Method and apparatus for testing the integrity of filtering membranes

• US 6,324,898 B1
• Filed: 12/21/1999
• Issued: 12/04/2001
• Est. Priority Date: 12/21/1999
• Status: Expired due to Fees

• Current Assignee: Zenon Environmental Incorporated (Veolia Environnement SA)
• Original Assignee: Zenon Environmental Incorporated (Veolia Environnement SA)
• Inventors: Janson, Arnold, Cote, Pierre, Adams, Nicholas
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): CYGAN, MICHAEL T
• Application Number:
  US09/468,779
• Time in Patent Office: 714 Days
• Field of Search: 73/38, 210/85, 210/90, 210/93
• US Class Current: 73/38
• CPC Class Codes: B01D 65/102 Detection of leaks in membranes
• CPC Class Codes: G01N 15/0826 and measuring fluid flow rate, i.e. permeation rate or pressure change
• CPC Class Codes: G01N 2015/086 of films, membranes or pellicules

Abstract

An improvement to an outside/in hollow fiber membrane filtration system includes a source of suction on the lumens of the membranes or pressure on the outside of the membranes operable without producing permeate and an air collector to collect any air that passes from the outside of the membranes to their lumens during an integrity test. A method for testing the integrity of filtering membranes involves exposing a first side of the membranes to air while a second side of the membranes remains exposed to water. A transmembrane pressure forces air through defects of concern in the membranes. Air that passes through a set of membranes is collected and its amount measured and compared to an acceptable amount of air to indicate whether there is a defect in the set of membranes. Preferably, air is collected individually from a plurality of membrane units in a filtration train and the amounts so collected compared to indicate if one of the membrane units is defective.

Claims

1. A method of testing the integrity of membranes used to filter a liquid feed applied to a first side of the membranes to produce a liquid permeate at a second side of the membranes comprising the steps of:

a) providing a membrane unit to be tested;

(b) providing an air collection vessel in fluid communication with the second side of the membranes of the membrane unit;

(c) stopping filtration through the membrane unit;

(d) exposing the first side of the membranes in the membrane unit to air;

(e) retaining liquid permeate at least between the second side of the membranes and the air collection vessel;

(f) creating a transmembrane pressure from the first side of the membranes to the second side of the membranes for a selected period of time, the transmembrane pressure being sufficient to pass air into the liquid permeate between the second side of the membranes and the air collection vessel through a potential defect of concern in the membranes but not sufficient to exceed the bubble point of a membranes without defects;

(g) separating air which passes through the membrane unit during at least a part of step (f) above from the retained liquid permeate and collecting the separated air in the air collection vessel;

(h) measuring the volume of air collected in step (g) above; and

,

(i) interpreting whether the measured volume of air indicates that there is a defect in the membranes of the membrane unit.

2. The method of claim 1 wherein the air is applied to a feed side of hollow fiber membranes normally operated in an O/I mode.

3. The method of claim 2 wherein the membranes have asymmetrical pores which widen towards the lumens of the membranes.

4. The method of claim 1 wherein the membranes are normally immersed during filtration in an open tank and operated in an O/I mode, the first side of the membranes is exposed to air by draining the tank and the transmembrane pressure is applied by applying a suction to the retained liquid permeate.

5. The method of claim 4 wherein the step of exposing the first side of the membranes to air by draining the tank coincides with a time in a filtration cycle at which the tank is drained to deconcentrate its contents where the tank is drained to deconcentrate its contents is done at least as frequently as the membranes are tested.

6. The method of claim 4 wherein the step of exposing the first side of the membranes to air by draining the tank coincides with a time in a filtration cycle at which the tank is drained to clean the membranes, where such cleaning is done at least as frequently as the membranes are tested.

7. The method of claim 4 wherein the air collection vessel is located at the top of the membrane unit or at a high point in a pipe connected to the membrane unit such that air entrained in the retained liquid permeate will collect in the air collection vessel.

8. The method of claim 7 wherein the air collection vessel has a valve which allows air to be released from the air collection vessel at a pressure above atmospheric and further comprising the step of discharging any air in the air collection vessel and filling the air collection vessel with liquid permeate prior to step (f) by backwashing the membrane unit through the pipe.

9. The method of claim 1 further comprising the step of discharging any air in the air collection vessel and filling the air collection vessel with liquid permeate prior to step iv.

