Electrolytic apparatus and methods for purification of aqueous solutions

• US 6,315,886 B1
• Filed: 12/07/1998
• Issued: 11/13/2001
• Est. Priority Date: 12/07/1998
• Status: Expired due to Fees

• Current Assignee: Zappi Water Purification System Incorporated
• Original Assignee: Electrosynthesis Co., Inc. (RWE AG)
• Inventors: Zappi, Guillermo Daniel, Weinberg, Norman L.
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US09/206,924
• Time in Patent Office: 1,072 Days
• Field of Search: 205/500, 205/701, 205/742, 205/746, 205/758, 204/228.3, 204/228.6, 204/229.2, 204/229.4, 204/230.2, 204/255, 204/256, 204/263, 204/266, 204/270, 204/271, 204/272, 204/275.1, 204/278
• US Class Current: 205/701
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/4672 by electrooxydation
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 1/4676 by electroreduction
• CPC Class Codes: C02F 2001/46128 Bipolar electrodes
• CPC Class Codes: C02F 2001/46133 characterised by the material
• CPC Class Codes: C02F 2001/46157 Perforated or foraminous electrodes
• CPC Class Codes: C02F 2101/163 Nitrates
• CPC Class Codes: C02F 2103/30 from the textile industry
• CPC Class Codes: C02F 2201/4611 Fluid flow
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/46155 Heating or cooling
• CPC Class Codes: C02F 2201/46195 Cells containing solid electrolyte
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C02F 2305/026 Fenton's reagent

Abstract

Electropurification of contaminated aqueous media, such as ground water and wastewater from industrial manufacturing facilities like paper mills, food processing plants and textile mills, is readily purified, decolorized and sterilized by improved, more economic open configuration electrolysis cell designs, which may be divided or undivided, allowing connection as monopolar or bipolar cells. When coupled with very narrow capillary gap electrodes more economic operation particular when treating solutions of relatively low conductivity is assured. The novel cell design is also useful in the electrosynthesis of chemicals, such as hypochlorite bleaches and other oxygenated species.

Claims

1. An open configuration electrolysis cell, which comprises at least one anode and at least one cathode as electrodes positioned in an electrolyzer zone, said electrodes spaced from one another, said electrolysis cell excluding a cell housing intended for retaining an aqueous electrolyte solution in said electrolyzer zone.

2. The electrolysis cell of claim 1 wherein said open configuration is characterized by controlled leakage.

3. The electrolysis cell of claim 1 wherein said electrodes are connected in a monopolar configuration.

4. The electrolysis cell of claim 1 wherein said electrodes are connected in a bipolar configuration.

5. The electrolysis cell of claim 1 which is a Swiss roll cell.

6. The electrolysis cell of claim 1 including means for continuously collecting modified aqueous electrolyte solution descending from said electrolyzer zone.

7. The electrolysis cell of claim 1 including means for regulating residency time comprising pumping means, control valve means or a combination of pumping means and control valve means.

8. The electrolysis cell of claim 1, including means for uniform distribution of contaminated aqueous electrolyte solution over the electrodes.

9. The electrolysis cell of claim 1 wherein said electrodes are substantially parallel and positioned in a generally horizontal plane.

10. The electrolysis cell of claim 1 wherein said electrodes are substantially parallel and positioned in a generally vertical plane.

11. The electrolysis cell of claim 1 wherein said anodes are electrocatalytic for producing reactive oxygen species.

12. The electrolysis cell of claim 11 wherein the electrocatalytic anodes comprise a member selected from the group consisting of noble metal, tin oxide, lead dioxide, substoichiometric titanium oxide and doped diamond.

13. The electrolysis cell of claim 1 wherein said cathodes are electrocatalytic for nitrate destruction.

14. The electrolysis cell of claim 1 wherein said cathodes are gas diffusion cathodes suitable for reduction of oxygen to water or peroxide.

15. The electrolysis cell of claim 1 which is an undivided electrochemical cell.

16. The electrolysis cell of claim 1 including a cell divider forming anolyte and catholyte compartments.

17. The electrolysis cell of claim 16 wherein said cell divider is a diaphragm, microporous separator, ion exchange membrane or a bipolar membrane.

18. The electrolysis cell of claim 1 including ion exchange particulates, beads or solid polymer electrolyte positioned in said interelectrode gaps.

19. The electrolysis cell of claim 1 wherein the inter-electrode gap is from nearly about zero to about 2.0 mm.

20. The electrolysis cell of claim 19 including electrically insulating spacers positioned between electrodes wherein the thickness of said spacers determines the width of the interelectrode gap.

21. The electrolysis cell of claim 1 including at least one sensor selected from the group consisting of pH, UV light, visible light conductivity, hydrogen and chlorine.

