Optical memory device

• US 6,337,117 B1
• Filed: 06/30/1999
• Issued: 01/08/2002
• Est. Priority Date: 07/01/1998
• Status: Expired due to Fees

• Current Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Inventors: Asami, Harumi, Dushkin, Ceco, Yamaguchi, Yukio, Saita, Soichiro, Maenosono, Shinya
• Primary Examiner(s): MULVANEY, ELIZABETH EVANS
• Application Number:
  US09/343,526
• Time in Patent Office: 923 Days
• Field of Search: 428/64.1, 428/64.2, 428/64.4, 428/143, 428/147, 428/148, 428/690, 428/913, 430/495.1, 430/945
• US Class Current: 428/64.1
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: G11B 2007/24304 group 2 or 12 elements (e.g. Be, Ca, Mg, Zn, Cd)
• CPC Class Codes: G11B 2007/24314 group 15 elements (e.g. Sb, Bi)
• CPC Class Codes: G11B 2007/24316 group 16 elements (i.e. chalcogenides, Se, Te)
• CPC Class Codes: G11B 2007/2432 Oxygen
• CPC Class Codes: G11B 2007/24322 Nitrogen
• CPC Class Codes: G11B 2007/24328 Carbon
• CPC Class Codes: G11B 7/00455 involving reflectivity, absorption or colour changes
• CPC Class Codes: G11B 7/0052 involving reflectivity, absorption or colour changes
• CPC Class Codes: G11B 7/0055 Erasing G11B7/006, G11B7/0065 take precedence
• CPC Class Codes: G11B 7/24 Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the arrangement of information on the carrier G11B7/007
• CPC Class Codes: G11B 7/243 comprising inorganic materials only, e.g. ablative layers
• CPC Class Codes: G11B 7/2531 comprising glass
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 430/146 Laser beam
• CPC Class Codes: Y10T 428/21 Circular sheet or circular blank
• CPC Class Codes: Y10T 428/24405 Polymer or resin [e.g., natural or synthetic rubber, etc.]
• CPC Class Codes: Y10T 428/24413 Metal or metal compound

Abstract

An optical memory device comprising a luminous material capable of increasing and/or memorizing a photoluminescence intensity (hereinafter referred to as a “luminous intensity”) as a function of irradiation energy of excitation light. And the luminous material comprises nanoparticles, diameters of which are smaller than Bohr radius of the luminous material so that excitons generated in the nanoparticles undergo quantum containment state in which the electrons and holes are individually contained as a result of irradiation with excitation light.

Claims

1. An optical memory device comprising:

a luminous material comprising luminous nanoparticles which increase and/or memorize a photoluminescence intensity as a function of irradiation energy of excitation light wherein an organic compound comprising at least one element selected from the group consisting of P, N, and S is present on at least a portion of the surface of each luminous nanoparticle, and the quantity of the organic compound is 1 to 50 wt. % with respect to the weight of the luminous nanoparticles.

2. The optical memory device of claim 1, wherein the luminous nanoparticles have a diameter which is smaller than the Bohr radius of the luminous material, whereby excitons generated in the nanoparticles undergo quantum containment state in which the electrons and holes are individually contained as a result of irradiation with excitation light.

3. The optical memory device of claim 2, wherein the nanoparticles are covered with a organic compound thin film comprising at least one element selected from the group consisting of P, N, O and S.

4. The optical memory device of claim 2, wherein the nanoparticles are made of CdSe.

5. The optical memory device of claim 2, wherein the nanoparticles are made of CdS.

6. The optical memory device of claim 1, wherein the nanoparticles are distributed in a TDLM thin film coated on a substrate.

7. The optical memory device of claim 1, wherein the luminous material has a time required for increasing luminous intensity of 1×

10<sup>−

12</sup> seconds or more.

8. The optical memory device of claim 1, wherein the luminous material has a rate of increase in luminous intensity of 1.1 times or more than an initial luminous intensity.

9. The optical memory device of claim 1, wherein the luminous material has a time during which luminous intensity is stored at a temperature of 77 K or more of 1 second or more.

10. The optical memory device of claim 1, wherein a mean distance between luminous nanoparticles in a cluster thereof falls in a range whose maximum is ten times 4 the diameter of the nanoparticle.

11. The optical memory device of claim 1, wherein the luminous nanoparticles have a particle size of 0.5 to 100 nm.

12. The optical memory device of claim 1, wherein the luminous nanoparticles comprise inorganic compounds.

13. The optical memory device of claim 1, wherein the luminous nanoparticles comprise organic compounds.

14. The optical memory device of claim 1, wherein the luminous nanoparticles comprise a semiconductor.

15. The optical memory device of claim 1, wherein one or more layers are formed on a solid substrate from a film containing luminous nanoparticles.

