Alkali metal diffusion barrier layer

• US 6,352,755 B1
• Filed: 09/17/1998
• Issued: 03/05/2002
• Est. Priority Date: 10/04/1994
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Gillery, F. Howard, Finley, James J.
• Primary Examiner(s): Ahmad, Nasser
• Application Number:
  US09/156,730
• Time in Patent Office: 1,265 Days
• Field of Search: 428/426, 428/428, 428/432, 428/433, 428/702, 428/100, 204/192.1, 204/192.12
• US Class Current: 428/100
• CPC Class Codes: C03C 17/245 by deposition from the vapour phase
• CPC Class Codes: C03C 17/2453 Coating containing SnO2
• CPC Class Codes: C03C 17/3411 with at least two coatings of inorganic materials C03C17/36, C03C17/42 take precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3607 Coatings of the type glass/inorganic compound/metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/3655 the multilayer coating containing at least one conducting layer
• CPC Class Codes: C03C 17/3671 specially adapted for use as electrodes
• CPC Class Codes: C03C 2217/212 TiO2
• CPC Class Codes: C03C 2217/22 ZrO2
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2217/445 Organic continuous phases
• CPC Class Codes: C03C 2217/477 Titanium oxide
• CPC Class Codes: C03C 2217/71 Photocatalytic coatings
• CPC Class Codes: C03C 2217/94 Transparent conductive oxide layers [TCO] being part of a multilayer coating
• CPC Class Codes: C03C 2218/156 by magnetron sputtering
• CPC Class Codes: Y10T 428/24017 Hook or barb

Abstract

Amorphous metal oxide barrier layers of titanium oxide, zirconium oxide and zinc/tin oxide are effective as alkali metal ion barrier layers at thicknesses below 180 Angstroms. The amorphous metal oxide barrier layers are most effective when the density of the layer is equal to or greater than 75% of the crystalline density. The barrier layers prevent migration of alkali metal ions such as sodium ions from glass substrates into a medium e.g. electrolyte of a photochromic cell, liquid material of a liquid crystal display device contacting the glass surface and a photocatalytic coating. The properties of the medium, particularly electroconductive metal oxide coatings, are susceptible to deterioration by the presence of sodium ions migrating from the glass.

Claims

1. An article comprising:

a glass substrate having alkali metal ions in a surface;

a medium over and spaced from the surface of the substrate, the medium characterized in that predetermined concentrations of alkali metal ion deteriorates the function of the medium, and

between the surface and the medium a sputtered amorphous layer of a metal oxide having a thickness of less than 180 Angstroms and having a density equal to or greater than 75% of its crystalline density to provide an alkali metal ion barrier layer between the glass substrate and the medium.

2. The article according to claim 1, wherein said layer is zirconium oxide layer having a thickness in the range of 30 to 120 Angstroms.

3. The article according to claim 2, wherein the density of the amorphous zirconium oxide is equal to or greater than 4.2 grams per cubic centimeter using cubic zirconium. oxide, and 4.42 grams per cubic centimeter using baddelyite.

4. The coated article according to claim 3, wherein the zirconium oxide barrier layer has a thickness in the range of 30 to 60 Angstroms.

5. The article according to claim 1, wherein said layer is a titanium oxide layer having a thickness in the range of about 45 to 180 Angstroms.

6. The article according to claim 5, wherein the density of the titanium oxide layer is equal to or greater than 3.2 grams per cubic centimeter.

7. The article according to claim 6, wherein the titanium oxide barrier layer has a thickness in the range of about 90 to 180 Angstroms.

8. The article according to claim 1, wherein the barrier layer is a zinc/tin oxide layer having a thickness in the range of 60 to 120 Angstroms.

9. The article according to claim 8, wherein the zinc/tin oxide layer has a density of 4.8 grams per cubic centimeter.

10. The article according to claim 9, wherein the thickness of the zinc/tin oxide layer is from 90 to 120 Angstroms.

11. The article according to claim 1, wherein the medium is an electroconductive coating selected from the group consisting of indium oxide, tin oxide, indium/tin oxide and zinc/aluminum oxide.

12. The article according to claim 1, wherein the medium is a photocatalytic composition.

13. The article according to claim 12, wherein the medium includes particles of titanium oxide in a silicone binder.

14. The article according to claim 1, wherein the medium is a liquid electrolyte.

15. An article comprising:

a glass substrate having a predetermined transmission at 550 nanometers, an index of refraction and alkali metal ions in a surface;

a medium over and spaced from the surface of the substrate, the medium characterized in that predetermined concentration of alkali metal ion deteriorates the function of the medium, and

between the surface and the medium a sputtered layer of a metal oxide having a thickness less than 180 Angstroms, an index of refraction higher than the index of refraction of the glass substrate and the layer when applied directly on the glass does not lower the transmission of the substrate at 550 nanometers more than 10%.