Electrode containing a polymeric binder material, method of formation thereof and electrochemical cell

• US 6,316,142 B1
• Filed: 03/31/1999
• Issued: 11/13/2001
• Est. Priority Date: 03/31/1999
• Status: Expired due to Term

• Current Assignee: IMRA America Incorporated (Aisin Corp.)
• Original Assignee: IMRA America Incorporated (Aisin Corp.)
• Inventors: Wang, Liya, Delnick, Frank M., Iwamoto, Alan, Hu, Zhendong
• Primary Examiner(s): CHANEY, CAROL DIANE
• Application Number:
  US09/281,922
• Time in Patent Office: 958 Days
• Field of Search: 429/217, 296/231, 296/235
• US Class Current: 429/217
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/054 Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
• CPC Class Codes: H01M 4/0404 by coating on electrode collectors
• CPC Class Codes: H01M 4/0435 Rolling or calendering
• CPC Class Codes: H01M 4/621 Binders
• CPC Class Codes: H01M 4/622 being polymers
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49112 including laminating of indefinite length material
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

Provided are methods of forming an electrode suitable for use in an electrochemical cell, and novel electrodes which can be formed therefrom. The methods involve the steps of: (a) forming an electrode slurry from components comprising a solvent, a polymeric binder material and a solid electrode material, wherein the polymeric binder material is formed by modifying a polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule; (b) coating the electrode slurry on a substrate; and (c) evaporating the solvent. Also provided are electrochemical cells which include the inventive electrodes. The invention has particular applicability to the manufacture of nonaqueous electrochemical power supplies.

Claims

1. A method of forming an electrode suitable for use in an electrochemical cell, comprising the steps of:

(a) forming an electrode slurry from components comprising a solvent, a polymeric binder material and a solid electrode material, wherein the polymeric binder material is formed by modifying a polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule;

(b) coating the electrode slurry on a substrate; and

(c) evaporating the solvent.

2. The method according to claim 1, wherein the components forming the electrode slurry further comprise a conductive additive.

3. The method according to claim 2, wherein the conductive additive is a carbon-containing conductive material.

4. The method according to claim 1, wherein the electrode is a cathode, and the solid electrode material is selected from the group consisting of manganese oxide, lithiated manganese oxides, lithiated cobalt oxides, lithiated vanadium oxides, lithiated nickel oxides, mixed oxides of two or more of manganese, cobalt, vanadium and nickel, sulfides of iron, cobalt, molybdenum and titanium, and carbon monofluoride.

5. The method according to claim 1, wherein the electrode is an anode, and the solid electrode material is selected from the group consisting of lithium intercalating materials, intermetallic alloys of lithium, transition metal oxides and sulfides.

6. The method according to claim 1, wherein the solvent is selected from the group consisting of toluene, xylene, 1,1,1-trichloroethane, cyclohexane, methyl cyclohexane, ethyl cyclohexane, methyl isobutyl ketone, n-methyl pyrrolidone, tetrahydronaphthalene, chlorinated hydrocarbons and mixtures thereof.

7. The method according to claim 6, wherein the solvent further comprises ethyl acetate, n-butyl acetate or ethyl methyl ketone.

8. The method according to claim 6, wherein the components of the electrode slurry further comprise an ester or an alcohol solvent diluent, and the diluent is evaporated with the solvent in step (c).

9. The method according to claim 1, further comprising subjecting the electrode to a pressing or rolling treatment after step (c).

10. The method according to claim 1, wherein the electrode slurry is coated on the substrates by electrostatic coating, dip coating, spray coating, roll coating, doctor blade, gravure coating, or screen printing.

11. The method according to claim 1, wherein the substrate is a current collector.

12. An electrode suitable for use in an electrochemical cell, comprising a substrate and a coating on the substrate, the coating comprising a polymeric binder material and a solid electrode material, wherein the polymeric binder material is formed by modifying a is polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule.

13. The electrode according to claim 12, wherein the coating further comprises a conductive additive.

14. The electrode according to claim 13 wherein the conductive additive is a carbon-containing conductive material.

15. The electrode according to claim 12, wherein the electrode is a cathode, and the solid electrode material is selected from the group consisting of manganese oxide, lithiated manganese oxides, lithiated cobalt oxides, lithiated vanadium oxides, lithiated nickel oxides, mixed oxides of two or more of manganese, cobalt, vanadium and nickel, sulfides of iron, cobalt, molybdenum and titanium, and carbon monofluoride.

16. The electrode according to claim 12, wherein the electrode is an anode, and the solid electrode material is selected from the group consisting of lithium intercalating materials, intermetallic alloys of lithium, transition metal oxides and sulfides.

17. The electrode according to claim 12, wherein the substrate is a current collector.

18. An electrochemical cell, comprising:

an anode, comprising an anode coating on a first current collector, the anode coating comprising a polymeric binder material and a solid anode material, wherein the polymeric binder material is formed by modifying a polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule;

a cathode, comprising a cathode coating on a second current collector, the cathode coating comprising a polymeric binder material and a solid cathode material, wherein the polymeric binder material is formed by modifying a polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule; and

an electrolyte providing a conducting medium between said anode and said cathode.

19. The electrochemical cell according to claim 18, further comprising a separator interposed between the anode and cathode.

20. The electrochemical cell according to claim 19, wherein the electrolyte is a liquid contained within the pores of the separator.

21. The electrochemical cell according to claim 18, further comprising one or more additional anodes and one or more additional cathodes.

22. The electrochemical cell according to claim 18, wherein the anode and cathode further comprise a seal surrounding the anode coating and cathode coating, respectively, wherein the seal comprises a polymeric material formed by modifying a polyolefin with at least one unsaturated polycarboxylic acid or an anhydride of the acid, chlorinating the modified polyolefin and partially crosslinking carboxyl groups or acid anhydride groups on the chlorinated, modified polyolefin with an epoxy group of a compound which has at least two epoxy groups per molecule.