Self bleaching photoelectrochemical-electrochromic device

• US 6,369,934 B1
• Filed: 08/01/2000
• Issued: 04/09/2002
• Est. Priority Date: 05/30/1996
• Status: Expired due to Fees

• Current Assignee: Alliance For Sustainable Energy LLC
• Original Assignee: Midwest Research Institute
• Inventors: Gregg, Brian A., Bechinger, Clemens S.
• Primary Examiner(s): Ben, Loha
• Application Number:
  US09/631,201
• Time in Patent Office: 616 Days
• Field of Search: 359/265, 359/266, 359/270, 359/272, 359/273, 359/275, 345/49, 345/84, 345/105, 345/106, 250/214.SG, 252/586, 252/582
• US Class Current: 359/265
• CPC Class Codes: G02F 1/153 Constructional details
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G02F 2001/1536 additional, e.g. protective, layer inside the cell
• CPC Class Codes: H01G 9/2031 comprising titanium oxide, e.g. TiO2 H01G9/2036 takes precedence
• CPC Class Codes: H01G 9/2059 comprising an organic dye as the active light absorbing material, e.g. adsorbed on an electrode or dissolved in solution
• CPC Class Codes: Y02E 10/542 Dye sensitized solar cells

Abstract

A photoelectrochemical-electrochromic device comprising a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other. The first transparent electrode is electrically connected to the second transparent electrode. An electrochromic material is applied to the first transparent electrode and a nanoporous semiconductor film having a dye adsorbed therein is applied to the second transparent electrode. An electrolyte layer contacts the electrochromic material and the nanoporous semiconductor film. The electrolyte layer has a redox couple whereby upon application of light, the nanoporous semiconductor layer dye absorbs the light and the redox couple oxidizes producing an electric field across the device modulating the effective light transmittance through the device.

Claims

1. A self-powered photoelectrochemical-electrochromic device that automatically modulates transmittance of incoming light without an external power source the device comprising:

a first transparent electrode;

a second transparent electrode disposed in parallel, spaced relation to said first electrode, the first transparent electrode being electrically connected to said second transparent electrode;

a layer of electrochromic material applied to said first transparent electrode;

a nanoporous semiconductor film applied to said second transparent electrode;

said nanoporous semiconductor film having adsorbed therein a light absorbing dye;

said absorbing dye enhancing the absorption of light in a specific spectral range; and

electrolyte means of a selected thickness to provide lateral ionic conductivity that darkens an entire immediately adjacent layer of electrochromic material when light strikes any portion of the electrolyte means deposited between and contacting said electrochromic material layer and said nanoporous semiconductor dye adsorbed film, the electrolyte means having a redox couple such that upon application of light, the dye is illuminated by the absorption of light and said redox couple oxidizes to produce an electric field across the device which modulates effective light transmittance in said electrochromic material, said device and electrochromic material spontaneously bleaching upon removal of the light as a result of illuminated oxidized dye causing a chemically reversible oxidation on ions in said electrolyte means.

2. The device of claim 1 and further comprising a first transparent substrate and a second transparent substrate, the first transparent electrode being applied to the first transparent substrate, the second transparent electrode being applied to the second transparent substrate.

3. The device of claim 2, wherein the first and second transparent substrates comprise a material selected from the group consisting of glass and plastic.

4. The device of claim 1 wherein the electrochromic material is selected from the group consisting of WO₃, IrO_x, V₂O₅, and NiO.

5. The device of claim 1 wherein the semiconductor film comprises a metal oxide or metal sulfide selected from the group consisting of TiO₂, CdS, ZnS, ZnO, and WO₃.

6. The device of claim 1 wherein a dye substance enhances the absorption of light in a specific spectral range.

7. The device of claim 6 wherein the dye substance comprises transition metal complexes selected from the group consisting of ML₃ and ML₂X₂, wherein M is selected from the group consisting of Fe, Ru, Os, CR, Mo and Mn, wherein L comprises bipyridinetype ligand selected from the group consisting of 2,2′

-bipyridine-4,4′

-dicarboxylic acid and 4,4′

-dimethyl-s-2′

-bipyridine, and wherein X comprises monodentate ligand selected from the group consisting of CN, SCN, Cl, Br, I and H₂O.

8. The device of claim 6 wherein the dye substance is selected form the group consisting of poryphyrins, perylenes, phthalocyanines and RHODAMINES.

9. The device of claim 1 wherein the electrolyte means includes Li ions.

10. The device of claims 1 wherein said electrolyte means is selected from the group consisting of a liquid, a polymer and an ionic solid.

11. A self-powered photoelectrochemical-electrochromic device that automatically modulates transmittance of incoming light without an external power source, the device comprising:

a first transparent electrode;

a second transparent electrode disposed in a parallel, spaced relation to said first electrode, the first transparent electrode being electrically connected to said second transparent electrode;

a layer of electrochromic material applied to said first transparent electrode;

a nanoporous semiconductor film applied to said second transparent electrode;

said nanoporous semiconductor film having adsorbed therein a light absorbing dye;

said absorbing dye enhancing the absorption of light in a specific spectral range; and

electrolyte means of a selected thickness to provide lateral ionic conductivity such that images are storable within the device when light strikes the electrolyte means deposited between and contacting said electrochromic material layer and said nanoporous semiconductor dye adsorbed film, the electrolyte means having a redox couple such that upon application of light, the dye is illuminated by the absorption of light and said redox couple oxidizes to produce an electric field across the device which modulates the effective light transmittance in said electrochromic material, said device and electrochromic material spontaneously bleaching upon removal of the light as a result of illuminated oxidized dye causing a chemically reversible oxidation of ions in said electrolyte means.

12. A method of modulating the transmittance of light comprising:

electrically connecting a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other;

applying an electrochromic material to the first transparent electrode;

applying a nanoporous semiconductor film to the second transparent electrode;

said nanoporous semiconductor film having adsorbed therein a light absorbing dye that enhances absorption of light in a specific spectral range;

positioning an electrolyte layer between the electrochromic material and the nanoporous semiconductor film, the electrolyte layer having a redox couple, whereby the first and second electrodes, the electrochromic material, the nanoporous semiconductor film, and the electrolyte layer form a photoelectrochemical-electrochromic device; and

exposing the photoelectrochemical-electrochromic device to a light source wherein the dye in the nanoporous semiconductor film absorbs the light and the redox couple oxidizes producing an electric field across the photo-electrochemical-electrochromic device to vary the effective light transmittance through the photoelectrochemical-electrochromic device.

13. The method of claim 12 further comprising applying the first transparent electrode to a first transparent substrate and applying the second transparent electrode to a second transparent substrate.

14. The method of claim 12 wherein the dye comprises transition metal complexes.

15. The method of claim 12 wherein the electrolyte layer has a predetermined thickness to provide high lateral ionic conductance.