Method for improving the exploitability and processability of guar endosperm and products obtained using said method

• US 6,348,590 B1
• Filed: 05/28/1999
• Issued: 02/19/2002
• Est. Priority Date: 12/23/1996
• Status: Expired due to Fees

• Current Assignee: Ties Karstens
• Original Assignee: Rhodia Acetow AG
• Inventors: Karstens, Ties, Stein, Armin
• Primary Examiner(s): Gitomer, Ralph
• Assistant Examiner(s): Khare, Devesh
• Application Number:
  US09/297,227
• Time in Patent Office: 998 Days
• Field of Search: 536/114, 536/123.1, 536/124, 536/127, 536/128
• US Class Current: 536/114
• CPC Class Codes: A23L 29/238 from seeds, e.g. locust bean gum or guar gum starch A23L29/212; pectin A23L29/231
• CPC Class Codes: A61K 8/737 Galactomannans, e.g. guar; Derivatives thereof
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: C08B 37/0096 Guar, guar gum, guar flour, guaran, i.e. (beta-1,4) linked D-mannose units in the main chain branched with D-galactose units in (alpha-1,6), e.g. from Cyamopsis Tetragonolobus; Derivatives thereof

Abstract

A method for processing guar endosperm in which guar splits are brought into contact with an amount of liquid ammonia at least sufficient to wet the guar splits at a pressure higher than atmospheric pressure and at a temperature of at least 25° C. The remaining available guar split/liquid ammonia system volume is increased in an explosion like manner by reducing the pressure by at least about 5 bars resulting in the sheaths of the guar splits being torn open to result in a product that can be processed more easily, such as by grinding.

Claims

1. A method for processing of guar endosperm to isolate the galactomannan of D-galactose and mannose component (guaran) therefrom, comprising:

providing guar endosperm halves;

bringing the halves into contact with liquid ammonia at an initial pressure, higher than atmospheric pressure, and at a temperature of at least 25°

C., the amount of liquid ammonia being sufficient at least for wetting the surface of the guar endosperm halves; and

increasing the volume available to the system of guar endosperm halves and liquid ammonia explosively by lowering the pressure by at least about 0.5 Mpa (5 bar) to tear open the sheaths of the guar endosperm halves to isolate the guaran.

2. The method of claim 1, wherein the explosive increase in volume is carried out within a time of less than 1 second.

3. The method of claim 1, wherein the guar endosperm halves and the liquid ammonia are brought into contact in pressure equipment and the pressure on the system of guar endosperm halves and liquid ammonia is reduced by transfer into an explosion space having a capacity larger than that of the pressure equipment.

4. The method of claim 1, wherein the initial pressure is adjusted to a value between about 0.5 and 4.6 MPa (5 and 46 bar).

5. The method of claim 3, wherein the temperature in the pressure equipment is adjusted before the explosive increase in volume to a value between about 25°

and 85°

C.

6. The method of claim 1, wherein the initial pressure is lowered by at least about 1 MPa (10 bar).

7. The method of claim 1, wherein at least one part by weight of liquid ammonia is used per part by weight of guar endosperm halves.

8. The method of claim 1, further comprising milling the ammonia-exploded material into guar flour.

9. Ammonia-exploded guar endosperm halves (guar splits), produced by the method of claim 1.

10. The method of claim 1, further comprising treating the exploded material with an extraction agent, so that the guaran goes substantially into solution and the endosperm sheaths remain substantially undissolved, removing the endosperm sheaths and, optionally, recovering the guaran from the guaran solution.

11. The method of claim 10, further comprising using an aqueous extraction agent, especially water.

12. The method of claim 10, wherein the exploded material is treated with the extraction agent at a temperature of about 25°

to 95°

C.

13. The method of claim 10, further comprising removing the endosperm sheaths by filtration or centrifugation.

14. The method of claim 10, further comprising obtaining the guaran by spray drying.