Viscosity stabilization of radiation-curable filled compositions
First Claim
1. A cured three-dimensional article that has been produced by stereolithocradhy and obtained by subjecting a radiation-curable composition to actinic radiation, said composition comprising a mixture of at least one cationically polymerizable compound and/or at least one radical polymerizable compound, at least one filler material, and at least one photoinitiator for caionic and/or radical polymerizations, in which an organic base stabilizer material is brought into contact with said composition in an effective amount to delay or prevent a significant increase in viscosity of the overall composition.
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Abstract
The present invention relates to a process for the production of three-dimensional articles by stereolithography using a radiation-curable composition comprising a mixture of at least one cationically polymerizable compound and/or at least one free radical polymerizable compound, at least one filler material and at least one photoinitiator for cationic and/or radical polymerization. An organic viscosity stabilizer material may be brought into contact with the composition to substantially delay or prevent undesirable viscosity increase and subsequently premature polymerization. A filler material is optionally added to the composition in an effective amount to at least delay or prevent a significant increase in viscosity and polymerization. The process is particularly suitable for stabilizing resins in stereolithography baths. The present invention also relates to a cured articles resulting from said process and a process for manufacturing said radiation-curable compositions and stabilized compositions resulting therefrom.
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Citations
33 Claims
- 1. A cured three-dimensional article that has been produced by stereolithocradhy and obtained by subjecting a radiation-curable composition to actinic radiation, said composition comprising a mixture of at least one cationically polymerizable compound and/or at least one radical polymerizable compound, at least one filler material, and at least one photoinitiator for caionic and/or radical polymerizations, in which an organic base stabilizer material is brought into contact with said composition in an effective amount to delay or prevent a significant increase in viscosity of the overall composition.
- 2. A process for manufacturing a stabilized filled resin composition for stereolithography comprising combining a mixture of at least one cationically polymerizable compound and/or at least one radical polymerizable compound, at least one filler material, at least one photoinitiator for cationic and/or radical polymerization(s) and an organic base stabilizer material in an effective amount to delay or prevent a significant increase in viscosity, in a reaction vessel.
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3. A stabilized radiation-curable composition comprising a mixture of at least one radiation polymerizable compound, at least one filler material, at least one photoinitiator for polymerization and an organic viscosity stabilizer material selected from the group consisting of aryl-N,N′
- -dialkylamines and benzyl-N,N-dialkylamines in an effective amount to delay or prevent a significant increase in viscosity of the overall composition.
- View Dependent Claims (5, 6, 7, 8, 9, 10, 11, 31, 32, 33)
- 4. A stabilized radiation-curable composition comprising a mixture of at least one radiation polymerizable compound, at least one filler material selected from the group consisting of sodium silicate, potassium silicate, calcium silicate, aluminum silicate, aluminum oxide and alumina trihydrate in an amount effective to delay or prevent a significant viscosity increase of the overall composition and at least one photoinitiator for polymerization.
- 16. A stabilized radiation curable composition comprising a mixture of at least one radiation polymerizable compound, at least one inorganic filler which has been surface treated such that that the surface treatment improves the compositional viscosity stability as compared to said mixture with the exception that the filler material has not been surface treated, and at least one photoinitiator for polymerization.
Specification