10. In a filtration system comprising;

(a) a tank for holding water to be filtered;

(b) an inlet for feed water into the tank;

(c) membranes normally immersed during permeation, the outsides of the membranes in communication with the water in the tank;

(d) a liquid permeate pump in fluid communication with a permeate collection pipe in fluid communication with the inside of the membranes operable to apply a suction to liquid permeate in the permeate collection pipe and thereby create a transmembrane pressure across the membranes for removing a filtered permeate from the tank; and

,

(e) an outlet for retentate from the tank;

the improvement comprising,

(i) a recycle loop having a loop inlet in communication with the discharge side of the permeate pump, a loop outlet in communication with the inlet side of the permeate pump and an open tank in communication with the loop inlet and loop outlet wherein the permeate pump is operable within the recycle loop to produce a source of suction on liquid permeate in the permeate collection pipe without producing permeate to produce a suction relative to atmospheric pressure greater than the bubble point of a defect in the membranes; and

(ii) an air collector in fluid communication with a high point in the permeate collection pipe and operable to collect and release air that passes from the outside of the set of membranes to the permeate collection pipe and which permits the volume of air collected to be measured,

wherein the set of membranes is chosen to produce a membrane unit of such a size that a defect of interest is distinguishable from diffusion of air through the pores of the membranes in the membrane unit.

11. The system of claim 10 having a single permeate pump operable in a recycle loop connected to a plurality of membrane units and a plurality of air collectors, at least one air collector associated with each membrane unit.

12. A method of testing the integrity of membranes used to filter a liquid feed applied to a first side of the membranes to produce a liquid permeate at a second side of the membranes comprising the steps of:

(a) dividing the membranes into one or more membrane units, each membrane unit being of such a size that a defect of interest is distinguishable from diffusion of air through the pores of the membranes in the membrane unit;

(b) for each membrane unit, providing an air collection vessel in fluid communication with the second side of the membranes; and

,

(c) for each membrane unit to be tested,

i) stopping filtration through the membrane unit;

ii) exposing the first side of the membranes in the membrane unit to air;

iii) retaining liquid permeate at least between the second side of the membranes and the air collection vessel;

iv) creating a transmembrane pressure from the first side of the membranes to the second side of the membranes for a selected period of time, the transmembrane pressure being sufficient to pass air into the liquid permeate between the second side of the membranes and the air collection vessel through a potential defect of concern in the membranes but not sufficient to exceed the bubble point of a membranes without defects,

v) separating air which passes through the membrane unit during at least a part of step c) iv) above from the retained liquid permeate and collecting the separated air in the air collection vessel;

vi) measuring the volume of air collected in step b) v) above; and

,

vii) interpreting whether the measured volume of air indicates that there is a defect in the membranes of the membrane unit,

wherein air is collected individually from a plurality of membrane units all subjected simultaneously to the same transmembrane pressure, and the step of interpreting whether the measured volume of air from a first membrane unit indicates that there is a defect in the first membrane unit includes comparing the measured volume of air from the first membrane unit to a measured volume of air from another membrane unit while the pressure of the liquid permeate in fluid communication with the air collection vessel of the first membrane unit is equilibrated with the pressure of the liquid permeate in fluid communication with the air collection vessel of the other membrane unit.

13. A method of testing the integrity of membranes used to filter a liquid feed applied to a first side of the membranes to produce a liquid permeate at a second side of the membranes comprising the steps of:

a) providing a membrane unit to be tested;

(b) providing an air collection vessel in fluid communication with the second side of the membranes of the membrane unit;

(c) stopping permeation through the membrane unit;

(d) exposing the first side of the membranes in the membrane unit to air;

(e) retaining liquid permeate at least between the second side of the membranes and the air collection vessel;

(f) creating a transmembrane pressure from the first side of the membranes to the second side of the membranes for a selected period of time, the transmembrane pressure being sufficient to pass air into the liquid permeate between the second side of the membranes and the air collection vessel through a potential defect of concern in the membranes but not sufficient to exceed the bubble point of a membranes without defects;

(g) re-applying feed to the first side of the membranes and creating a transmembrane pressure from the first side of the membranes to the second side of the membranes for a selected period of time, the transmembrane pressure being sufficient to pass permeated feed into the retained liquid permeate;

(h) separating air which passes through the membrane unit during at least a part of steps (f) and (g) above from the retained liquid permeate and collecting the separated air in the air collection vessel;

(i) measuring the volume of air collected in step (h) above; and

,

(j) interpreting whether the measured volume of air indicates that there is a defect in the membranes of the membrane unit.

14. The method of claim 13 wherein the membranes are normally immersed during filtration in an open tank and operated in an O/I mode, the first side of the membranes is exposed to air by draining the tank and the transmembrane pressure is applied by applying a suction to the liquid permeate.

15. The method of claim 13 further comprising the step of discharging any air in the air collection vessel and filling the air collection vessel with liquid permeate prior to step (f).