Method for temporarily protecting glass articles

• US 6,379,746 B1
• Filed: 01/31/2000
• Issued: 04/30/2002
• Est. Priority Date: 02/02/1999
• Status: Expired due to Term

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Carre, Alain R. E., Birch, William, Tennent, David L., Bookbinder, Dana C.
• Primary Examiner(s): Beck, Shrive P.
• Assistant Examiner(s): Crockford, Kirsten A.
• Application Number:
  US09/495,166
• Time in Patent Office: 820 Days
• Field of Search: 65/603, 65/61, 65/601, 427/154, 427/289, 427/293, 427/165, 427/168, 427/368
• US Class Current: 427/154
• CPC Class Codes: C03C 17/28 with organic material C03C17/34, C03C17/44 take precedence
• CPC Class Codes: C03C 2218/355 Temporary coating

Abstract

Methods for temporarily protecting a surface of a glass article by coating the surface are provided. The methods include forming a stable, hydrophobic, removable film on the surface at the end of the glass manufacturing process while the glass is still at an elevated temperature (e.g., above 175° C.). The film reduces chip adhesion to the surface as a result of cutting and grinding. After cutting and grinding, the film is removed allowing the glass to be used in such processes as the manufacture of liquid crystal displays (LCDs).

Claims

1. A method for treating glass having at least one substantially flat surface comprising:

(a) forming a hydrophobic coating on the surface by applying an aqueous solution comprising at least one surfactant to the surface as part of the manufacturing process for the glass, wherein;

(1) the manufacturing process produces newly formed glass at an elevated temperature;

(2) the newly formed glass is at a temperature above 175°

C. when it first comes into contact with the aqueous solution;

(3) the surfactant is selected from the group consisting of cationic surfactants, non-ionic surfactants, and betaines; and

(4) the coating reduces adhesion of glass chips to the surface;

(b) cutting the glass;

(c) grinding and/or polishing at least one edge of the cut glass; and

(d) removing the coating from the surface;

wherein;

(i) water or a water-containing solution is applied to the coated surface during at least one of steps (b) and (c); and

(ii) the coating has a sessile drop contact angle of at least 40°

after steps (b) and (c).

2. The method of claim 1 wherein the glass is vertical in step (a) and the temperature of the glass remains sufficiently high throughout step (a) so that drips do not form on the surface.

3. The method of claim 1 wherein the temperature of the glass is at least 150°

C. at the end of step (a).

4. The method of claim 1 wherein the newly formed glass is at a temperature above 250°

C. when it first comes into contact with the aqueous solution.

5. The method of claim 1 wherein the aqueous solution is applied to the surface by spraying.

6. The method of claim 1 wherein the surfactant is a cationic surfactant which comprises at least one straight or branched hydrocarbon chain that comprises on average at least 8 and no more than 18 carbon atoms.

7. The method of claim 6 wherein the cationic surfactant comprises two straight or branched hydrocarbon chains each of which comprises on average at least 8 and no more than 18 carbon atoms.

8. The method of claim 7 wherein the surfactant is a dicocoalkyldimethyl ammonium salt.

9. The method of claim 7 wherein the surfactant is a didecyldimethyl ammonium salt.

10. The method of claim 1 wherein the concentration of the surfactant in the aqueous solution is between about 10⁻

6 moles/liter and about 0.5 moles/liter.

11. The method of claim 1 wherein the coating reduces the number of glass chips adhered to the surface by at least 80 percent compared to the number of glass chips adhered to an uncoated surface under comparable conditions.

12. The method of claim 11 wherein the number of glass chips adhered to the surface is reduced by at least 90 percent.

13. The method of claim 1 wherein step (d) comprises applying an aqueous solution which comprises a detergent to the coating.

14. The method of claim 13 wherein step (d) comprises applying ultrasonic energy to the coating.

15. The method of claim 13 wherein step (d) comprises brush washing the surface.

16. The method of claim 13 wherein step (d) comprises applying ultrasonic energy to the coating and brush washing the surface.

17. The method of claim 1 wherein step (d) comprises oxidizing at least the outer surface of the coating.

18. The method of claim 13 wherein step (d) comprises oxidizing at least the outer surface of the coating.

19. The method of claim 14 wherein step (d) comprises oxidizing at least the outer surface of the coating.

20. The method of claim 15 wherein step (d) comprises oxidizing at least the outer surface of the coating.

21. The method of claim 16 wherein step (d) comprises oxidizing at least the outer surface of the coating.

22. The method of claim 17 wherein the outer surface of the coating is oxidized using ozone.

23. The method of claim 22 wherein the ozone is produced using a corona discharge.

24. The method of claim 22 wherein the ozone is produced using UV light.

25. The method of claim 17 wherein the outer surface of the coating is oxidized using ozonated water.

26. The method of claim 1 wherein the coating has a sessile drop contact angle of at least 50°

after steps (b) and (c).

27. The method of claim 1 wherein the surface has a sessile drop contact angle of less than 10°

after step (d).

28. The method of claim 1 wherein in at least one of steps (b) and (c), a water-containing solution comprising a surfactant used in step (a) is applied to the coated surface.

29. The method of claim 1 wherein after rinsing with water and prior to step (d), the coating is sufficiently thin to permit visual inspection of the glass through the coating.

30. The method of claim 1 wherein the glass has two substantially flat surfaces and the coating is formed on both surfaces in step (a).

31. The method of claim 1 wherein after step (d), the glass is used to make a liquid crystal display.