Waste water treatment method and apparatus

• US 6,358,398 B1
• Filed: 07/25/2000
• Issued: 03/19/2002
• Est. Priority Date: 05/21/1999
• Status: Expired due to Fees

• Current Assignee: Applied Oxidation Technologies, Inc. (Aqua-Pure Ventures, Inc.)
• Original Assignee: Applied Oxidation Technologies, Inc. (Aqua-Pure Ventures, Inc.)
• Inventors: Lambert, Lawrence, Halldorson, Jacob, Kresnyak, Steve
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US09/625,545
• Time in Patent Office: 602 Days
• Field of Search: 205/754, 205/755, 205/756, 205/757, 204/275.1, 204/277, 204/278
• US Class Current: 205/754
• CPC Class Codes: C02F 1/008 Control or steering systems not provided for elsewhere in subclass C02F
• CPC Class Codes: C02F 1/24 by flotation C02F1/465 takes precedence
• CPC Class Codes: C02F 1/46 by electrochemical methods
• CPC Class Codes: C02F 1/4608 using electrical discharges
• CPC Class Codes: C02F 1/46114 Electrodes in particulate form or with conductive and/or non conductive particles between them
• CPC Class Codes: C02F 1/463 by electrocoagulation
• CPC Class Codes: C02F 1/4672 by electrooxydation
• CPC Class Codes: C02F 1/52 by flocculation or precipitation of suspended impurities C02F1/463 takes precedence
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 1/76 with halogens or compounds of halogens C02F1/4674 takes precedence
• CPC Class Codes: C02F 1/766 by means of halogens other than chlorine or of halogenated compounds containing halogen other than chlorine
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2001/46123 Movable electrodes
• CPC Class Codes: C02F 2001/46152 characterised by the shape or form electrodes in particulate form or with conductive or non-conductive particles between them C02F1/46114
• CPC Class Codes: C02F 2103/22 from the processing of animals, e.g. poultry, fish, or parts thereof
• CPC Class Codes: C02F 2201/003 Coaxial constructions, e.g. a cartridge located coaxially within another
• CPC Class Codes: C02F 2201/4612 Controlling or monitoring
• CPC Class Codes: C02F 2201/4613 Inversing polarity
• CPC Class Codes: C02F 2201/4615 Time
• CPC Class Codes: C02F 2201/4617 : DC only
• CPC Class Codes: C02F 2201/46175 : Electrical pulses
• CPC Class Codes: C02F 2201/4619 : Supplying gas to the electrolyte gas diffusion electrodes C02F2001/46166
• CPC Class Codes: C02F 2209/005 : Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/05 : Conductivity or salinity
• CPC Class Codes: C02F 2301/024 : Turbulent
• CPC Class Codes: C02F 2301/066 : Overpressure, high pressure

Abstract

A method for separating contaminants from a aqueous source containing contaminants. In one embodiment, the method involves the use of a high powdered oxidant dissolved within the aqueous system. The gas is dissolved within a reservoir in the aqueous solution and the pressure within the reservoir is controllable. This allows maximum contact of the oxidizing dissolved gas with the contaminant material. Once oxidized, the outlet of the reservoir is adapted to permit hydraulic cavitation. The net effect of the cavitation is to induce a foam formation which foam transports a floc into a separate phase from the aqueous solution. In this manner, the process is effectively a dissolved oxidizing gas mass transfer process. In another embodiment, the process may be augmented by electrocoagulation. This involves the use of an electric cell which is disposed within the reservoir containing the oxidant material. By providing electrodes and exposing the electrodes to a source of current, the contaminants within the aqueous solution are either oxidized or otherwise degraded and this complements the oxidation by the dissolved gaseous oxidant. An apparatus is also disclosed to effect the methods set forth above.

Claims

1. An electrocell for use in electrochemical separating contaminants from an aqueous solution, said reactor having a divergent inlet stage and an inlet suitable for receiving said aqueous solution containing contaminants and an outlet for discharging effluent, said inlet stage diverging in cross-sectional area from said inlet to said outlet;

electrodes in electrical communication with said inlet stage in spaced relation and connectable to a source of power for supplying current to said electrodes;

a plurality of discrete fluidizable metal reaction surfaces freely fluidizable within said inlet stage for electrochemically oxidizing said contaminants in said aqueous solution in the presence of said electrodes to isolate said contaminants.

2. The electrocell as set forth in claim 1, wherein said divergent inlet stage comprises metal and is connectable to said power supply to act as a first electrode of said electrodes.

3. The electrocell as set forth in claim 2, wherein a second electrode of said electrodes comprises an elongate metal member in spaced relation to said first electrode.

4. The electrocell as set forth in claim 3, wherein said electrodes comprise stainless steel.

5. The electrocell as set forth in claim 2, wherein the second electrode of said electrodes comprises a divergent electrode positioned in spaced relation to and within said divergent inlet stage, a narrow end of said divergent electrode positioned in spaced relation to and within said divergent inlet stage, said narrow end of said divergent electrode in spaced relation to said inlet of said divergent stage.

