Alkaline sorbent injection for mercury control

• US 6,372,187 B1
• Filed: 12/07/1998
• Issued: 04/16/2002
• Est. Priority Date: 12/07/1998
• Status: Expired due to Term

• Current Assignee: Babcock & Wilcox Company (Babcock International Group PLC)
• Original Assignee: McDermott Technology, Inc.
• Inventors: Holmes, Michael J., Madden, Deborah A.
• Primary Examiner(s): Griffin, Steven P.
• Assistant Examiner(s): MEDINA SANABRIA, MARIBEL
• Application Number:
  US09/206,465
• Time in Patent Office: 1,226 Days
• Field of Search: 422/171, 422/172, 423/243.08, 423/243.11, 423/244.07, 423/244.08, 110/345, 95/71, 952/34
• US Class Current: 422/171
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01D 53/80 Semi-solid phase processes, i.e. by using slurries
• CPC Class Codes: B01D 53/81 Solid phase processes

Abstract

A mercury removal system for removing mercury from combustion flue gases is provided in which alkaline sorbents at generally extremely low stoichiometric molar ratios of alkaline earth or an alkali metal to sulfur of less than 1.0 are injected into a power plant system at one or more locations to remove at least between about 40% and 60% of the mercury content from combustion flue gases. Small amounts of alkaline sorbents are injected into the flue gas stream at a relatively low rate. A particulate filter is used to remove mercury-containing particles downstream of each injection point used in the power plant system.

Claims

1. A mercury removal system for removing mercury from a flue gas generated in a combustion system having a boiler and a stack, comprising:

an alkaline sorbent source;

particulate removal means for separating and removing particulate matter containing mercury from a boiler flue gas, the particulate removal means located between the boiler and the stack; and

sorbent injection means for providing an alkaline sorbent in one of powdered and slurried form to to the boiler flue gas having a temperature below 2000°

F., the sorbant injection means being located upstream of the stack and further being fluidically connected to the alkaline sorbent source, the alkaline sorbent containing at least one element selected from the alkaline earth elements and further being provided in a stoichiometric molar ratio of alkaline earth to sulfur of less than 1 mole alkaline earth/mole sulfur.

2. The mercury removal system according to claim 1, wherein the stoichiometric molar ratio is in a range of about 0.001 mole alkaline earth/mole sulfur to about 0.5 mole alkaline earth/mole sulfur.

3. The mercury removal system according to claim 2, wherein the alkaline sorbent comprises one of limestone, lime, a calcium-based sorbent, and a combination thereof.

4. The mercury removal system according to claim 3, wherein the alkaline sorbent comprises limestone.

5. The mercury removal system according to claim 1, wherein the stoichiometric molar ratio is about 0.35 mole alkaline earth/mole sulfur.

6. The mercury removal system according to claim 5, wherein the alkaline sorbent comprises one of limestone, lime, a calcium-based sorbent, and a combination thereof.

7. The mercury removal system according to claim 1, wherein the particulate removal means comprises an electrostatic precipitator.

8. The mercury removal system according to claim 7, wherein the stoichiometric molar ratio is in a range of about 0.001 mole alkaline earth/mole sulfur to about 0.5 mole alkaline earth/mole sulfur.

9. The mercury removal system according to claim 7, comprising means for providing the alkaline sorbent to at least one of upstream adjacent the electrostatic precipitator and upstream adjacent the stack, the stack further comprising separator means for separating and removing particulate containing mercury from the flue gas.

10. A mercury removal system for removing mercury from a flue gas generated in a combustion system having a boiler and a stack, comprising:

an alkaline sorbent source;

particulate removal means for separating and removing particulate matter containing mercury from a boiler flue gas, the particulate removal means located between the boiler and the stack; and

sorbent injection means for providing an alkaline sorbent in one of powdered and slurried form to the boiler flue gas having a temperature below 2000°

F., the sorbent injection means being located upstream of the stack and further being fluidically connected to the alkaline sorbent source, the alkaline sorbent containing at least one element selected from the alkali metals and further being provided in a stoichiometric molar ratio of alkali metal to sulfur of less than 1 mole alkali metal/mole sulfur.

11. The mercury removal system according to claim 10, wherein the stoichiometric molar ratio is in a range of about 0.001 mole alkali metal/mole sulfur to about 0.5 mole alkali metal/mole sulfur.

12. The mercury removal system according to claim 11, wherein the alkaline sorbent comprises a sodium-based sorbent.

13. The mercury removal system according to claim 10, wherein the stoichiometric molar ratio is about 0.35 mole alkali metal/mole sulfur.

14. The mercury removal system according to claim 13, wherein the alkaline sorbent comprises a sodium-based sorbent.

15. The mercury removal system according to claim 10, wherein the alkaline sorbent is a sodium-based sorbent.

16. The mercury removal system according to claim 10, wherein the particulate removal means comprises an electrostatic precipitator.

17. The mercury removal system according to claim 10, wherein the particulate removal means comprises an electrostatic precipitator.

18. The mercury removal system according to claim 17, wherein the stoichiometric molar ratio is in a range of about 0.001 mole alkali metal/mole sulfur to about 0.5 mole alkali metal/mole sulfur.

19. The mercury removal system according to claim 17, comprising means for providing the alkaline sorbent to at least one of upstream adjacent the electrostatic precipitator and upstream adjacent the stack, the stack further comprising separator means for separating and removing particulate containing mercury from the flue gas.

20. A mercury removal system for removing mercury from a flue gas generated in a combustion system having a boiler and a stack, comprising:

an alkaline sorbent source;

particulate removal means for separating and removing particulate matter containing mercury from a boiler flue gas, the particulate removal means located between the boiler and the stack; and

sorbent injection means for providing au alkaline sorbent in one of powdered and slurried form to the boiler flue gas having a temperature below 2000°

F., the sorbent injection means being located upstream of the stack fluidically connected to the alkaline sorbent source, the alkaline sorbent containing a combination of at least one element selected from the alkaline earth elements and at least one element selected from the alkali metals, and the sorbent further being provided in a stoichiometric molar ratio of alkaline earth and alkali metal to sulfur of less than 1 mole alkaline earth and alkali metal/mole sulfur.