Dispersions containing a polyurethane and a radiation-hardenable prepolymer

• US 6,335,397 B1
• Filed: 10/15/1999
• Issued: 01/01/2002
• Est. Priority Date: 04/17/1997
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Kokel, Nicolas, Menzel, Klaus, Reich, Wolfgang
• Primary Examiner(s): NILAND, PATRICK DENNIS
• Application Number:
  US09/403,006
• Time in Patent Office: 809 Days
• Field of Search: 524/507, 524/591, 524/839, 524/840, 524/457, 525/123, 525/455
• US Class Current: 524/507
• CPC Class Codes: C08L 2205/04 containing interpenetrating networks
• CPC Class Codes: C08L 2666/14 Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
• CPC Class Codes: C08L 75/04 Polyurethanes
• CPC Class Codes: C09D 175/04 Polyurethanes
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds

Abstract

Aqueous dispersions which are essentially free from protective colloids or emulsifiers, comprise, in dispersed form,

A. a polyurethane (A) comprising hydrophilic groups, which bring about the water-dispersibility of the polyurethane, this polyurethane (A) being essentially free from C—C double bonds, and

B. a prepolymer having a content of from 0.1 to 1 mol of free-radically polymerizable C—C double bonds per 100 g of prepolymer.

Claims

1. A water-dispersible polyurethane, which is essentially free from protective colloids or emulsifiers, comprising in dispersed form:

A) a polyurethane (A) comprising hydrophilic groups, which effect the water-dispersibility of the polyurethane, the polyurethane (A) being essentially free from C—

C double bonds; and

B) a non self-dispersible radiation-curable prepolymer having a content of from 0.1 to 1 mol of free-radically polymerizable C—

C double bonds per 100 g of prepolymer;

wherein the polyurethane (A) and the prepolymer (B) are present a form comprising a molecular mixture and not in the form of a dispersion, containing in one discontinuous phase only the polyurethane (A) and in a further discontinuous phase the prepolymer (B).

2. The water-dispersible polyurethane of claim 1, wherein the weight ratio of polyurethane (A) to prepolymer (B) is from 0.3:

1 to 99;

1.

3. The water-dispersible polyurethane of claim 1, wherein the polyurethane (A) is made from monomers, comprising:

a) diisocyanates having 4 to 30 carbons;

b) diols of which

b1) from 10 to 100 mol-%, based on the overall amount of the diols (b), have a molecular weight of from 500 to 5000; and

b2) from 0 to 90 mol-%, based on the overall amount of the diols (b), have a molecular weight of from 60 to 500 g/mol;

c) monomers, other than the monomers (a) and (b), which have at least one isocyanate group or at least one group which is reactive toward isocyanate groups, and which additionally carry at least one hydrophilic group or a potentially hydrophilic group, so as to effect the water-dispersibility of the polyurethanes;

d) optionally, further polyfunctional compounds, other than the monomers (a) to (c), which have reactive groups which are alcoholic hydroxyls, primary or secondary aminos or isocyanate groups; and

e) optionally, monofunctional compounds, other than the monomers (a) to (d), which have a reactive group which is an alcoholic hydroxyl, a primary or secondary amino or an isocyanate group.

4. The water-dispersible polyurethane of claim 3, where the proportion of the monomers (a) among the monomers (a) to (e) is from 20 to 70% by weight.

5. The water-dispersible polyurethane of claim 1, having a viscosity measured at 23°

C. and at a shear rate of 250 s<sup>−

1</sup>, of from 10 to 1000 mPas.

6. A process for preparing the water-dispersible polyurethane of claim 1, which comprises:

a) preparing a melt or solution containing the prepolymer (B) and the polyurethane (A) or a prepolymer thereof; and

b) dispersing the melt or solution, prepared in step a), in water.

7. The process of claim 6, wherein the polyurethane prepolymer is reacted during or after dispersion to form the polyurethane.

8. A method of coating articles comprising wood, paper, textile, metal or plastic, which comprises:

a) applying a film of the water-dispersible polyurethane of claim 1, to said articles; and

b) exposing the film produced in step a) to light.

9. The method of claim 8, wherein the film produced in step a) is dried before step b).

10. A coated article, comprising wood, paper, textile, metal or plastic produced by the method of claim 8.