Process of aluminizing steel to obtain and interfacial alloy layer and product therefrom

• US 6,309,761 B1
• Filed: 02/18/2000
• Issued: 10/30/2001
• Est. Priority Date: 02/18/1999
• Status: Expired due to Term

• Current Assignee: Sollac, Co.
• Original Assignee: Sollac, Co.
• Inventors: Lesueur, Eric, Guesdon, Philippe, Godin, Jean-Pierre
• Primary Examiner(s): Koehler, Robert R.
• Application Number:
  US09/506,586
• Time in Patent Office: 620 Days
• Field of Search: 428/653, 428/926, 428/933, 428/939, 427/430.1, 427/431, 427/436, 148/527, 148/531, 148/535
• US Class Current: 428/653
• CPC Class Codes: C23C 2/12 Aluminium or alloys based thereon
• CPC Class Codes: Y10S 428/926 Thickness of individual layer specified
• CPC Class Codes: Y10S 428/933 Sacrificial component
• CPC Class Codes: Y10S 428/939 Molten or fused coating
• CPC Class Codes: Y10T 428/12757 Fe

Abstract

A process in which a steel is dipped in an aluminum-based bath wherein the composition and mean temperature of the bath and the immersion temperature of the steel are adjusted to obtain, in the immersion zone of the steel, a local bath temperature and composition resulting in an equilibrium with the solid phase designated as θ≡FeAl₃. Dipping is performed at a temperature higher than the temperatures normally employed in the art and a coating is obtained having at the interface with the steel an alloy layer significantly smaller in thickness than the art. The coating obtained better resists cracking and corrosion.

Claims

1. An aluminized steel, the coating of which comprises an Al—

Fe—

Si alloy layer and an aluminum-based outer surface layer, wherein the alloy layer comprises, at the contact of the steel substrate, a sub-layer composed essentially of θ

phase.

2. A steel according to claim 1, wherein the thickness of the alloyed layer is less than or equal to about 3 μ

m.

3. A steel according to claim 1, which comprises a carbon steel.

4. A steel according to claim 1, which comprises a stainless steel.

5. A process for aluminizing a steel, comprising:

dipping the steel into an aluminum-based liquid bath;

maintaining a composition and a mean temperature of said bath and a temperature of said steel to obtain, in an immersion zone of the steel, a local bath temperature and bath composition thereby providing an equilibrium with a solid phase designated as θ

, the composition of which corresponds approximately to the chemical formula FeAl₃;

continuing the progression of said steel in said bath beyond said immersion zone and adjusting the composition and the mean temperature of said bath to be in equilibrium with a phase designated as τ

5 or a phase designated as τ

6;

thereby forming an aluminized coating layer.

6. The process according to claim 5, wherein said immersion zone extends:

in thickness, up to a distance of approximately 30 μ

m from a surface of said steel,

in length, along the surface of said steel between the beginning of direct contact between the steel surface and the liquid bath and the beginning of solidification of an interfacial layer composed of the τ

5 or τ

6 phase.

7. The process according to claim 5, wherein the composition and mean temperature of the bath are adjusted to be in equilibrium with the τ

6 phase.

8. The process according to claim 5, wherein the liquid bath is saturated with iron.

9. The process according to claim 5, wherein an immersion temperature of the steel is higher than the bath temperature.

10. The process according to claim 5, wherein the bath contains silicon in an amount of about 8% and an immersion temperature ranges between about 700°

and about 740°

C.

11. The process according to claim 5, wherein the bath contains silicon in an amount of about 9% and an immersion temperature ranges between about 720°

and about 765°

C.

12. The process according to claim 5, wherein the bath contains silicon in an amount of about 9.5%, and an immersion temperature ranges between about 740°

and about 760°

C.

13. The process according to claim 5, wherein the steel is a carbon steel casting.

14. The process according to claim 5, wherein the steel is a stainless-steel casting.

15. In a process for aluminizing steel wherein a steel object is dipped into a molten aluminum-based bath and thereafter cooled to obtain an aluminum-containing layer on said steel object, the improvement which comprises maintaining the composition and mean temperature of the bath and the temperature of the steel object as it is immersed in the bath, to provide in an area of the bath where the object is immersed, a liquid/solid equilibrium with a solid θ

phase whose composition approximates FeAl₃; and

continuing the progression of said steel in said bath and adjusting the composition and the mean temperature of said bath to be in equilibrium with a phase designated as τ

5 or a phase designated as τ

6.