16. The optical memory device of claim 15, wherein the film comprises a cluster of luminous nanoparticles and has a thickness greater than the diameter of the luminous nanoparticle but less than 1 mm.

17. The optical memory device of claim 1, further comprising luminous nanoparticles and a photoconductive material, wherein a cluster of the luminous nanoparticles and the photoconductive material are present in close proximity to each other.

18. The optical memory device of claim 1, wherein the luminous intensity can be diminished or erased by radiation, onto the optical memory device, of light whose wavelength differs from that of the excitation light.

19. The optical memory device of claim 1, wherein at least a part of a luminous nanoparticle is formed from a protective layer including an insulating material.

34. An optical disk comprising, as a recording medium, the optical device of claim 1, wherein at least a portion of the surface of each of the luminous nanoparticles which increase, decrease or memorize reflectivity as a function of irradiation time of excitation light or as a function of the dose of excitation light have an organic compound comprising at least one element selected from the group consisting of P, N, and S.

35. The optical disk of claim 34, comprising luminous nanoparticles deposited on at least one side of a solid substrate.

36. The optical disk of claim 34, wherein the luminous material has a time at which reflectivity is diminished of three hours or less.

37. The optical disk of claim 34, wherein the luminous intensity of the luminous material is diminished to 0.9 times or less than an initial luminous intensity.

38. The optical disk of claim 34, wherein the luminous material has a time during which reflectivity is stored at a temperature of 77 K or more of 1 second or more.

39. The optical disk of claim 34, wherein a signal is recorded by reducing reflectivity by radiation of excitation light onto the optical disk, and a recorded signal is reproduced by detecting a variation in reflectivity through use of light whose wavelength is identical with or differs from that of excitation light.

20. A nanoparticle thin film manufacturing method comprising forming on a solid substrate a thin film from nanoparticles capable of increasing, or increasing and memorizing, photoluminescence as a function of irradiation time of excitation light or as a function of the dose of excitation light, wherein

the solid substrate is coated by spin coating a suspension formed by suspending nanoparticles in a solvent, while rotating the solid substrate at a speed of 500 rpm or more for 1 minute or more.

21. The nanoparticle thin film manufacturing method of claim 20, wherein the suspension has a nanoparticle content of 0.001 to 10 g/ml.

22. The nanoparticle thin film manufacturing method of claim 21, wherein the solvent comprises an organic compound.

23. The nanoparticle thin film manufacturing method of claim 22, wherein the quantity of organic compound in the suspension is one-ten-thousandth or more the weight of a nanoparticle.

24. The nanoparticle thin film manufacturing method of claim 20, wherein the nanoparticle thin film is dried in air for 30 minutes or more after spin coating at a temperature ranging from −

20 to 200°

C.

25. The nanoparticle thin film manufacturing method of claim 24, wherein the nanoparticle thin film is further subjected to drying under reduced pressure after having been dried in air.

26. The nanoparticle thin film manufacturing method of claim 25, wherein the nanoparticle thin film is dried in a vacuum of 1×

10⁵ Pa or less at −

20 to 200°

C. for 1 to 24 hours.

27. A nanoparticle thin film manufacturing method of forming on a solid substrate a thin film comprising nanoparticles capable of increasing, or increasing and memorizing, a luminous intensity as a function of irradiation time of excitation light or as a function of the dose of excitation light, wherein

the solid substrate is ink-jet coated with a dispersed solution formed by dispersing nanoparticles in an emulsion whose continuous phase comprises water and whose dispersed phase is an oily phase.

28. The nanoparticle thin film manufacturing method of claim 27, wherein the nanoparticle thin film is dried in air for 30 minutes or more after ink-jet coating at a temperature ranging from −

20 to 200°

C.

29. The photoluminescence erasing method of claim 28, wherein the heat treatment is carried out for a time of from 10⁻

9 seconds to 1 hour.

30. A photoluminescence erasing method, wherein

after the luminous intensity of an optical memory device—

which includes luminous nanoparticles capable of increasing, or increasing and memorizing, a luminous intensity as a function of irradiation time of excitation light or as a function of the dose of excitation light—

has been increased, or increased and memorized, the optical memory device is subjected to heat treatment, thereby diminishing the luminous intensity.

31. The photoluminescence erasing method of claim 30, wherein the heat treatment is carried out at a temperature of 50 to 200°

C.

32. An integrating optical sensor comprising:

a thin film including luminous nanoparticles capable of increasing, or increasing and memorizing, a luminous intensity as a function of irradiation time of excitation light or as a function of the dose of excitation light; and

a mask including a region which is exposed to light to be measured and a region which is not exposed to the light.

33. The integrating optical sensor of claim 32, wherein the excitation light has an intensity of 1 nW/cm² or more.