Strengthened, light weight wallboard and method and apparatus for making the same

• US 6,319,312 B1
• Filed: 12/23/1999
• Issued: 11/20/2001
• Est. Priority Date: 11/18/1998
• Status: Expired due to Fees

• Current Assignee: Innovative Technologies Enterprises Corporation
• Original Assignee: Advanced Construction Materials Corporation
• Inventors: Luongo, Joseph S.
• Primary Examiner(s): GREEN, ANTHONY J
• Application Number:
  US09/471,448
• Time in Patent Office: 698 Days
• Field of Search: 106/672, 106/675, 106/680, 106/677, 106/778, 106/779, 106/783, 106/DIG.2, 156/39, 156/45, 156/346, 524/5, 524/423, 428/292.7, 428/312.4, 428/703
• US Class Current: 106/675
• CPC Class Codes: B28B 11/24 for curing, setting or hardening processes for influencing or modifying the setting or hardening ability of mortars, concrete or artificial stone compositions, in general C04B40/00
• CPC Class Codes: B28B 15/00 General arrangement or layout of plant ; Industrial outlines or plant installations
• CPC Class Codes: B28B 19/0092 to webs, sheets or the like, e.g. of paper, cardboard
• CPC Class Codes: B28B 23/0087 Lightweight aggregates for making lightweight articles
• CPC Class Codes: B29C 67/245 for making articles of indefinite length
• CPC Class Codes: B32B 29/00 Layered products comprising a layer of paper or cardboard
• CPC Class Codes: C04B 14/18 Perlite
• CPC Class Codes: C04B 14/185 expanded
• CPC Class Codes: C04B 14/365 Gypsum synthetic gypsum C04B18/0445, C04B18/064
• CPC Class Codes: C04B 2111/00612 as one or more layers of a layered structure
• CPC Class Codes: C04B 2111/0062 Gypsum-paper board like materials
• CPC Class Codes: C04B 2111/28 Fire resistance, i.e. materials resistant to accidental fires or high temperatures
• CPC Class Codes: C04B 22/0013 Boron compounds
• CPC Class Codes: C04B 24/2623 Polyvinylalcohols; Polyvinylacetates
• CPC Class Codes: C04B 24/2641 Polyacrylates; Polymethacrylates
• CPC Class Codes: C04B 24/2682 Halogen containing polymers, e.g. PVC
• CPC Class Codes: C04B 24/282 Polyurethanes; Polyisocyanates
• CPC Class Codes: C04B 24/38 Polysaccharides or derivatives thereof C04B24/243 takes precedence
• CPC Class Codes: C04B 26/02 Macromolecular compounds
• CPC Class Codes: C04B 28/14 containing calcium sulfate cements gypsum-paper plates E04C
• CPC Class Codes: C04B 40/0028 : Aspects relating to the mixing step of the mortar preparation
• CPC Class Codes: C04B 40/0263 : Hardening promoted by a rise in temperature C04B40/024 takes precedence
• CPC Class Codes: C08K 2003/3045 : Sulfates
• CPC Class Codes: C08K 3/30 : Sulfur-, selenium- or tellurium-containing compounds
• CPC Class Codes: C08K 7/22 : Expanded, porous or hollow particles
• CPC Class Codes: C08L 75/04 : Polyurethanes
• CPC Class Codes: E04C 2/043 : of plaster E04C2/049 takes precedence
• CPC Class Codes: Y10S 106/02 : Perlite
• CPC Class Codes: Y10T 428/249926 : Including paper layer
• CPC Class Codes: Y10T 428/249968 : Of hydraulic-setting material

Abstract

A novel wallboard composition is disclosed comprising a unique combination of synthetic binders selected for their ability to establish a strengthened permanent bond in the final dry state for use in a wallboard composition comprising primarily gypsum, and in a wallboard composition comprising an expanded mineral such as Perlite which largely reduces the amount of gypsum over current gypsum wallboard formulations, thus reducing the weight while maintaining the strength of the wallboard structure. In a preferred embodiment, the lightweight, strengthened wallboard of the present invention also comprises an optional covering veneer that is applied to the top ply of the face paper to provide increased strength, moisture resistance, and fire retardency, and the back paper top ply is treated to provide increased flexural strength. Additionally, this invention relates to the unique manufacturing process to produce the wallboard composition of the present invention in order to create a lightweight, strengthened, moisture resistant, and fire retardant wallboard used to cover walls and ceilings in construction applications. Still further, this invention relates to the apparatus for manufacturing the wallboard composition of the present invention, including a method and apparatus for economically converting a standard gypsum wallboard manufacturing facility into a facility for manufacturing wallboard of the present invention.

Claims

1. A slurry composition suitable for use in the manufacture of construction grade wallboard comprising:

expanded perlite present at about 0.5% up to about 47.5% by weight of the total wet weight of the slurry, said expanded perlite being water-permeable;

calcium sulfate present at about 5% up to about 60% by weight of the total wet weight of the slurry; and

a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water.

2. The composition of claim 1, wherein said vinyl acetate emulsion is present at about 0.001% to about 40% by weight of the total wet weight of the slurry.

3. The composition of claim 1, where said polyvinyl alcohol is present in said vinyl acetate emulsion at about 0.10% to about 30% by weight of the total weight of the emulsion.

4. The composition of claim 1, wherein said polyvinyl alcohol is about 80% to about 100% hydrolyzed.

5. A slurry composition suitable for use in the manufacture of construction grade wallboard comprising:

a dry powder mineral substrate selected from the group of minerals consisting of calcium sulfate, perlite, and combinations thereof; and

a synthetic binder comprising a vinyl acetate emulsion, starch, and a boron source.