22. The electrolysis cell of claim 1, including at least one power supply selected from the group consisting of a DC power supply, AC power supply, pulsed power supply and battery power supply.

23. The electrolysis cell of claim 1 wherein at least one of said electrodes comprises a high surface area.

24. The electrochemical cell of claim 1 which is also a hypochlorite generator.

28. The purification system of claim 24, including means for pretreatment of said contaminated aqueous electrolyte solution selected from the group consisting of filtration, pH adjustment and temperature adjustment.

25. A system for purification of aqueous solutions, which comprises:

(i) an open configuration electrolysis cell comprising at least one anode and at least one cathode as electrodes positioned in an electrolyzer zone, said electrodes spaced from one another, said electrolysis cell excluding a cell housing intended for retaining an aqueous electrolyte solution in said electrolyzer zone;

(ii) control valve means for regulating the flow of contaminated aqueous electrolyte solution to said electrodes;

(iii) means for pumping contaminated aqueous electrolyte solution to said electrodes, and

(iv) rectifier means for providing a DC power supply to said electrolysis cell.

26. The purification system of claim 25, including sensor means and computerized means for receiving input from said sensors and providing output for controlling at least one operating condition in said system selected from the group consisting of current density, flow rate of contaminated aqueous solution to said electrolysis cell, temperature and pH of the contaminated aqueous electrolyte solution.

27. The purification system of claim 26, including exhaust means for further handling of electrochemically produced gaseous by-products.

29. A method for electropurification of a contaminated aqueous solution, which comprises the steps of:

(i) providing an open configuration electrolysis cell comprising at least one anode and at least one cathode as electrodes positioned in an electrolyzer zone, said electrodes spaced from one another, said electrolysis cell excluding a cell housing intended for retaining an aqueous electrolyte solution in said electrolyzer zone;

(ii) introducing into the electrolysis cell of (i) a contaminated aqueous electrolyte solution, and

(iii) imposing a voltage across the electrodes of said electrolysis cell to electrolyze the contaminated aqueous solution to modify the contaminants therein.

30. The electropurification method of claim 29 including the step of collecting the modified electrolyte solution from said electrolysis cell.

31. The electropurification method of claim 29 wherein the aqueous electrolyte solution comprises contaminants selected from the group consisting of organic compounds, inorganic compounds, microorganisms, viruses and mixtures thereof.

32. The electropurification method of claim 31 wherein the aqueous electrolyte solution introduced into said electrochemical cell comprises contaminants selected from the group consisting of bacteria, spores, cysts, protozoa, fungi and mixtures thereof.

33. The electropurification method of claim 29 wherein the aqueous electrolyte solution introduced into the electrolysis cell is a textile effluent comprising dyes or other color producing contaminants, and the modified aqueous electrolyte solution recovered from said electrolysis cell is substantially color-free.

34. The electropurification method of claim 29 wherein the contaminated aqueous electrolyte solution is electrolyzed at a temperature ranging from about the freezing point of the contaminated solution to above about ambient temperature.

35. The electropurification method of claim 29 wherein the contaminated aqueous electrolyte solution is electrolyzed at a temperature ranging from about 40°

to about 90°

C.

36. The electropurification method of claim 29 wherein said electrodes of said electrolysis cell are connected in a monopolar configuration.

37. The electropurification method of claim 29 wherein said electrodes of said electrolysis cell are connected in a bipolar configuration.

38. The electropurification method of claim 29 conducted in a batch mode.

39. The electropurification method of claim 29 conducted in a continuous or semi-continuous mode.

40. The electropurification method of claim 29 wherein said electrochemical cell of step (i) is a component part of a portable battery powered water purifier.

41. The electropurification method of claim 29 including the autogenous generation of at least one oxidizing chemical in the contaminated aqueous electrolyte solution.

42. The electropurification method of claim 29 including the generation of a chemical agent in the contaminated aqueous electrolyte solution selected from the group consisting of hydrogen peroxide, ozone, oxygen, hydroxyl radical, hypochlorite ion, chlorine and mixtures thereof.

43. The electropurification method of claim 29 wherein electrolysis is conducted without the introduction of a current carrier to the aqueous electrolyte solution.

44. The electropurification method of claim 29 wherein electrolysis is conducted with the introduction of a current carrier to the aqueous electrolyte solution in an amount sufficient to enhance the destruction of contaminants.

45. The electropurification method of claim 44 wherein the current carrier is an alkali metal or a quaternary ammonium salt selected from the group consisting of chloride, phosphate and sulfate.

46. The electropurification method of claim 29 including the step of adding sufficient salt to the contaminated aqueous electrolyte solution to provide an active halogen residue in the purified water.

47. The electropurification method of claim 29 wherein the contaminated aqueous electrolyte solution is sufficiently modified to produce potable water.