Triboelectric device

• US 6,335,856 B1
• Filed: 04/05/1999
• Issued: 01/01/2002
• Est. Priority Date: 03/05/1999
• Status: Expired due to Fees

• Current Assignee: Etat Francais Represented By The Delegue General Pour L'Armement
• Original Assignee: Etat Francais Represente Par Le Delegue General Pour L'Armement
• Inventors: Meyer, Luc P., Boisrayon, Michel P., Scarpitta, Alain A.
• Primary Examiner(s): Leja, Ronald W.
• Application Number:
  US09/285,692
• Time in Patent Office: 1,002 Days
• Field of Search: 307/400, 298/86, 310/337, 310/363, 310/345, 310/311, 310/320-322, 136/254, 361/230
• US Class Current: 361/230
• CPC Class Codes: H10N 30/802 Drive or control circuitry or methods for piezoelectric or electrostrictive devices not otherwise provided for
• CPC Class Codes: H10N 30/852 Composite materials, e.g. having 1-3 or 2-2 type connectivity
• CPC Class Codes: H10N 30/857 Macromolecular compositions

Abstract

A triboelectric device includes a voltage source, a polarizing amplifier, and electrodes to apply a polarizing voltage to a first material of the device. The electrodes are not fixed to the first material, allowing relative rubbing displacement between the electrodes and the first material. Preferably, a conductive second material, such as petrolatum, is provided between the first material and the electrodes. Such a device can have its properties change while in service. To accommodate this, the voltage source preferably provides an adjustable polarization voltage. The triboelectric device is useful as a transducer, and particularly useful as a hydrophone used in sonar antenna, as its mode type can be changed in the field during service to correct spurious signals or interferring noises.

Claims

1. A triboelectric device comprising means for applying a polarizing voltage to a first material which is a polymer or dielectric organic substance, said means comprising a voltage source, a polarizing amplifier and electrodes which are not fixed to the first material, allowing relative rubbing displacement between the electrodes and the first material, wherein the electrodes are of the comb type.

2. The triboelectric device according the claim 1, wherein the polymer or the dielectric organic substance is chosen from the following group including polystyrenes, polysulfones, polycarbonates, polypropylenes, polyethylene, polyethylene terephthalates, polyphenylene oxides, polyacrylate esters, polymethacrylate esters, polyvinyl chlorides, polyvinylidenes, acrylonitrile polymers, methacrylonitrile polymers, polyvinyl acetates, celluloids, celluose acetates, polyvinyl pyrrolidones, cellulosic polymers, phenol formaldehydes, phenol-furfural resins, soluble polymers of polyimide, epoxy resins, polymerisable resins, natural rubbers, synthetic rubbers, silicone resins, methanol or bone glues, polystyrols, gum-lacs, copolymers of vinylidene and trifluoroethlene.

3. The triboelectric device according to claim 1, wherein said means for applying a polarizing voltage to a first material comprises means for adjusting a value of the polarizing voltage.

4. The triboelectric device according to claim 3, wherein the polarizing voltage is continuous.

5. The triboelectric device according to claim 3, wherein the polarizing voltage is alternating.

6. The triboelectric device according to claim 1, wherein the first material comprises particles which are selected from piezoelectric, slightly piezoelectric or non-piezoelectric particles.

7. The triboelectric device according to claim 6, wherein a size of the particles is between 5×

10<sup>−

9</sup> m and 5×

10<sup>−

3</sup> m.

8. The triboelectric device according to claim 6, wherein the particles have a same size.

9. The triboelectric device according to claim 6, wherein the particles are wholly or partly chosen from a biological material or piezoelectric plastic material, or from microcrystals.

10. The triboelectric device according to claim 9, wherein the biological material is chosen from oligosaccharides, homopolysaccharides, heteropolysaccharides, glycosaminoglycans, proteoglycans, terpenes, steriods, amino acids, oligopeptides and polypeptides, proteins, nucleotides or nucleic acids, urea or natural silk.