6. The composition of claim 5, wherein said starch is selected from the group consisting of corn starch, dent corn starch, oxidized starch, waxy oxidized starch, dextrin, and white-canary dextrin.

7. The composition of claim 5, wherein said boron source is selected from the group consisting of borate and boric acid.

8. The composition of claim 5, wherein said boron source is selected from the group consisting of sodium tetraborate pentahydrate and sodium tetraborate decahydrate.

9. The composition of claim 5, wherein said vinyl acetate emulsion is present at about 0.001% to about 40% by weight of the total wet weight of the slurry.

10. The composition of claim 5, wherein said starch is present at about 0.001% to about 15% by weight of the total wet weight of the slurry.

11. The composition of claim 10, wherein said starch is present at about 0.353% to about 10% by weight of the total wet weight of the slurry.

12. The composition of claim 5, wherein said boron source is present at about 0.001% to about 10% by weight of the total wet weight of the slurry.

13. The composition of claim 12, wherein said boron source is present at about 0.01% to about 2.5% by weight of the total wet weight of the slurry.

14. The composition of claim 5, wherein said vinyl acetate emulsion comprises a water-soluble organic polymer selected from the group consisting of vinyl acetate, polyvinyl alcohol, partially hydrolyzed polyvinyl alcohol, a derivative of polyvinyl acetate with polyvinyl alcohol, and combinations thereof.

15. A wallboard composition comprising:

a mineral selected from the group consisting of calcium sulfate, perlite, and combinations thereof;

a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water; and

paper cover sheets sandwiching said mineral and said vinyl acetate emulsion therebetween, said paper cover sheets formed from a virgin paper pulp comprising fibers having a length of at least one inch.

16. A wallboard composition comprising:

a mineral selected from the group consisting of calcium sulfate, perlite, and combinations thereof;

a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water; and

paper cover sheets sandwiching said mineral and said vinyl acetate emulsion therebetween, said paper cover sheets further comprising a fire retardant agent.

17. The composition of claim 16, wherein said fire retardant agent comprises an agent selected from the group consisting of boric acid, zinc borate, sulfamates, diammonium phosphate, nitrogen compounds, antimony oxide, silica, titanium oxide, zircon, and combinations thereof.

18. The composition of claim 17, wherein said fire retardant agent is present at about 0.15% to about 3% by weight of the finished wallboard.

19. A method of manufacturing a construction grade wallboard product comprising the steps of:

forming a mixture by adding a mineral selected from the group consisting of calcium sulfate, perlite, and combinations thereof, to a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water;

combining said mixture with a suitable amount of water;

gradually preparing a slurry by mixing and stirring said mixture and said water to form said slurry;

enveloping said slurry between two paper cover sheets to form a wet board; and

drying said wet board at a temperature in the range of 75°

C. to 325°

C.

20. The method of claim 19, further comprising the step of:

applying heat to said wet after said enveloping step and prior to said drying step.

21. The method of claim 19, further comprising the step of:

adding starch and borate to said vinyl acetate emulsion prior to mixing said vinyl acetate emulsion with said mineral.

22. The method of claim 21, in which said vinyl acetate emulsion is present in the amount of about 0.001% to about 40% by weight of the total wet weight of the slurry.

23. The method of claim 22, in which said starch is selected from the group consisting of corn starch, dent corn starch, oxidized starch, waxy oxidized starch, dextrin, white-canary dextrin, and combinations thereof.

24. The method of claim 22, in which said starch is present in the amount of about 0.001% to about 15% by weight of the total wet weight of the slurry.

25. The method of claim 24, in which said starch is present in the amount of about 0.353% to about 8% by weight of the total wet weight of the slurry.

26. The method of claim 22, in which said borate is selected from the group consisting of sodium tetraborate pentahydrate and sodium tetraborate decahydrate.

27. The method of claim 22, in which said borate is present in the amount of about 0.001% to about 10% by weight of the total wet weight of the slurry.

28. The method of claim 27, in which said borate is present in the amount of about 0.01% to about 2.5% by weight of the total wet weight of the slurry.

29. A slurry composition suitable for use in the manufacture of construction grade wallboard, said slurry composition, when hardened, forming a rigid core situated between two paper cover sheets, said slurry composition comprising:

a dry powder mineral substrate selected from the group of minerals consisting of calcium sulfate, perlite, and combinations thereof; and

a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water.

30. The composition of claim 29, wherein said vinyl acetate emulsion is present at about 0.001% to about 40% by weight of the total wet weight of the slurry.

31. The composition of claim 29, wherein said polyvinyl alcohol is present in said vinyl acetate emulsion at about 0.10% to about 30% by weight of the total weight of the emulsion.

32. The composition of claim 29, wherein said polyvinyl alcohol is about 80% to about 100% hyrdrolyzed.

33. A wallboard composition comprising:

a mineral selected from the group consisting of calcium sulfate, perlite, and combinations thereof;

a vinyl acetate emulsion comprising a homogeneous blend of suspended polyvinyl acetate particles in polyvinyl alcohol and water; and

paper cover sheets sandwiching said mineral and said vinyl acetate emulsion therebetween.

34. A wallboard composition comprising:

a mineral selected from the group consisting of calcium sulfate, perlite, and combinations thereof;

a synthetic binder comprising a vinyl acetate emulsion, starch, and a boron source; and

paper cover sheets sandwiching said mineral and said vinyl acetate emulsion therebetween.