Method for controlling snails using dialkyl diallyl ammonium polymers

• US 6,315,910 B2
• Filed: 03/03/1999
• Issued: 11/13/2001
• Est. Priority Date: 03/11/1998
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Calgon Carbon Corporation (Kuraray Company Limited)
• Inventors: Dicksa, James K., Farmerie, James E.
• Primary Examiner(s): Simmons, David A.
• Assistant Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US09/261,791
• Publication Number:
  US 20010013496A1
• Time in Patent Office: 986 Days
• Field of Search: 210/698, 210/701, 210/755, 210/764, 210/749, 514/642
• US Class Current: 210/755
• CPC Class Codes: A01K 67/0331 Snails A01K67/0333 takes precedence
• CPC Class Codes: A01N 33/12 Quaternary ammonium compounds
• CPC Class Codes: C02F 1/50 by addition or application of a germicide or by oligodynamic treatment C02F1/4606, C02F1/467, C02F1/76 take precedence
• CPC Class Codes: Y10S 210/931 Zebra mussel mitigation or treatment

Abstract

A method for controlling snails in aqueous systems which involves treating aqueous systems which contain snails or which are prone to snail infestation with an effective amount of a water-soluble dialkyl diallyl quaternary ammonium polymer (polyquat) is disclosed. A preferred polymer is a poly(quaternary ammonium) compound having a recurring structure (DMDAAX⁻) resulting from the polymerization of monomeric dimethyl diallyl ammonium X⁻, wherein X⁻ is any suitable anion.

Claims

1. A method for controlling snails in an aqueous waste water biological treatment system, comprising adding to said waste water biological treatment system an effective amount of a water soluble polymer consisting of dialkyl diallyl quaternary ammonium monomers.

2. The method of claim 1, wherein said control includes one or more members selected from the group consisting of killing snails, inhibiting snail growth, preventing snail growth, inhibiting development of snail eggs, inhibiting hatching of snail eggs, and controlling the fouling potential of snails.

3. The method of claim 1, wherein said aqueous system contains snails or is prone to growth of snails.

4. The method of claim 1, wherein said waste water treatment system uses nitrifying bacteria to reduce biochemical oxygen demand, and where said water soluble polymer does not affect said nitrifying bacteria, yet kills any snails present and inhibits the development and hatching of snail eggs.

5. The method of claim 1, wherein said snails are adult snails, snail eggs, or both, and wherein said snails are submerged, partially submerged or intermittently submerged in the water of the aqueous system being treated.

6. The method of claim 1, wherein at least one of said monomers is dimethyl diallyl ammonium X⁻

, wherein X⁻

is any suitable counterion.

7. The method of claim 6, wherein said counterion is selected from the group consisting of fluoride, bromide, chloride, hydroxide, nitrate, acetate, hydrogen sulfate and primary phosphates.

8. The method of claim 6, wherein said counterion is chloride.

9. The method of claim 1, wherein more than one polymer is added to said aqueous system.

10. The method of claim 1, wherein said effective amount is between about 0.1 and 2000 parts per million, based on total weight of active polymer and the total weight of the water in the aqueous system being treated.

11. The method of claim 1, wherein said polymer is added daily for a period of between about one and two weeks, in an amount between about 1 and 100 parts per million, based on total weight of active polymer and the total weight of the water in the aqueous system being treated.