Extrusion coating process for making protective and decorative films

• US 6,336,988 B1
• Filed: 08/06/1997
• Issued: 01/08/2002
• Est. Priority Date: 06/07/1995
• Status: Expired due to Fees

• Current Assignee: Avery Dennison Corporation
• Original Assignee: Avery Dennison Corporation
• Inventors: Truog, Keith L., Roys, John E., Young, Frederick, Enlow, Howard H., McCready, Russell J.
• Primary Examiner(s): Ball, Michael W.
• Assistant Examiner(s): Piazza, Gladys
• Application Number:
  US08/793,836
• Time in Patent Office: 1,616 Days
• Field of Search: 156/239, 156/238, 156/240, 156/244.11, 156/244.16, 156/244.24, 156/19, 156/209, 264/211.12, 264/284
• US Class Current: 156/238
• CPC Class Codes: B05D 1/286 using a temporary backing to which the coating has been applied
• CPC Class Codes: B05D 7/53 Base coat plus clear coat type
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/15 incorporating preformed parts or layers, e.g. extrusion moulding around inserts
• CPC Class Codes: B29D 7/01 Films or sheets
• CPC Class Codes: B29K 2027/16 PVDF, i.e. polyvinylidene fluoride
• CPC Class Codes: B29K 2995/0022 Bright, glossy or shiny surface
• CPC Class Codes: B32B 2307/4026 within the layer by addition of a colorant, e.g. pigments, dyes
• CPC Class Codes: B32B 2307/406 Bright, glossy, shiny surface
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2327/00 Polyvinylhalogenides
• CPC Class Codes: B32B 2327/12 containing fluorine
• CPC Class Codes: B32B 2333/04 Polymers of esters
• CPC Class Codes: B32B 2451/00 Decorative or ornamental articles wall paper B32B2607/02
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/308 comprising acrylic (co)polymers
• CPC Class Codes: B32B 37/153 at least one layer is extruded and immediately laminated while in semi-molten state
• CPC Class Codes: C08J 2327/16 Homopolymers or copolymers of vinylidene fluoride
• CPC Class Codes: C08J 5/18 : Manufacture of films or sheets
• CPC Class Codes: Y10T 428/24628 : Nonplanar uniform thickness material
• CPC Class Codes: Y10T 428/24901 : including coloring matter
• CPC Class Codes: Y10T 428/31909 : Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 : Monoolefin polymer

Abstract

A process for making a protective and decorative surfacing film comprises extrusion coating a solid polymeric material from an extruder die to form an optically clear first layer of uniform film thickness on a smooth surface of a carrier sheet traveling continuously past the extruder die opening. The extrusion coated first layer is immediately cooled on the carrier sheet to harden it, followed by applying a pigmented second layer in thin film form to the first layer to form a composite paint coat in which the first and second layers are bonded to each other. The composite paint coat is then transferred to a supportive backing sheet or substrate panel, after which the carrier sheet is separated from the paint coat, to expose the outer surface of the first layer as a high gloss surface with a high distinctness-of-image, providing a transparent protective outer coat for the underlying pigmented second layer. The pigmented second layer can be solvent cast and dried or extruded and hardened as a separate coating on the extrusion coated first layer. Alternatively, the second layer can be formed with the first layer as a coextrusion which is extrusion coated onto the smooth surface of the release coated carrier sheet that travels past the extruder die.

Claims

1. A process for making a protective and decorative sheet material for use as a surfacing film for automotive body panels, comprising extrusion coating a solid polymeric extruded material from an extrusion die onto a smooth surface of a carrier sheet traveling continuously past the extrusion die to form a first layer comprising a weatherable thermoplastic and thermoformable optically clear coat of uniform thickness on the carrier sheet, in which a starting material for the clear coat comprises a blended fluoropolymer and acrylic resinous material;

immediately cooling the clear coat on the traveling carrier sheet to harden the clear coat;

applying a pigmented second layer of a thermoplastic and thermoformable polymeric material in thin film form to the first layer and hardening the second layer to form a composite paint coat in which the first and second layers are bonded to each other while supported by the carrier sheet; and

separating the carrier sheet from the composite paint coat to expose an outer surface of the first layer as a transparent protective outer coat for the pigmented second layer, in which the starting material for the clear coat is made by first melt blending the acrylic resin an a UV stabilizer followed by melt blending the fluoropolymer resin with the blended UV stabilizer/acrylic resin, and in which the first layer is extrusion coat from the extrusion die so that heat generated within the extruded material is controlled to a temperature below the gel formation temperature of the polymers contained in the extruded material.