6. The electrocell as set forth in claim 5, wherein the said divergent electrode has a contoured shape for augmenting fluidization of metal reaction surfaces.

7. The electrocell as set forth in claim 1, wherein said electrodes comprise a first electrode and a second electrode in spaced relation with said inlet stage.

8. The electrocell as set forth in claim 1, wherein said discrete fluidizable metal reaction surfaces comprise a member selected from the group comprising:

metal powder, metal balls, metal beads, metal pellets and metal powder.

9. The electrocell as set forth in claim 8, wherein said metal comprises aluminum.

10. A closed system for separating contaminants from an aqueous solution containing contaminants, comprising:

an oxidizing stage for oxidizing contaminants in an aqueous solution including;

a closed container containing oxidant and having an inlet in fluid communication with a source of aqueous solution containing said contaminants and an outlet for discharging oxidant and oxidized contaminant; and

an electrocoagulation stage for electrocoagulating oxidized contaminants from said oxidizing stage, said electrocoagulation stage including;

a closed reactor for electrocoagulating oxidized contaminants, said reactor having an inlet in fluid communication with said outlet of said closed container and an outlet for discharging effluent, said reactor configured to diverge from said inlet to said outlet thereof;

electrodes in electrical communication with said reactor, said electrodes being in spaced relation and connectable to a source of power for supplying current to said electrodes; and

a power supply for supplying currents to said electrodes; and

a plurality of discrete fluidizable metal reaction surfaces freely fluidizable within said reactor for electrochemically oxidizing said contaminants in said aqueous solution in the presence of said electrodes to isolate said contaminants.

11. The system as set forth in claim 10, wherein said oxidizing stage and said electrocoagulation stage are isolated.

12. The system as set forth in claim 10, further including means for separating electrocoagulated contaminants and aqueous solution.

13. The system as set forth in claim 10, further including means for entraining oxidant in said aqueous solution.

14. The system as set forth in claim 10, further including means for selectively inducing hydrodynamic cavitation in oxidized aqueous solution for generating bubbles in said aqueous solution.

15. The system as set forth in claim 10, further including a settling container in fluid communication with said outlet of said reactor for settling electrocoagulated contaminants generated from said electrocoagulation stage.

16. The system as set forth in claim 15, wherein said settling tank is connected to said outlet of said reactor.

17. The system as set forth in claim 10, wherein said divergent inlet stage comprises metal and is connectable to said power supply to act as a first electrode of said electrodes.

18. The system as set forth in claim 17, wherein a second electrode of said electrodes comprises an elongate metal member in spaced relation to said first electrode.

19. The system as set forth in claim 18, wherein said electrodes comprise stainless steel.

20. The system as set forth in claim 17, wherein the second electrode of said electrodes comprises a divergent electrode positioned in spaced relation to and within said divergent inlet stage, a narrow end of said divergent electrode positioned in spaced relation to and within said divergent inlet stage, said narrow end of said divergent electrode in spaced relation to said inlet of said divergent stage.

21. The system as set forth in claim 20, wherein the said divergent electrode has a contoured shape for augmenting fluidization of metal reaction surfaces.

22. The system as set forth in claim 10, wherein said electrodes comprise a first electrode and a second electrode in spaced relation with said inlet staged.

23. The system as set forth in claim 10, wherein said discrete fluidizable metal reaction surfaces comprise a member selected from the group comprising:

metal powder, metal balls, metal beads, metal pellets and metal powder.

24. The system as set forth in claim 23, wherein said metal comprises aluminum.

25. A method of separating contaminants from an aqueous solution containing said contaminants, comprising the steps of:

a) providing an aqueous solution containing said contaminants;

b) oxidizing, in an oxidizing phase, contaminants present in said aqueous solution;

c) electrocoagulating, in an electrocoagulation phase, oxidized contaminants from step b, said electrocoagulation phase including;

providing a reactor having an inlet and an outlet from the said reactor diverging in configuration from said inlet to said outlet, said reactor including electrode means actuable by a power supply;

providing discrete fluidizable metal reaction surfaces within said reactor;

introducing oxidized contaminants and aqueous solution into said inlet of said reactor;

fluidizing said metal reaction surface in said reactor in the presence of electric current;

electrocoagulating contaminants; and

d) separating electrocoagulated contaminants from said aqueous solution.

26. The method as set forth in claim 25, wherein said step of oxidizing includes entraining an oxidant into a source of aqueous solution containing contaminants to be treated.

27. The method as set forth in claim 25, further including the step of insulating said electrode means from direct contact with said fluidizable metal reaction services with non conductive material permeable to said oxidant and said aqueous solution.

28. The method as set forth in claim 25, further including the step of fluidizing said metal reaction surfaces in a circular flow pattern.

29. The method as set forth in claim 28, wherein said circular flow pattern is divided into at least two substantially circular flow patterns.

30. The method as set forth in claim 25, wherein said method is a continuous closed circuit treatment.