Cool burning gas generating composition

• US 6,361,630 B2
• Filed: 08/17/1999
• Issued: 03/26/2002
• Est. Priority Date: 08/17/1999
• Status: Expired due to Fees

• Current Assignee: TRW Inc. (Northrop Grumman Corporation)
• Original Assignee: TRW Inc. (Northrop Grumman Corporation)
• Inventors: Helmy, Abdel K., Michon, Tracy N.
• Primary Examiner(s): Carone, Michael J.
• Assistant Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US09/376,738
• Publication Number:
  US 20010017176A1
• Time in Patent Office: 952 Days
• Field of Search: 149/36, 149/19.4, 149/19.5, 149/46, 149/45, 149/62, 149/78, 149/92
• US Class Current: 149/19.4
• CPC Class Codes: C06B 23/04 for cooling the explosion gases including antifouling and flash suppressing agents
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

An apparatus (10) comprises an inflatable vehicle occupant protection device (16) and a gas generating composition which when ignited produces gas to inflate the inflatable vehicle occupant protection device (16). The gas generating composition comprises a non-azide nitrogen containing organic fuel, an inorganic salt oxidizer, and a metal organic coolant selected from the group consisting of alkali metal formates, alkaline earth metal formates, alkali metal oxalates, and alkaline earth metal oxalates. The amount of metal organic coolant in the gas generating composition is a cooling amount.

Claims

1. A gas generating composition which when ignited produces gas to inflate an inflatable vehicle occupant protection consisting essentially of:

a non-azide nitrogen containing organic fuel selected from the group consisting of guanidine nitrate, triaminoguanidine nitrate, and mixtures of guanidine nitrate and triaminoguanidine nitrate;

an inorganic salt oxidizer;

a burn rate modifier selected from the group consisting of cyclotetramethylenetetranitramine, cyclotrimethylenetrinitramine, iron oxide and mixtures thereof;

0 to about 10% by weight of a non-energetic binder; and

a metal organic coolant selected from the group consisting of alkali metal formates, alkaline earth metal formates, alkali metal oxalates, and alkaline earth metal oxalates;

wherein the gas generating composition upon combustion has a flame temperature less than about 1700K and produces at least about 2.5 moles/100 grams of gas.

2. The gas generating composition of claim 1 wherein the amount of formate or oxalate in the gas generating composition is that amount effective to cause liquid particles formed upon combustion of the gas generating composition to coalesce into an easily filterable slag.

3. The gas generating composition of claim 2 wherein the amount of formate or oxalate is from about 15% to about 25% based on the weight of the gas generating composition.

4. The gas generating composition of claim 2 wherein the inorganic salt oxidizer is selected from the group consisting of alkali metal nitrates, alkaline earth metal nitrates, alkali metal perchlorates, alkaline earth metal perchlorates, ammonium perchlorate, and ammonium nitrate.

5. The gas generating composition of claim 2 wherein the burn rate modifier comprises cyclotetramethylenetetranitramine.

6. The gas generating composition of claim 5 wherein the burn rate modifier further comprises iron oxide.

7. A gas generating composition which when ignited produces gas to inflate an inflatable vehicle occupant protection device comprising:

a non-azide nitrogen containing organic fuel selected from the group consisting of guanidine nitrate, triaminoguanidine nitrate, and mixtures of guanidine nitrate and triaminoguanidine nitrate;

an inorganic salt oxidizer; and

a metal organic coolant selected from the group consisting of alkali metal formates and alkaline earth metal formates, wherein the amount of metal organic coolant in the gas generating composition is that amount effective to cause liquid particles formed upon combustion of the gas generating composition to coalesce into an easily filterable slag.

8. The gas generating composition as defined in claim 7 wherein the amount of metal organic coolant in the gas generating composition is from about 15% to about 25% based on the weight of the gas generating composition.

9. The gas generating composition as defined in claim 8 further comprising a burn rate modifier selected from the group consisting of cyclotrimethylenetrinitramine, cyclotetramethylenetetranitramine, iron oxide, and mixtures thereof.

10. The gas generating composition of claim 9 wherein the burn rate modifier comprises cyclotetramethylenetetranitramine and iron oxide.

11. The gas generating composition as defined in claim 7 wherein the gas generating composition further comprises a non-energetic binder.

12. The gas generating composition as defined in claim 7 wherein the inorganic salt oxidizer is selected from group consisting of alkali metal nitrates, alkaline earth metal nitrates, alkali metal perchlorates, alkaline earth metal perchlorates, ammonium perchlorate, and ammonium nitrate.

13. A gas generating composition which when ignited produces gas to inflate an inflatable vehicle occupant protection device comprising:

about 15% to about 35%, based on the weight of the gas generating composition, of a non-azide nitrogen containing organic fuel selected from the group consisting of guanidine nitrate, triaminoguanidine nitrate, and mixtures of guanidine nitrate and triaminoguanidine nitrate;

about 30% to about 50%, based on the weight of the gas generating composition, an inorganic salt oxidizer selected from group consisting of alkali metal nitrates, alkaline earth metal nitrates, alkali metal perchlorates, alkaline earth metal perchlorates, ammonium perchlorate, and ammonium nitrate; and

about 15% to about 25%, based on the weight of the gas generating composition, of a metal organic coolant selected from the group consisting of alkali metal formates, and alkaline earth metal formates;

wherein the gas generating composition upon combustion has a flame temperature less than about 1700K and produces at least about 2.5 mole/100 g of combustion gas.

14. The gas generating composition of claim 13 further comprising a burn rate modifier selected from the group consisting of cyclotetramethylenetetranitramine, cyclotrimethylenetrinitramine, iron oxide, and mixtures thereof.

15. The gas generating composition of claim 14 wherein the burn rate modifier comprises cyctetramethylenetetranitramine.

16. The gas generating composition as defined in claim 15 wherein the oxidizer is strontium nitrate and the non-azide organic fuel is guanidine nitrate.

17. The gas generating composition as defined in claim 16 wherein the metal organic coolant is calcium formate.