2. The process according to claim 1 in which the second layer is solvent cast on the layer.

3. The process according to claim 1 including applying a thermoformable polymeric supportive sheet to the pigmented second layer side of the composite paint coat to form a thermoformable laminate.

4. The process according to claim 1 in which the solid polymeric material comprising the extrusion coated first layer is a blend of polyvinylidene fluoride (PVDF) and acrylic resins.

5. The process according to claim 1 in which the first layer is extrusion coated onto the carrier sheet at a line speed greater than about 50 feet/minute.

6. The process according to claim 1 in which the outer surface of the extruded clear coat has a distinctness-of-image in excess of 60.

7. The process according to claim 1 in which the clear coat layer and pigmented second layer comprise a blend of a PVDF copolymer and an acrylic resin.

8. The process according to claim 1 including coextruding a thermoformable supportive backing sheet and a primer coat as a coextrusion and thereafter bonding the pigmented second layer side of the composite paint coat to the primer coat of the coextrusion.

9. The process according to claim 8 including extruding the clear coat at a temperature above 350°

F. followed the clear coat to contact with a chill roll having a temperature of less than about 80°

F., to harden the clear coat within an elapsed time of less than about three to four seconds.

10. The process according to claim 1 in which the clear coat comprises a blend of polyvinylidene fluoride and an acrylic material having a Tg of at least 65°

C.

11. The process according to claim 10 in which the polyvinylidene fluoride/acrylic weight ration is from about 50/50 to about 70/30 based on the total solids of these materials present in the clear coat.

12. The process according to claim 1 in which the extruded material is subjected to an extruder rotational rate of less than about 50 rpm, producing a line speed greater than about 100 ft/min.

13. The process according to claim 12 in which the extruded material is subjected to an extrusion pressure below about 1,000 psi.

14. The process according to claim 13 in which a starting material for the extrusion step comprises pellets made by extrusion of starting material components carried out at temperatures below the gel formation temperature of each of the components being formed into pellets.

15. The process according to claim 1 in which a starting material for the extrusion step comprises pellets made by extrusion of starting material components carried out at temperatures below the gel formation temperatures of each of the components being formed into pellets.

16. The process according to claim 1 in which the extrusion temperature is below about 450°

F.

17. The process according to claim 16 in which the extruded material is subjected to an extruder rotational rate of less than about 55 rpm.

18. The process according to claim 1 in which the extruded material comprises a thermoformable film having less than about five defects based on the C-charting standard of measurement.

19. The process according to claim 1 in which a starting material for the extrusion step comprises pellets made by first extruding the acrylic component into pellet form followed by extruding the fluoropolymer component from a pellet form to the extruded clear coat.

20. The process according to claim 1 in which a starting material for the extrusion step is in briquette form produced by compressing the starting material polymers in dry powder form.

21. The process according to claim 6 in which the outer surface of the extruded clear coat has a 20°

gloss of in excess of 75.

22. The process according to claim 8 in which the coextruded backing sheet and primer coat comprise ABS and an acrylic size coat, or a polyolefin polymer and a CPO size coat.

23. The process according to claim 1 in which the extruded first layer comprises a blend of a PVDF copolymer and an acrylic resin.

24. The process according to claim 4 in which a starting material for the extrusion step comprises pellets made by first blending the acrylic component and a UV stabilizer in a first extrusion step, followed by blending the PVDF with the extruded acrylic/UV stabilizer material in a second extrusion step.

25. The process according to claim 24 in which the extrusion temperature of the first extrusion step is higher than the extrusion temperature of the second extrusion step.

26. The process according to claim 4 in which compatibility of the PVDF and acrylic components is enhanced by closely matching their respective melt viscosities.

