Two layer protective coatings

• US 6,312,815 B1
• Filed: 06/12/1997
• Issued: 11/06/2001
• Est. Priority Date: 05/01/1992
• Status: Expired due to Fees

• Current Assignee: American Polymer
• Original Assignee: American Polymer
• Inventors: Dobney, David, Macris, Michael N.
• Primary Examiner(s): Dawson, Robert
• Assistant Examiner(s): AYLWARD, DAVID E
• Application Number:
  US08/873,329
• Time in Patent Office: 1,608 Days
• Field of Search: 428/424.2, 427/407.1, 524/507
• US Class Current: 428/424.2
• CPC Class Codes: B05D 5/00 Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
• CPC Class Codes: B05D 7/53 Base coat plus clear coat type
• CPC Class Codes: C08G 18/42 Polycondensates having carboxylic or carbonic ester groups in the main chain
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• CPC Class Codes: C09D 175/04 Polyurethanes
• CPC Class Codes: C09D 9/04 with surface-active agents
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31573 Next to addition polymer of ethylenically unsaturated monomer

Abstract

A system for protecting surfaces and facilitating the removal of unwanted substances therefrom is disclosed, the system including a polymeric coating having a low volatile organics content (VOC) which is safe for the environment, and a cleaner for application to the coating to remove material from the coating, such as graffiti. The coating may be either a water-based epoxy comprising a bisphenol A resin and polyamide resin, or an aliphatic urethane comprising a polymer having reactive sites which react with a isocyanate and an aliphatic isocyanate. The cleaner is suitable for removing all manner of epoxy and urethane based spray paints, indelible inks, industrial chemicals, and the like. The cleaner comprises N-methyl pyrrolidone in a concentration of fifty percent by weight or greater and a surfactant.

Claims

1. A two layer protective coating for protecting a substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a polyol and an aliphatic polyisocyanate;

said topcoat being clear;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat.

2. A two layer coated substrate as defined in claim 1, wherein said polyol is selected from the group consisting of saturated polyester polyols, acrylic polyols, polyether polyols, ethylene glycol and propylene glycol.

3. A two layer coated substrate as defined in claim 1, wherein said polyol includes saturated polyester polyols having an equivalent weight ranging from about 150 to about 1300.

4. A two layer coated substrate as defined in claim 1, wherein said polyol includes saturated polyester polyols have a weight average molecular weight ranging from about 3500 to about 4300.

5. A two layer coated substrate as defined in claim 1, wherein said aliphatic polyisocyanate has a weight average molecular weight ranging from about 100 to about 5000 and an equivalent weight ranging from about 100 to about 500.

6. A two layer coated substrate as defined in claim 1, wherein the topcoat composition further includes a flatting agent such that the urethane protective topcoat has a finish that is flat.

7. A two layer coated substrate as defined in claim 1, wherein the topcoat composition further includes a flatting agent selected from the group consisting of talc, diatomaceous silica and flumed silica.

8. A two layer coated substrate as defined in claim 1, wherein the topcoat composition further includes a flatting agent in an amount ranging up to about 4.5% by weight of the composition.

9. A two layer coated substrate as defined in claim 1, wherein the topcoat is characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

10. A two layer coated substrate as defined in claim 1, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone without degradation during removal of unwanted substances from the topcoat.

11. A two layer coated substrate as defined in claim 1, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone in a concentration in a range from about fifty percent to one hundred percent by weight of the cleaner without degradation during removal of unwanted substances from the topcoat.

12. A coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a polyol and an aliphatic polyisocyanate;

said polyol being selected from the group consisting of saturated polyester polyols, acrylic polyols, polyether polyols, ethylene glycol and propylene glycol;

said topcoat being clear;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat.

13. A two layer coated substrate as defined in claim 12, wherein said saturated polyester polyols have an equivalent weight ranging from about 150 to about 1300.

14. A two layer coated substrate as defined in claim 12, wherein said saturated polyester polyols have a weight average molecular weight ranging from about 3500 to about 4300.

15. A two layer coated substrate as defined in claim 12, wherein said aliphatic polyisocyanate has a weight average molecular weight ranging from about 100 to about 5000 and an equivalent weight ranging from about 100 to about 500.

16. A two layer coated substrate as defined in claim 12, wherein the topcoat composition further includes a flatting agent such that the urethane protective topcoat has a finish that is flat.

17. A two layer coated substrate as defined in claim 12, wherein the topcoat composition further includes a flatting agent selected from the group consisting of talc, diatomaceous silica and famed silica.

