Electrochemical treating method and apparatus

• US 6,375,827 B1
• Filed: 02/03/2000
• Issued: 04/23/2002
• Est. Priority Date: 02/04/1999
• Status: Expired due to Term

• Current Assignee: De Nora Permelec Ltd. (Industrie De Nora S.p.A)
• Original Assignee: Permelec Electrode, Ltd.
• Inventors: Nara, Miwako, Kurosu, Tateki, Nishiki, Yoshinori, Wakita, Shuhei, Nakamatsu, Shuji
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US09/497,644
• Time in Patent Office: 810 Days
• Field of Search: 205/687, 205/688, 205/746, 205/763, 205/765, 204/263, 204/265, 204/266, 204/275.1, 204/294, 204/290.F
• US Class Current: 205/687
• CPC Class Codes: A61L 2/035 Electrolysis
• CPC Class Codes: B01D 53/326 in electrochemical cells
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/4672 by electrooxydation
• CPC Class Codes: C02F 1/4676 by electroreduction
• CPC Class Codes: C02F 2001/46138 Electrodes comprising a substrate and a coating
• CPC Class Codes: C02F 2101/305 Endocrine disruptive agents

Abstract

An electrochemical treating apparatus comprising an electrolytic cell comprising an anode and a cathode spaced apart from the anode, the anode including an electrode material made of diamond and the cathode including an electrode material made of diamond. Also disclosed is an electrochemical treating method for electrochemically decomposing a substance contained in a gas or solution, which comprises introducing a gas or solution containing a substance to be treated into the electrolytic cell, passing an electric current through the electrolytic cell, and recovering a treated gas or solution. In a preferred embodiment, the electrolytic cell comprises an anode including an electrode material made of diamond, a cathode including an electrode material made of diamond and an ion exchange resin or an ion exchange membrane as an electrolyte disposed between the anode and the cathode.

Claims

1. An electrochemical treating apparatus comprising an electrolytic cell including a reaction chamber and an anode and a cathode spaced apart from said anode, said anode and cathode being arranged within the same reaction chamber, said anode including an electrode material made of diamond and said cathode including an electrode material made of diamond.

2. The electrochemical treating apparatus as claimed in claim 1, said electrolytic cell further comprising an inlet for supplying a gas or solution containing a substance to be treated and an outlet for removing a treated gas or solution.

3. The electrochemical treating apparatus as claimed in claim 2, further including a stirrer for increasing the rate of supply of the gas or solution to be treated to the electrode materials of the anode and cathode, respectively.

4. The electrochemical treating apparatus as claimed in claim 1, wherein at least one of said and anode and cathode comprises a substrate having a surface and a diamond layer formed on the surface of the substrate.

5. The electrochemical treating apparatus as claimed in claim 4, wherein said substrate is selected from the group consisting of a punched plate, gauze, sintered powder or sintered fiber of titanium, niobium, tantalum, silicon, carbon, nickel or tungsten carbide.

6. The electrochemical treating apparatus as claimed in claim 4, wherein the diamond layer has a thickness of from 0.1 to 50 μ

m.

7. The electrochemical treating apparatus as claimed in claim 4, wherein said diamond is bonded to the substrate with a binder.

8. The electrochemical treating apparatus as claimed in claim 1, wherein the diamond contains an impurity for imparting electrical conductivity to said anode and cathode electrode materials.

9. An electrochemical treating apparatus comprising an electrolytic cell comprising an anode including an electrode material made of diamond, a cathode including an electrode material made of diamond and an ion exchange resin or an ion exchange membrane as an electrolyte disposed between said anode and said cathode.

10. The electrochemical treating apparatus as claimed in claim 9, wherein said electrolyte comprises an ion exchange membrane and said anode and cathode are in close contact with opposing sides of said ion exchange membrane.

11. The electrochemical treating apparatus as claimed in claim 9, wherein said electrolyte comprises an ion exchange resin and said anode and cathode are in close contact with said ion exchange resin.

12. The electrochemical treating apparatus as claimed in claim 9, wherein at least one of said anode and cathode comprises a substrate having a surface and a diamond layer formed on the surface of the substrate.

13. The electrochemical treating apparatus as claimed in claim 12, wherein the diamond layer has a thickness of from 0.1 to 50 μ

m.

14. The electrochemical treating apparatus as claimed in claim 9, wherein the diamond contains an impurity for imparting electrical conductivity to said anode and cathode electrode materials.

15. An electrochemical treating method for electrochemically decomposing a substance contained in a gas or solution, which comprises introducing a gas or solution containing a substance to be treated into an electrolytic cell including a reaction chamber and an anode and a cathode spaced apart from said anode, said anode and cathode being arranged within the same reaction chamber, said anode including an electrode material made of diamond and said cathode including an electrode material made of diamond, passing an electric current through the electrolytic cell, and recovering a treated gas or solution.

16. The electrochemical treating method as claimed in claim 15, which comprises contacting a gas or solution containing a substance to be treated with said anode and cathode to decompose said substance into lower molecular weight components.

17. The electrochemical treating method as claimed in claim 15, which comprises contacting a gas or solution containing a substance to be treated with said anode and cathode so as to generate oxidizing and/or reducing species which in turn act to decompose said substance into lower molecular weight components.

18. An electrochemical treating method for electrochemically decomposing a substance contained in a gas or solution, which comprises introducing a gas or solution containing a substance to be treated into an electrolytic cell comprising an anode including an electrode material made of diamond, a cathode including an electrode material made of diamond and an ion exchange resin or an ion exchange membrane as an electrolyte disposed between said anode and said cathode, passing an electric current through the electrolytic cell, and recovering a treated gas or solution.

19. The electrochemical treating apparatus as claimed in claim 18, wherein said electrolyte comprises and ion exchange membrane and said anode and cathode are in close contact with opposing sides of said ion exchange membrane.

20. The electrochemical treating apparatus as claimed in claim 18, wherein said electrolyte comprises an ion exchange resin and said anode and cathode are in close contact with said ion exchange resin.

21. The electrochemical treating method as claimed in claim 18, which comprises contacting a gas or solution containing a substance to be treated with said anode and cathode to decompose said substance into lower molecular weight components.

22. The electrochemical treating method as claimed in claim 18, which comprises contacting a gas or solution containing a substance to be treated with said anode and cathode so as to generate oxidizing and/or reducing species which in turn act to decompose said substance into lower molecular weight components.