F1/467, C02F1/76 take precedence
• CPC Class Codes: C02F 3/28 Anaerobic digestion processes
• CPC Class Codes: C02F 3/34 characterised by the microorganisms used
• CPC Class Codes: C02F 3/345 for biological oxidation or reduction of sulfur compounds
• CPC Class Codes: E21B 41/02 in situ inhibition of corrosion in boreholes or wells

Abstract

A method for reducing the level of hydrogen sulfide in water containing sulfur-reducing bacteria and hydrogen sulfide-metabolizing bacteria by addition of an aqueous solution of metallic nitrogen oxides and small particles of water-insoluble polycyclic quinones.

Claims

1. A method for reducing the level of hydrogen sulfide (H₂S) in water of pH 4-10, having dispersed therein indigenous amounts of sulfate-reducing bacteria and H₂S-metabolizing bacteria, comprising adding to the H₂S-containing water:

(a) finely divided particles of polycyclic quinone selected from anthraquinone, anthrahydroquinone and mixtures thereof, the average size of the particles being no greater than 10 micrometers, which particles are applied as an aqueous dispersion of (a) water-insoluble non-ionic particles suspended in an aqueous medium or (b) an alkaline solution of an ionic salt of the polycyclic quinone having a pH at least 2 pH units higher than the H₂S-containing water, which salt is thereby converted to the corresponding water-insoluble, non-ionic polycylic quinone particles upon exposure to the lower pH of the H₂S-containing water and

(b) an aqueous solution of metallic nitrogen oxide selected from the group consisting of metal nitrate, nitrite and mixtures thereof, the weight ratio of polycyclic quinone to metallic nitrogen oxide being (3-30)×

10<sup>−

3</sup>, and the amount of the polycyclic quinone and nitrogen oxide added to the H₂S-containing water being sufficient to increase its oxidation-reduction potential (ORP) to a preselected higher level.

2. The method of claim 1 in which the polycyclic quinone is dispersed in the aqueous solution of metallic nitrogen oxide.

3. The method of claim 2 in which the polycyclic quinone is added to the H₂S-containing water in the form of non-ionic particles dispersed in the aqueous solution of metallic nitrogen oxide.

4. The method of claim 2 in which the polycyclic quinone is added to the H₂S-containing water in the form of ionic compounds dissolved in the aqueous alkaline solution of the metallic nitrogen oxide.

5. The method of claim 2 or in which the water is contained in a vessel or conduit, the inner walls of which bear a layer of biofilm in contact with the contained water.

6. The method of claim 1 in which the treated water is quiescent.

7. The method of claim 1 in which the treated water is flowing.

8. The method of claim 1 in which the size of the water-insoluble particles in step (b) is no greater than 2 micrometers.

9. The method of claim 1 in which the preselected ORP level is at least about −

50 mv.