Removal of contaminants from materials

• US 6,312,528 B1
• Filed: 02/27/1998
• Issued: 11/06/2001
• Est. Priority Date: 03/06/1997
• Status: Expired due to Term

• Current Assignee: CRI Recycling Service Incorporated
• Original Assignee: CRI Recycling Service Incorporated
• Inventors: Markiewicz, John P., Summerfield, John W., Barcus, Randall L., Moses, John M.
• Primary Examiner(s): Markoff, Alexander
• Application Number:
  US09/031,901
• Time in Patent Office: 1,348 Days
• Field of Search: 134/19, 134/10, 134/104.2, 134/104.4, 134/105, 134/107, 134/109, 134/12, 134/40, 134/1, 134/11, 134/17, 134/31, 68/18 R, 68/18 D, 68/19, 210/634
• US Class Current: 134/40
• CPC Class Codes: B08B 3/104 using propellers
• CPC Class Codes: B08B 3/12 by sonic or ultrasonic vibrations washing or rinsing machines for crockery or tableware using sonic or ultrasonic waves A47L15/13; of natural teeth, of prostheses using ultrasonic techniques similar to those used for natural teeth A61C17/20; application of ultrasonic vibrations to chemical, physical or physico-chemical processes in general B01J19/10
• CPC Class Codes: B08B 7/0021 by liquid gases or supercritical fluids
• CPC Class Codes: C09K 3/32 for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
• CPC Class Codes: C11D 2111/24 Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
• CPC Class Codes: C11D 2111/46 applying energy, e.g. irradiation
• CPC Class Codes: C11D 3/43 Solvents
• CPC Class Codes: Y02P 20/54 using solvents, e.g. supercritical solvents or ionic liquids

Abstract

An improved approach for cleaning and recycling materials is based on pressurized solvents including liquid propane, butane, dimethyl ether, and supercritical carbon dioxide. The approaches are particularly suitable for cleaning sorbent materials. The approach allows for recycling of the sorbent materials, the solvent and the contaminents, typically oils and the like.

Claims

1. A method of removing contaminants from a contaminated sorbent granular mineral material, said sorbant granular mineral material in virgin form having a contaminant absorbency within the structure of the granular particles of at least about 25 percent by weight of said virgin sorbent granular mineral material, said method comprising:

contacting said contaminated sorbent granular mineral material in a pressure chamber with a pressurized solvent to form a solvent/contaminant mixture and cleaned sorbent granular mineral material, said solvent consisting essentially of a liquefied or supercritical form of ammonia, hydrocarbons or hydrocarbon substituted with functional groups including halogen atoms, oxygen atoms or nitrogen atoms, the solvent being a gas at standard temperature and pressure; and

removing said cleaned sorbent granular mineral material from the pressurized chamber, wherein said cleaned sorbent granular mineral material has at least about 70 percent by weight of said contaminants removed; and

distilling said solvent/contaminant mixture to recover at least a portion of said solvent.

2. The method of claim 1 wherein said sorbent granular mineral material in virgin form has an absorbency greater than about 45 percent by weight of said virgin sorbent material.

3. The method of claim 1 wherein granules of said sorbent granular mineral material has an average diameter from about 0.1 mm to about 2 cm.

4. The method of claim 1 further comprising agitating said solvent in said pressurized chamber.

5. The method of claim 4 wherein said agitation is performed by an approach selected from the group consisting of bubbling gas through said pressure chamber, propelling a mechanical agitator, and applying sonic energy.

6. The method of claim 1 wherein said sorbent granular mineral material comprises a material selected from the group consisting of ball clay, common clay, shale, fire clay, Fuller'"'"'s earth, kaolin, diatomaceous earth, and montmorillonite.

7. The method of claim 1 wherein said cleaned sorbent granular mineral material has an absorptive capacity of at least about 50 percent by volume relative to the corresponding virgin sorbent granular mineral material.

8. The method of claim 1 wherein said cleaned sorbent granular mineral material has at least 85 percent by weight of said contaminants removed.

9. The method of claim 1 wherein said contaminants comprise lubricants, petroleum oils, machine oils, dielectric oils, silicone oils, reflux residues, adhesive residues, plasticizers, fatty materials, waxy materials, or combinations thereof.

10. The method of claim 1 wherein said solvent comprises a liquified form of propane, isobutane, butane, or dimethyl ether.

11. The method of claim 1 wherein said solvent further comprises a surfactant.