11. The triboelectric device according to claim 9, wherein the particles are, wholly or partly, microcrystals or fibres of ammonium tartrate, potassium tartrate, ethylene diamine tartrate, dipotassium tartrate, sodium chlorate, sodium bromate, nickel sulfate hexahydrate, iodic acid, benzophenone, hydrated or dehydrated lithium gallate, polyvinyl difluoridine, polyvinyl chloride, copolymer of vinyl acetate and vinylidene cyanide, copolymer of vinylidene and trifluoroethylene, polyvinyl flouride, nylon, polyacrylonitrile, polyparaxylene, polybichloromethyloextane, aromatic polymide, polysulfone, cyanoethlyicellulose, monosaccharides, disaccharides, brushite, monetite or salts of carboxylix acid.

12. The triboelectric device according to claim 9, wherein the particles are prepolarized in a through-thickness direction.

13. A triboelectric device comprising means for applying a polarizing voltage to a first material which is a polymer or dielectric organic substance, said means comprising a voltage source, a polarizing amplifier and electrodes which are not fixed to the first material, allowing relative rubbing displacement between the electrodes and the first material, wherein petrolatum is interposed between the electrodes and the first material.

14. The triboelectic device according the claim 13, wherein the polymer or the dielectric organic substance is chosen from the following group including polystyrenes, polysulfones, polycarbonates, polypropylenes, polyethylene, polyethylene terephthalates, polyphenylene oxides, polyacrylate esters, polymethacrylate esters, polyvinyl chlorides, polyvinylidenes, acrylonitrile polymers, methacrylonitrile polymers, polyvinyl acetates, celluloids, cellulose acetates, polyvinyl pyrrolidones, cellulosic polymers, phenol formaldehydes, phenol-furfural resins, soluble polymers of polyimide, epoxy resins, polymersible-resins, natural rubbers, synthetic rubbers, silicone resins, methanol or bone glues, polystyrols, gum-lacs, copolymers of vinylidene and trifluoroethlene.

15. The triboelectric device according to claim 13, wherein said means for applying a polarizing voltage to a first material comprises means for adjusting a value of the polarizing voltage.

16. The triboelectric device according to claim 13, wherein the first material comprises particles which are selected from piezoelectric, slightly piezoelectric or non-piezoelectric particles.

17. The triboelectric device according to claim 16, wherein a size of the particles is between 5×

10<sup>−

9</sup> m and 5×

10<sup>−

3</sup> m.

18. The triboelectric device according to claim 16, wherein the particles have a same size.

19. The triboelectric device according to claim 16, wherein the particles are wholly or partly chosen from a biological material or piezoelectric plastic material, or from microcrystals.

20. The triboelectric device according to claim 19, wherein the biological material is chosen from oligosaccharides, homopolysaccharides, heteropolysaccharides, glycosaminoglycans, proteoglycans, terpenes, steroids, amino acids, oligopeptides and polypeptides, proteins, nucleotides or nucleic acids, urea or natural silk.

21. The triboelectric device according to claim 19, wherein the particles are, wholly or partly, microcrystals or fibres of ammonium tartrate, potassium tartrate, ethylene diamine tartrate, dipotassium tartrate, sodium chlorate, sodium bromate, nickel sulfate hexahydrate, iodic acid, benzophenone, hydrated or dehydrated lithium gallate, polyvinyl difluoridine, polyvinyl chloride, copolymer of vinyl acetate and vinylidene cyanide, copolymer of vinylidene and trifluoroethylene, polyvinyl flouride, nylon, polyacrylonitrile, polyparaxylene, polybichloromethyloextane, aromatic polymide, polysulfone, cyanoethlyicellulose, monosaccharides, disaccharides, brushite, monetite or salts of carboxylix acid.

22. The triboelectric device according to claim 19, wherein the particles are prepolarized in a through-thickness direction.