Application of Raman spectroscopy to identification and sorting of post-consumer plastics for recycling

• US 6,313,423 B1
• Filed: 07/14/1999
• Issued: 11/06/2001
• Est. Priority Date: 11/04/1996
• Status: Expired due to Term

• Current Assignee: National Recovery Technologies Incorporated (Bulk Handling Systems)
• Original Assignee: National Recovery Technologies Incorporated (Bulk Handling Systems)
• Inventors: Sommer, Edward J., Rich, John T.
• Primary Examiner(s): Walsh, Donald P.
• Assistant Examiner(s): Schlak, Daniel K
• Application Number:
  US09/284,955
• Time in Patent Office: 846 Days
• Field of Search: 209/576, 209/577, 209/578, 209/579, 209/587, 356/301
• US Class Current: 209/587
• CPC Class Codes: B07C 5/342 according to optical properties, e.g. colour according to radiation transmittivity B07C5/3416
• CPC Class Codes: B07C 5/366 during free fall of the articles
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0203 Separating plastics from plastics
• CPC Class Codes: B29B 2017/0279 Optical identification, e.g. cameras or spectroscopy
• CPC Class Codes: G01N 2021/656 Raman microprobe
• CPC Class Codes: G01N 21/65 Raman scattering
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

A high accuracy rapid system for sorting a plurality of waste products by polymer type. The invention involves the application of Raman spectroscopy and complex identification techniques to identify and sort post-consumer plastics for recycling. The invention reads information unique to the molecular structure of the materials to be sorted to identify their chemical compositions and uses rapid high volume sorting techniques to sort them into product streams at commercially viable throughput rates. The system employs a laser diode (20) for irradiating the material sample (10), a spectrograph (50) is used to determine the Raman spectrum of the material sample (10) and a microprocessor based controller (70) is employed to identify the polymer type of the material sample (10).

Claims

1. A method for rapid sorting of a plurality of materials by polymer type, comprising the steps of:

a) conveying at least one of said plurality of materials;

b) irradiating material conveyed with infrared light from a laser to induce distinguishable Raman emission;

c) collecting the light reflected from the said material;

d) performing a spectroscopic analysis of the collected light to determine its Raman spectra;

e) identifying the polymer type of said material by comparing said Raman spectra with a database of spectra of at least one known polymer type; and

f) sorting at least one of said plurality of materials by identified polymer type.

2. A method according to claim 1, wherein step (e) further comprises the step of performing a baseline correction of the Raman spectra to reduce the effect of background noise.

3. A method according to claim 2, wherein step (e) further comprises the use of a vector dot product technique to perform the comparison with the said database of spectra.

4. A method according to claim 2, wherein step (e) further comprises the use of an artificial neural network technique to perform the comparison with the said database of spectra.

5. A method according to claim 1 wherein step (c) further comprises the use of a notch-filter to block substantially all of the collected reflected light having the same wavelength as the irradiating light while allowing substantially all of the remainder of the collected reflected light, including said Raman emission, to pass through.

6. A method according to claim 1 wherein step (a) further comprises conveying said plurality of materials in a serial manner.

7. A system for rapid recognition and sorting of a plurality of materials by polymer type, said system comprising:

a feed conveyor for conveying at least one of said plurality of materials;

a laser for providing irradiating infrared light to induce distinguishable Raman emission;

a probe head, coupled to said laser diode, for irradiating at least a portion of at least one of said conveyed plurality of materials conveyed by the feed conveyor with said irradiating light and inducing said Raman emission from the irradiated material and for collecting reflected light energy from the irradiated material;

a spectrograph, coupled to said probe head, for analyzing the collected reflected light to determine frequency components and outputting data corresponding to said frequency components;

a microprocessor based controller, coupled to said spectrograph, for controlling the spectrograph and for processing the said data corresponding to the frequency components of the collected reflected light to identify the irradiated material as a recognized polymer type and to generate a signal to indicate whether the irradiated material should be separated; and

a sorter, coupled to and controlled by said microprocessor based controller, wherein said sorter separates at least one of said plurality of materials in accordance with said signal.

8. A system according to claim 7 wherein the feed conveyor performs said function in a serial manner.

9. A system according to claim 7, wherein the signal to indicate whether the material should be separated, also indicates the polymer type of the material and wherein said sorter separates at least one of plurality of materials in accordance with said signal.

10. A system according to claim 7, wherein said probe head further comprises a notch-filter for blocking substantially all of the collected reflected light having the same wavelength as the irradiating light while allowing substantially all of the remainder of the collected reflected light, including said Raman emission, to pass through.