27. The process according to claim 1 in which the extruded clear coating is extruded in a twin screw extruder.

28. The process according to claim 1 in which the starting material is pre-dried prior to the extrusion step.

29. A process for making a protective and decorative sheet material for use as a surfacing film for automotive body panels, comprising extrusion coating a solid polymeric extruded material from an extrusion die onto a smooth surface of a carrier sheet traveling continuously past the extrusion die to form a first layer comprising a weatherable thermoplastic and thermoformable optically clear coat of uniform thickness on the carrier sheet, in which a starting material for the clear coat comprises a blend of polyvinylidene fluoride (PVDF) and acrylic resins;

cooling the extrusion coated first layer to harden the first layer on the carrier sheet;

applying a pigmented second layer of a thermoplastic and thermoformable polymeric material in thin film form to the hardened first layer to form a composite paint coat in which the first and second layers are bonded to each other while supported by the carrier sheet;

laminating a thermoformable polymeric supportive sheet to the second layer side of the composite paint coat to form a laminate; and

separating the carrier sheet from the composite paint coat to expose an outer surface of the first layer as a transparent protective outer coat for the pigmented second layer of the laminate, in which the starting material for the clear coat is made by first melt blending the acrylic resin and a UV stabilizer followed by melt blending the PVDF with the blended UV stabilizer/acrylic resin, and in which the first layer is extrusion coated from the extrusion die so that heat generated within the extruded material is controlled to a temperature below the gel formation temperature of the polymers contained in the extruded material.

30. The process according to claim 29 in which the second layer is solvent cast on the first layer.

31. The process according to claim 29 including applying the supportive sheet to the pigmented second layer side of the laminate prior to separating the carrier sheet from the laminate.

32. The process according to claim 29 in which the first layer is extrusion coated onto the carrier sheet at a line speed greater than 50 feet/minute.

33. The process according to claim 29 in which the outer surface of the extruded clear coat has a distinctness-of-image in excess of 60.

34. The process according to claim 29 in which the first layer and pigmented second layer comprise a blend of a PVDF copolymer and an acrylic resin.

35. The process according to claim 29 in which the supporting sheet is coextruded with a primer coat prior to applying the primer coat side of the coextrusion to the pigmented second layer side of the laminate.

36. The process according to claim 29 in which the extruded material is subjected to an extruder rotational rate of less than about 50 rpm, producing a line speed of more than about 100 ft/min.

37. The process according to claim 36 in which the extruded material is subjected to an extrusion pressure below about 1,000 psi.

38. The process according to claim 37 in which a starting material for the extrusion step comprises pellets made by extrusion of starting material components carried out at temperatures below the gel formation temperature of each of the components being formed into pellets.

39. The process according to claim 29 in which a starting material for the extrusion step comprises pellets made by extrusion of starting material components carried out at temperatures below the gel formation temperature of each of the components being formed into pellets.

40. The process according to claim 29 in which the extrusion temperature is below about 450°

F.

41. The process according to claim 40 in which the extruded material is subjected to an extruder rotational rate of less than about 50 rpm.

42. The process according to claim 29 in which the extruded material comprises a thermoformable film having less than about five defects based on the C-charting standard of measurement.

43. The process according to claim 33 in which the outer surface of the extruded clear coat has a 20°

gloss in excess of 75.

44. The process according to claim 43 in which the laminate is capable of retaining a DOI in excess of 60 and a 20°

gloss in excess of 75 following thermoforming of the laminate into a three-dimensionally contoured shape.

45. The process according to claim 29 in which the extruded clear coat is extruded in a twin screw extruder.

46. The process according to claim 29 in which the starting material is pre-dried prior to the extrusion step.

47. A process for making a protective and decorative sheet material for use as a surfacing film for automotive body panels, comprising extrusion coating a polymeric material by solventless extrusion from an extrusion die onto a smooth surface of a carrier sheet traveling continuously past the extrusion die to form a first layer comprising a weatherable thermoplastic and thermoformable optically clear coat of uniform thickness on the carrier sheet, in which the starting material for the extruded polymeric material comprises a blend of polyvinylidene fluoride (PVDF) and acrylic resins, immediately cooling the clear coat on the traveling carrier sheet by contact with a smooth surfaced chill roll to harden the clear coat, including extruding the clear coat at a temperature above 350°

