Composite ceramic article and method of making

• US 6,361,735 B1
• Filed: 09/01/1999
• Issued: 03/26/2002
• Est. Priority Date: 09/01/1999
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Duclos, Steven Jude, Venkataramani, Venkat Subramaniam, Brewer, James Anthony, Greskovich, Charles David
• Primary Examiner(s): DERRINGTON, JAMES H
• Application Number:
  US09/388,091
• Time in Patent Office: 937 Days
• Field of Search: 264/614, 264/642, 264/643, 264/645, 264/656, 156/89.11, 156/89.23
• US Class Current: 264/643
• CPC Class Codes: B28B 1/008 made from two or more materials having different characteristics or properties casting for producing layered articles B28B1/16; feeding several succesive layers, optionally of different materials B28B13/022; coating B28B11/04; applying material to surfaces to form a permanent layer thereon B28B19/00
• CPC Class Codes: B28B 1/24 by injection moulding injection moulding of ceramic slips B28B1/265; of tubular articles B28B21/38
• CPC Class Codes: C04B 35/50 based on rare-earth compounds non-oxide rare earth compounds C04B35/5156
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence

Abstract

The invention relates to a method of forming a composite article comprising the steps of forming a plurality of green ceramic elements, wherein the green ceramic elements are arranged side by side, and the green ceramic elements are spaced from each other by gaps; filling the gaps with a second material; and sintering the green ceramic elements with the second material to form the composite article. The second material, after being sintered, acts as a reflector layer to prevent substantially all light in one of the sintered ceramic elements from reaching an adjacent sintered ceramic element. The step of filling the gaps may be carried out by forming a slurry containing the second material in powder form and immersing the green ceramic elements in the slurry. The process of cosintering the green ceramic elements with the reflector composition provides improved dimensional control during sintering and reduces processing costs.

Claims

1. A method of forming a ceramic scintillator article, the method comprising the steps of:

forming a plurality of green ceramic elements, wherein the green ceramic elements are arranged side by side, and the green ceramic elements are spaced from each other by gaps;

filling the gaps with a second material; and

sintering the green ceramic elements with the second material to form the ceramic scintillator article;

wherein the second material, after being sintered, substantially remains between two sintered ceramic elements and prevents substantially all light in one of the sintered ceramic elements from reaching an adjacent sintered ceramic element.

2. The method of claim 1, wherein each of the plurality of green ceramic elements extend from a connecting member.

3. The method of claim 1, wherein the step of filling the gaps comprises:

forming a slurry containing the second material in powder form; and

immersing the green ceramic elements in the slurry.

4. The method of claim 3, further comprising the step of exposing the green ceramic elements to a vacuum while the green ceramic elements are immersed in the slurry.

5. The method of claim 1, further comprising the step of aligning the plurality of green ceramic elements in a jig, and wherein the step of filling the gaps comprises immersing the plurality of ceramic elements in a slurry.

6. The method of claim 1, wherein the second material comprises a dry powder, and the step of filling the gaps comprises spraying the dry powder into the gaps.

8. The method of claim 1, wherein the step of forming a plurality of green ceramic elements comprises preparing a ceramic powder comprising gadolinium oxide and yttrium oxide.

9. The method of claim 1, wherein the step of forming a plurality of green ceramic elements comprises preparing a ceramic powder comprising an activated garnet material.

10. The method of claim 1, wherein the second material comprises at least one of yttrium oxide and gadolinium oxide.

11. The method of claim 1, wherein the first and second materials have the same chemical composition and different pack densities.

12. The method of claim 1, further comprising the step of preheating the composite article to remove at least one binder from at least one of the green ceramic elements and the second material.

13. The method of claim 3, further comprising the step of curing the slurry.

14. The method of claim 1, wherein the gaps comprise a plurality of parallel rectilinear gaps.

15. The method of claim 1, wherein the gaps comprise a first set of parallel rectangular gaps and a second set of parallel rectangular gaps, the first set of gaps being perpendicular to the second set of gaps.

7. A method of forming a composite article, the method comprising the steps of:

forming a plurality of green ceramic elements, wherein the green ceramic elements are arranged side by side, and the green ceramic elements are spaced from each other by gaps;

filling the gaps with a second material, wherein the step of filling the gaps comprises the steps of;

coating a metal foil with the second material; and

inserting the metal foil in the gaps; and

sintering the green ceramic elements with the second material to form the composite article;

wherein the second material, after being sintered, substantially remains between two sintered ceramic elements and prevents substantially all light in one of the sintered ceramic elements from reaching an adjacent sintered ceramic elements.

16. A method of forming a ceramic scintillator structure comprising the steps of:

forming a plurality of green ceramic elements from a first powder comprising a first ceramic material, the first powder having a first pack density;

filling gaps between the green ceramic elements with a second powder comprising a second ceramic material, the second powder having a second pack density; and

cosintering the green ceramic elements with the second powder to form the ceramic scintillator structure;

wherein the first ceramic material is the same as the second ceramic material, and the first pack density is different from the second pack density.

17. The method of claim 16, wherein the first and second ceramic materials comprise yttria and gadolinia.

18. The method of claim 17, wherein the first pack density is 55-65% of theoretical density, and the second pack density is 25-35% of theoretical density.

19. The method of claim 18, wherein the first powder has mean particle diameter of about 0.5-0.7 microns, and the second powder has a mean particle diameter of about 0.2-0.3 microns.

20. A method of forming a ceramic scintillator article, the method comprising the steps of:

forming a first component, the first component comprising a plurality of green ceramic elements extending from a connecting member, the plurality of green ceramic elements being connected only at the connecting member, wherein the gaps are defined between the green ceramic elements;

filling the gaps with a ceramic powder; and

cosintering the green ceramic elements with the ceramic powder to form the ceramic scintillator article, wherein the ceramic powder, after being sintered, substantially remains between two sintered ceramic elements and prevents substantially all light in one of the sintered ceramic elements from reaching an adjacent sintered ceramic element.

21. The method of claim 20, wherein the step of filling the gaps comprises:

forming a slurry containing the second material; and

immersing the green ceramic elements in the slurry.

22. The method of claim 21, further comprising the step of exposing the green ceramic elements to a vacuum while the green ceramic elements are immersed in the slurry.

23. The method of claim 20, wherein the step of filling the gaps comprises spraying the second material into the gaps.

25. The method of claim 20, wherein the step of forming a plurality of green ceramic elements comprises preparing a ceramic powder comprising gadolinium oxide and yttrium oxide.

26. The method of claim 20, wherein the step of forming a plurality of green ceramic elements comprises preparing a ceramic powder comprising an activated garnet material.

24. A method of forming a composite article, the method comprising the steps of:

forming a first component, the first component comprising a plurality of green ceramic elements extending from a connecting member, the plurality of green ceramic elements being connected only at the connecting member, wherein the gaps are defined between the green ceramic elements;

filling the gaps with a ceramic powder, wherein the step of filling the gaps composes the steps of;

coating a metal foil with the ceramic powder; and

inserting the metal foil in the gaps; and

cosintering the green ceramic elements with the ceramic powder to form the composite article, wherein the ceramic powder, after being sintered, substantially remains between two sintered ceramic elements and prevents substantially all light in one of the sintered ceramic elements from reaching an adjacent sintered ceramic element.

27. The method of claim 24 wherein the ceramic powder has the same composition as the green ceramic elements.

28. The method of claim 24 wherein the ceramic powder has a different composition than the green ceramic elements.