11. A system according to claim 7, wherein the spectrograph further comprises:

a spectroscope for separating the frequency components of the collected reflected light; and

a charged-coupled device for receiving said frequency components of the collected reflected light and outputting data corresponding to said frequency components of the collected reflected light to the microprocessor based controller.

12. A system according to claim 11, wherein the microprocessor based controller further comprises:

a database of spectral data for at least one known polymer type wherein the irradiated material is identified by the microprocessor based controller upon a comparison of the data corresponding to the frequency components of its collected reflected light with said database of spectral data for at least one known polymer type.

13. A system according to claim 12 wherein the data corresponding to the frequency components of the collected reflected light used in the microprocessor based controller includes Stokes radiation characteristics for the said Raman emission and said Stokes radiation characteristics are used in identifying the irradiated material.

14. A system according to claim 12 wherein the data corresponding to the frequency components of the collected reflected light used in the microprocessor based controller includes anti-Stokes radiation characteristics for the said Raman emission and said anti-Stokes radiation characteristics are used in identifying the irradiated material.

15. A system for rapid recognition and sorting of a plurality of materials by polymer type, said system comprising:

conveyor means for conveying at least one of said plurality of materials;

light energy source means for providing irradiating infrared light energy to induce distinguishable Raman emission;

probe means, coupled to said light energy source means, for irradiating at least a portion of at least one of said conveyed plurality of materials with said irradiating light energy and inducing said Raman emission from the irradiated material and for collecting reflected light energy from the irradiated material;

spectrograph means, coupled to said probe means, for analyzing the collected reflected light energy to determine frequency components and outputting data corresponding to said frequency components;

recognition processor means, coupled to said spectrograph means, for processing the said data corresponding to the frequency components of the collected reflected light energy to identify the irradiated material as a recognized polymer type and to generate a signal to indicate whether the irradiated material should be separated; and

sorting means, coupled to said recognition processor means, for separating at least one of said plurality of materials in accordance with said signal.

16. A system according to claim 15 wherein the conveyor means performs said function in a serial manner.

17. A system according to claim 15, wherein the signal to indicate whether the material should be separated also indicates the polymer type of the material and wherein said sorting means separates at least one of said plurality of materials in accordance with said signal.

18. A system according to claim 15, wherein said probe means further comprises a notch-filtering means for blocking substantially all of the collected reflected light energy having the same wavelength as the irradiating light energy while allowing substantially all of the remainder of the collected reflected light energy, including said Raman emission, to pass through.

19. A system according to claim 15 wherein the spectrograph means further comprises:

a spectroscope means for separating the frequency components of the collected reflected light energy; and

a charged-coupled device means for receiving said frequency components of the collected reflected light energy and outputting data corresponding to said frequency components of the collected reflected light energy to the recognition processor means.

20. A system according to claim 19, the recognition processor means comprising:

a microprocessor; and

a database of spectral data for at least one known polymer type wherein the irradiated material is identified by the microprocessor based upon a comparison of the data corresponding to the frequency components of its collected reflected light energy with said database of spectral data for at least one known polymer type.

21. A system according to claim 20 wherein the data corresponding to the frequency components of the collected reflected light energy used in the microprocessor includes Stokes radiation characteristics for the said Raman emission and said Stokes radiation characteristics are used in the identifying the material sample.

22. A system according to claim 20 wherein the data corresponding to the frequency components of the collected reflected light energy used in the microprocessor includes anti-Stokes radiation characteristics for the said Raman emission and said anti-Stokes radiation characteristics are used in identifying the material sample.

23. A system for rapid recognition and sorting of a plurality of materials by polymer type, said system comprising:

conveyor means for conveying at least one of said plurality of materials;

light energy source means for providing irradiating infrared light energy to induce distinguishable Raman emission;

probing means comprising a plurality of probe heads, each of said plurality of probe heads coupled to said light energy source means, for irradiating at least a portion of at least one of said conveyed plurality of materials with said irradiating light energy and inducing said Raman emission from at least one of the irradiated materials and for collecting reflected light energy from at least one of the irradiated materials;

spectrograph means, coupled to each of said plurality of probe heads, for analyzing each of the resulting plurality of collected reflected light energies to determine their frequency components and outputting data corresponding to said frequency components,

recognition processor means, coupled to said spectrograph means, for processing the said data corresponding to the frequency components of each of said plurality of collected reflected light energies to identify at least one of the irradiated materials as a recognized polymer type and to generate a signal to indicate whether at least one of the irradiated materials should be separated, and

sorting means, coupled to said recognition processor means, wherein said sorting means separates at least one of said plurality of materials in accordance with said signal.