18. A two layer coated substrate as defined in claim 12, wherein the topcoat composition further includes a flatting agent in an amount ranging up to about 4.5% by weight of the composition.

19. A two layer coated substrate as defined in claim 12, wherein the topcoat is characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

20. A two layer coated substrate as defined in claim 12, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone without degradation during removal of unwanted substances from the topcoat.

21. A two layer coated substrate as defined in claim 12, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone in a concentration in a range from about fifty percent to one hundred percent by weight of the cleaner without degradation during removal of unwanted substances from the topcoat.

22. A two layer coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a saturated polyester polyol having an equivalent weight ranging from about 150 to about 1300 with an aliphatic polyisocyanate;

said topcoat being clear;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat.

23. A two layer coated substrate as defined in claim 22, wherein said saturated polyester polyol has a weight average molecular weight ranging from about 3500 to about 4300.

24. A two layer coated substrate as defined in claim 22, wherein the topcoat composition further includes a flatting agent such that the urethane protective topcoat has a finish that is flat.

25. A two layer coated substrate as defined in claim 22, wherein the topcoat composition further includes a flatting agent selected from the group consisting of talc, diatomaceous silica and fumed silica.

26. A two layer coated substrate as defined in claim 22, wherein the topcoat composition further includes a flatting agent in an amount ranging up to about 4.5% by weight of the composition.

27. A two layer coated substrate as defined in claim 22, wherein said aliphatic polyisocyanate has a weight average molecular weight ranging from about 100 to about 5000 and an equivalent weight ranging from about 100 to about 500.

28. A two layer coated substrate as defined in claim 22, wherein the topcoat is characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

29. A two layer coated substrate as defined in claim 22, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone without degradation during removal of unwanted substances from the topcoat.

30. A two layer coated substrate as defined in claim 22, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone in a concentration in a range from about fifty percent to one hundred percent by weight of the cleaner without degradation during removal of unwanted substances from the topcoat.

31. A two layer coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a saturated polyester polyol having a weight average molecular weight ranging from about 3500 to about 4300 with an aliphatic polyisocyanate;

said topcoat being clear;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat.

32. A two layer coated substrate as defined in claim 31, wherein the topcoat composition further includes a flatting agent such that the urethane protective topcoat has a finish that is flat.

33. A two layer coated substrate as defined in claim 31, wherein the topcoat composition further includes a flatting agent selected from the group consisting of talc, diatomaceous silica and fumed silica.

34. A two layer coated substrate as defined in claim 31, wherein the topcoat composition further includes a flatting agent in an amount ranging up to about 4.5% by weight of the composition.

35. A two layer coated substrate as defined in claim 31, wherein said aliphatic polyisocyanate has a weight average molecular weight ranging from about 100 to about 5000 and an equivalent weight ranging from about 100 to about 500.

36. A two layer coated substrate as defined in claim 31, wherein the topcoat is characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

37. A two layer coated substrate as defined in claim 31, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone without degradation during removal of unwanted substances from the topcoat.

38. A two layer coated substrate as defined in claim 31, wherein the topcoat is characterized by the ability to withstand contact with a cleaner comprising N-methyl pyrrolidone in a concentration in a range from about fifty percent to one hundred percent by weight of the cleaner without degradation during removal of unwanted substances from the topcoat.

39. A two layer coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a polyol, a flatting agent, and an aliphatic polyisocyanate;

said polyol being selected from the group consisting of saturated polyester polyols, acrylic polyols, polyether polyols, ethylene glycol and propylene glycol;

said topcoat being clear and having a finish that is at least primarily flat;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat;

said topcoat being characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

40. A two layer coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a saturated polyester polyol having an equivalent weight ranging from about 150 to about 1300, a flatting agent, and an aliphatic polyisocyanate;

said topcoat being clear and having a finish that is flat;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat;

said topcoat being characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.

41. A two layer coated substrate comprising:

a primer layer formed on the substrate from a water-based primer composition obtained by mixing an acrylic copolymer and water;

said primer layer being clear; and

a saturated, aliphatic urethane protective topcoat formed on the primer layer by application of a topcoat composition obtained by mixing a saturated polyester polyol having a weight average molecular weight ranging from about 3500 to about 4300, a flatting agent, and an aliphatic polyisocyanate;

said topcoat being clear and having a finish that is flat;

said primer layer being characterized by the ability to prevent the topcoat from causing the substrate to appear darkened after the topcoat has hardened on the primer layer compared to the appearance of the substrate before application of the primer layer and the topcoat;

said topcoat being characterized by the ability to resist penetration by unwanted substances and by the ability to withstand removal of unwanted substances by a solvent without being degraded.