F. followed by exposing the clear coat to contact with the chill roll at a chill roll temperature of less than about 80°

F. to harden the clear coat within an elapsed time of less than about three to four seconds;

applying a pigmented second layer of a thermoplastic and thermoformable polymeric material in thin film form to the first layer and hardening the second layer to form a composite paint coat in which the first and second layers are bonded to each other while supported by the carrier sheet; and

separating the carrier sheet from the composite paint coat to expose an outer surface of the protective first layer as a transparent protective outer coat for the pigmented second layer, in which the starting material is made by first melt blending the acrylic resin and a UV stabilizer, followed by melt blending the PVDF with the blended UV/acrylic resin, and in which the first layer is extrusion coated from the extrusion die so that heat generated within the extruded material is controlled to a temperature below the gel formation temperature of the polymers contained in the extruded material.

48. The process according to claim 47 in which the second layer is solvent cast on the first layer.

49. The process according to claim 48 in which the extruded material is subjected to an extruder rotational rate of less than about 50 rpm, producing a line speed greater than 100 ft/min.

50. The process according to claim 48 in which the outer surface of the extruded clear coat has a distinctness-of-image in excess of 60 and a 20°

gloss in excess of 75.

51. The process according to claim 47 in which a starting material for the extrusion step comprises pellets made by first extruding the acrylic component into pellet form followed by extruding the PVDF component from a pellet form to the extruded clear coat.

52. The process according to claim 47 in which a starting material for the extrusion step comprises pellets made by extrusion of starting material components carried out at temperatures below the gel formation temperatures of each of the components being formed into pellets.

53. The process according to claim 47 in which the extruded clear coat has a T_g of at least 65°

C.

54. The process according to claim 47 in which the extruded clear coat comprises a thermoformable film having less than about five defects based on the C-charting standard of measurement.

55. The process according to claim 47 in which a starting material for the extrusion step comprising pellets made by first blending the acrylic component and a UV stabilizer in a first extrusion step, followed by blending the PVDF with the extruded acrylic/UV stabilizer material in a second extrusion step.

56. The process according to claim 47 in which the starting material is pre-dried prior to the extrusion step.

57. A process for making a protective and decorative sheet material for use as a surfacing film for automotive body panels, comprising:

extruding a polymeric material to form a clear coat comprising a solid transparent pre-dried blended polyvinylidene fluoride (PVDF) and acrylic resinous material, in which the PVDF/acrylic weight ration is from about 50/50 to about 70/30 based on the total solids of these materials present in the clear coat;

forming the extruded material as a continuous extrusion-coated film directed form an extruder die onto a smooth surface of a flexible heat-resistant temporary carrier sheet traveling continuously past the extrude die to form a first layer comprising a weatherable thermoplastic and thermoformable optically clear coat of uniform film thickness on the carrier sheet, in which heat generated within the extruded material is controlled to a temperature below the gel formation temperature of the polymers contained in the polymeric material, where said temperature is about 450°

F., and in which said polymeric material is subjected to an extrusion pressure below about 2000 psi;

passing the traveling carrier sheet around a rotating chill roll operated at a temperature below about 85°

F. and directing the extruded material on the carrier sheet into pressure contact with the rotating chill roll for immediately cooling the clear coat while supported on the traveling carrier sheet to thereby form a hardened clear coat releasably bonded to the temporary carrier sheet;

applying a pigmented second layer of a thermoplastic and thermoformable polymeric material in thin film form to the first layer and hardening the second layer to form a composite paint coat in which the first and second layers are bonded to each other while supported by the carrier sheet; and

separating the carrier sheet from the composite paint coat to expose an outer surface of the first layer as a transparent protective outer coat for the pigmented second layer, the clear coat having an average of less than about five defects per 8 sq. ft. of extruded film.

58. The process according to claim 57 in which the resinous components of the polymeric material are pre-dried prior to melt blending them to form a starting material.

59. The process according to claim 57 in which the clear coat is extruded at an extruder rotation rate of less than about 50 rpm.

60. The process according to claim 57 in which the clear coat on the composite paint coat has a distinctness-of-image of at least 60.