Thermoplastic moisture cure polyurethanes

• US 6,355,317 B1
• Filed: 06/19/1997
• Issued: 03/12/2002
• Est. Priority Date: 06/19/1997
• Status: Expired due to Term

• Current Assignee: HB Fuller Company
• Original Assignee: H.B. Fuller Licensing & Financing, Inc.
• Inventors: Reid, Kevin J., Jarocz, Jacqueline J., Spinks, Anne E.
• Primary Examiner(s): Loney, Donald J.
• Application Number:
  US08/878,520
• Time in Patent Office: 1,727 Days
• Field of Search: 428/34, 527/861.3, 527/861, 525/123, 525/125, 525/130, 156/109, 528/53, 524/588
• US Class Current: 428/34
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/289 containing silicon
• CPC Class Codes: C08G 18/307 Atmospheric humidity
• CPC Class Codes: C08G 18/423 containing cycloaliphatic groups
• CPC Class Codes: C08G 2170/20 Compositions for hot melt adhesives
• CPC Class Codes: C08G 2190/00 Compositions for sealing or packing joints
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C09D 175/06 from polyesters
• CPC Class Codes: C09J 175/06 from polyesters

Abstract

This invention relates to a one-part thermoplastic moisture cure polyurethane composition, comprising a) at least one polyurethane prepolymer component; and b) at least one thermoplastic component. This composition is especially useful in the window area as a sealant.

Claims

1. An insulating glass unit, comprising:

a) at least one edge assembly;

b) at least two glass panels; and

c) a polyurethane sealant, comprising the reaction product of;

i) a moisture curing polyurethane prepolymer component comprising the reaction product of at least one isocyanate compound and at least one dihydroxy polyol selected from the group consisting of polyester polyols, polyether polyols, polyalkylene polyols and mixtures thereof; and

ii) at least one thermoplastic component;

wherein said sealant is disposed between said edge assembly or assemblies and said glass panel and engages said edge assembly or assemblies and said glass panels.

2. The unit of claim 1 wherein said polyurethane prepolymer component further comprises from about 0.01% to about 2% by weight of said polyurethane prepolymer component of a catalyst.

3. The unit of claim 2 wherein said catalyst is selected from the group consisting of metals, metal salts and amines.

4. The unit of claim 3 wherein said catalyst is selected from the group consisting of:

and mixtures thereof,

where R can be an alkyl group having from 1-4 carbon atoms, R₁ or R₂ can be selected from the group consisting of hygrogen and alkyl groups having from 1-4 carobn atoms and n is an integer ranging from 1-10.

5. The unit of claim 1 wherein said edge assembly comprises a spacer selected from the group consisting of hollow tubes used to provide a fixed air space between the two glass panels and U-channels.

6. The unit of claim 1 wherein said sealant is applied to the spacer by a method selected from the group consisting of the preformed roll method, the hand gunned method, the three sided extrusion method and the coextrusion method.

7. The unit of claim 1 wherein said thermoplastic component comprises at least one compound selected from the group consisting of butyl rubber compounds;

ethylene-propylene rubber compounds;

ethylene vinyl acetate copolymers;

homogeneous, linear or substantially linear interpolymers of ethylene and at least one C₃ to C₂₀ alphaolefin and mixtures thereof.

8. The unit of claim 1 wherein said sealant further comprises a silane adhesion promoter.

9. The unit of claim 1 wherein said sealant further comprises a filler selected from the group consisting of talcs, clays, silicas and treated versions, carbon blacks, micas and mixtures thereof.

10. A one-part thermoplastic moisture cure polyurethane composition, comprising:

a) at least one polyurethane prepolymer component comprising the reaction product of at least one polyisocycanate compound and at least one dihydroxy polyol selected from the group consisting of polyester polyols, polyether polyols, polyalkylene polyols and mixtures thereof;

b) at least one thermoplastic component; and

c) at least one silane adhesion promoter having a boiling point of greater than about 120°

C.;

wherein the one-part polyurethane hot melt composition has primeness adhesion to glass and metal.

11. The composition of claim 10 wherein said composition further comprises from about 0.01% to about 2% by weight of the composition of a catalyst.

12. The composition of claim 11 wherein said catalyst is selected from the group consisting of metals, metal salts, amines and mixtures thereof.

13. The composition of claim 12 wherein said catalyst is selected from the group consisting of:

and mixtures thereof,

where R can be an alkyl group having from 1-4 carbon atoms, R₁ or R₂ can be selected from the group consisting of hydrogen and alkyl groups having from 1-4 carbon atoms and n is an integer ranging from 1-10.

14. The composition of claim 10 wherein said polyurethane prepolymer component comprises the reaction product of at least one polyisocyanate compound and at least one amorphous polyester polyol formed from a diol and a diacid.

15. The composition of claim 14 wherein said diacid has a chain length greater than about 10 carbon atoms.

16. The composition of claim 14 wherein said thermoplastic component comprises at least one thermoplastic rubber compound selected from the group consisting of butyl rubber compounds and ethylene-propylene rubber compounds.

17. The composition of claim 10 wherein said thermoplastic component comprises at least one compound selected from the group consisting of butyl rubber compounds;

ethylene-propylene rubber compounds;

ethylene vinyl acetate copolymers;

homogeneous, linear or substantially linear interpolymers of ethylene and at least one C₃ to C₂₀ alphaolefin and mixtures thereof.

18. The composition of claim 10 wherein said composition further comprises a filler selected from the group consisting of talcs, clays, silicas and treated versions thereof, carbon blacks, micas and mixtures thereof.

19. A sealant, for an insulating glass unit, comprising the composition of claim 10.

20. The composition of claim 10 comprising from about 0.1% to about 5% by weight of said silane adhesion promoter.

21. The composition of claim 10 wherein said silane adhesion promoter is tris-isocyanurate.

22. The composition of claim 10 wherein said dihyroxy polyol is a polyester polyol.

23. A one-part thermoplastic moisture cure polyurethane composition, comprising:

a) at least one polyurethane prepolymer component comprising the reaction product of at least one polyisocyanate compound and at least one dihydroxy polyol which is an amorphous polyester polyol formed from a diol and a diacid; and

b) at least one thermoplastic component selected from the group consisting of butyl rubber compounds;

ethylene propylene rubber compounds;

block copolymers having an A block and a B block wherein said A block is styrene and said B block is selected from the group consisting of butadiene, ethylene/butylene, ethylene/propylene, isoprene; and

mixtures thereof;

wherein said the one-part polyurethane hot melt composition has primerless adhesion to glass and metal.