Hydrogen peroxide disinfectant with increased activity

• US 6,346,279 B1
• Filed: 07/19/1999
• Issued: 02/12/2002
• Est. Priority Date: 12/14/1998
• Status: Expired due to Term

• Current Assignee: Virox Technologies Incorporated
• Original Assignee: Virox Technologies Incorporated
• Inventors: Rochon, Michael J.
• Primary Examiner(s): PAK, JOHN D
• Application Number:
  US09/356,345
• Time in Patent Office: 939 Days
• Field of Search: 424/616, 424/601-606, 424/126, 424/DIG.6, 514/557, 514/558, 514/559, 514/560, 514/574, 514/553, 514/576, 514/709, 514/970, 422/12, 422/28, 504/151
• US Class Current: 424/616
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/22 containing ingredients stabilising the active ingredients
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A61P 31/02 Local antiseptics
• CPC Class Codes: Y10S 424/06 Chelate

Abstract

An acidic aqueous hydrogen peroxid solution is provided, with improved disinfectant activity. Concentrated solutions preferably contain up to about 8% and as-used concentrations contain about 0.5% peroxide. The solution also contains from 0.1 to 5.0% of at least one acid compound, e.g. phosphoric and/or a phosphonate with from 1 to 5 phosphonic acid groups, and from 0.02 to 5% of at least one anionic surfactant. The surfactant is selected from C8 to C16-alkyl aryl sulphonic acids, sulphonated C12 to C22 carboxylic acids, C8 to C22-alkyl diphenyl oxide sulphonic acids, naphthalene sulphonic acids, C8 to C22 alkyl sulphonic acids, and alkali metal and ammonium salts thereof, and alkali metal C8 to C18 alkyl sulphates, and mixtures thereof. Most preferably the solution has an emulsifier, e.g. a salt of an alkylated diphenyl oxide. The solution may also contain corrosion inhibitors and/or lower alcohols.

Claims

1. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, and iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution.

2. A solution according to claim 1 wherein the at least one anionic surfactant is dodecyl benzene sulfonic acid or an alkali metal or ammonium salt thereof.

3. A solution according to claim 1 wherein the solution has a hydrogen peroxide concentration of from 0.05 to 1.0 wt./wt. % of the solution.

4. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) up to about 3 wt./wt. % of at least one emulsifier.

5. A solution according to claim 4 wherein the emulsifier is selected from the group consisting of polyoxyethylene surfactants and hydrotropes.

6. A solution according to claim 5 wherein the hydrotrope is selected from the group consisting of an alkylated sulphonated diphenyl oxide and an alkylated sulphonated diphenyl oxide salt.

7. A solution according to claim 4 wherein the emulsifier is a C8 to C16 alkyl phenoxypolyethoxy ethanol.

8. A solution according to claim 5, containing phosphoric acid, a phosphonate having from 1 to 5 phosphonic acids groups, an alkylphenol alkoxylate, and an alkyated sulfonated diphenyl oxide salt.

9. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) from 0.1 to 10 wt./wt. % of an alcohol comprising one to six carbon atoms.

10. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) from 0.05 to 10.0 wt.wt % of a corrosion inhibitor.

11. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) a non-ionic surfactant selected from the group consisting of alkylated alkoxylate surfactants, alkyl aryl alkoxylate surfactants and mixtures thereof.

12. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) a monocarboxylic acid, a polycarboxylic acid, or mixtures thereof, in a concentration of from about 0.05 to about 4.0 wt./wt. % of the solution.

13. An aqueous solution having a pH from about 1 to about 3 and consisting essentially of i) hydrogen peroxide in a concentration of from 0.05 to about 8.0 wt./wt. % of the solution, ii) at least one phosphorus-based acid selected from the group consisting of phosphoric acid and a mixture of phosphoric acid and phosphonates having 1 to 5 phosphonic acid groups, in a concentration range of from 0.05 to 8.0 wt./wt. % of the solution, iii) at least one anionic surfactant selected from the group consisting of C8 to C16-alkyl aryl sulfonic acids and alkali metal and ammonium salts thereof, in a concentration range of from 0.02 to 5 wt./wt. % of the solution, and (iv) a hydrotrope selected from the group consisting of an alkylated sulfonated diphenyl oxide and an alkylated sulphonated diphenyl oxide salt.

14. A solution according to claim 13 wherein the hydrotrope is a C6 alkylated sulfonated diphenyl oxide salt.