Gas generating compositions

• US 6,368,432 B2
• Filed: 12/15/1998
• Issued: 04/09/2002
• Est. Priority Date: 07/13/1998
• Status: Expired due to Term

• Current Assignee: NOF Corporation
• Original Assignee: NOF Corporation
• Inventors: Nakamichi, Kenji, Takahashi, Katsuhiko, Serizawa, Kazuya
• Primary Examiner(s): Carone, Michael J.
• Assistant Examiner(s): FELTON, AILEEN BAKER
• Application Number:
  US09/211,900
• Publication Number:
  US 20020007885A1
• Time in Patent Office: 1,211 Days
• Field of Search: 149/46, 149/45
• US Class Current: 149/46
• CPC Class Codes: C06B 31/30 with vegetable matter; with resin; with rubber
• CPC Class Codes: C06B 45/00 Compositions or products which are defined by structure or arrangement of component of product explosive charges of particular form or shape F42B1/00, F42B3/00
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A gas generating composition for generating gas by a combustion reaction to inflate, for example, an airbag. The gas generating composition includes an oxidant and crystalline carbon powder that reacts with the oxidant. The oxidant is preferably ammonium nitrate. The crystalline carbon powder is preferably activated carbon powder. The gas generating composition preferably includes a high energy substance, binder and plasticizer.

Claims

1. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant; and

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 95;

5 and 99;

1, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

9. The gas generating composition according to one of claims 1-8, wherein each of the ammonium nitrate and the microcrystalline activated carbon has average diameter of in a range of 1 to 1000 pm.

10. The gas generating composition according to claim 9, wherein the ammonium nitrate has a coated surface to prevent moisture absorption.

11. The gas generating composition according to claim 9, wherein the ammonium nitrate is a phase-stabilized ammonium nitrate.

12. The gas generating composition according to claim 9, wherein the occupant restraint system is an air bag apparatus and the gas generating composition is formed in one of a lobed tube and polygonal prism with an outer diameter of 5 to 40 mm, an axial length of 5 to 40 mm and through holes inner diameter of 1 to 10 mm, wherein the number of the through holes is either 7 or 19.

13. The gas generating composition according to claim 9, wherein the occupant restraint system is an air bag apparatus and the gas generating composition is formed in a tube with an outer diameter of 3 to 10 mm, an axial length of 2 to 10 mm and a through hole inner diameter of 1 to 8 mm.

14. The gas generating composition according to claim 9, wherein the occupant restraint system is a seat belt pre-tensioner apparatus and the gas generating composition is formed in a tube with an outer diameter of 0.5 to 5 mm, an axial length of 0.5 to 5 mm and a through hole inner diameter of 0.1 to 4 mm.

15. The gas generating composition according to claim 9, wherein the occupant restraint system is a seat belt pre-tensioner apparatus and the gas generating composition is formed in a tube with an outer diameter of 0.5 to 2 mm, an axial length of 0.5 to 2 mm and a through hole inner diameter of 0.2 to 1 mm.

2. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1; and

high energy substance selected from the group consisting of RDX, HMX, PETN, HN and a mixture thereof, wherein the content of the high energy substance is in a range of 0.6 to 16 wt % of the gas generating composition, and wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

3. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1 and the total weight of the ammonium nitrate and the microcrystalline activated carbon is in 73.5-99.5% of the gas generating compound; and

a binder selected from the group consisting of cellulose acetate, polyvinyl alcohol, glycidylazide polymer and a mixture thereof, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

4. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1 and the total weight of the ammonium nitrate and the microcrystalline activated carbon is in 73.5-99.5% of the gas generating compound;

nitrocellulose; and

a stabilizer for impeding decomposition of the nitrocellulose, wherein the stabilizer is in 0.5-1.0% of the gas generating compound, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

5. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1;

high energy substance selected from the group consisting of RDX, HMX, PETN, TAGN, HN and a mixture thereof, wherein the content of the high energy substance is in a range of 1.3 to 2.5 wt % of the gas generating composition; and

a binder selected from the group consisting of cellulose acetate, polyvinyl alcohol, glycidylazide polymer and a mixture thereof, wherein the content of the binder is in a range of 4.0 to 22.5 wt % of the gas generating composition, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

6. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 an 99;

1;

high energy substance selected from the group consisting of RDX, HMX, PETN, TAGN, HN and a mixture thereof, wherein the content of the high energy substance is in a range of 1.3 to 2.5 wt % of the gas generating composition;

nitrocellulose; and

a stabilizer for impeding decomposition of the nitrocellulose, wherein the stabilizer is in 0.5-1.0% of the gas generating compound, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

7. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1 and the total weight of the ammonium nitrate and the microcrystalline activated carbon is in 83-87% of the gas generating compound;

high energy substance selected from the group consisting of RDX, HMX, PETN, TAGN, HN and a mixture thereof, wherein the content of the high energy substance is in a range of 1.0 to 2.0 wt % of the gas generating composition; and

a binder selected from the group consisting of cellulose acetate, polyvinyl alcohol, glycidylazide polymer and a mixture thereof; and

a plasticizer to increase plasticity of the gas generating composition, wherein the gas generating composition has a predetermined size and shape, the shape being one of cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.

8. A gas generating composition, which is installed in a vehicle occupant restraint system and generates gas by a combustion reaction when the vehicle occupant restraint system is actuated, wherein the gas generating composition essentially consists of:

ammonium nitrate as an oxidant;

microcrystalline activated carbon as an reductant, wherein the microcrystalline activated carbon has a specific surface area of 700 to 1600 m²/g, wherein the weight ratio of the ammonium nitrate to the microcrystalline activated carbon is between 94;

6 and 99;

1;

high energy substance selected from the group consisting of RDX, HMX, PETN, TAGN, HN and a mixture thereof, wherein the content of the high energy substance is in a range of 1.0 to 2.0 wt % of the gas generating composition;

nitrocellulose;

a stabilizer for impeding decomposition of the nitrocellulose; and

a plasticizer to increase plasticity of the gas generating composition, wherein the gas generating composition has a predetermined size and shape, the shape being one of a cylinder, a tube, a lobed tube having a plurality of through holes, and a polygonal prism having a plurality of through holes.