Polymer particles of controlled shape

• US 6,380,297 B1
• Filed: 08/12/1999
• Issued: 04/30/2002
• Est. Priority Date: 08/12/1999
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: NEXPRESS SOLUTIONS LLC (Eastman Kodak Company)
• Inventors: Zion, Todd C., Ezenyilimba, Matthew C., Yoon, Hichang, Smith, Dennis E.
• Primary Examiner(s): Wu, David W.
• Assistant Examiner(s): Lee, Rip A
• Application Number:
  US09/373,340
• Time in Patent Office: 992 Days
• Field of Search: 523/335, 523/336, 523/337, 523/338, 523/339, 430/137, 206/37.87
• US Class Current: 524/493
• CPC Class Codes: C08J 3/14 by precipitation from solutions C08J3/122 takes precedence

Abstract

A method for the preparation of polymer particles comprising the steps of: a) forming an organic phase by dissolving a polymer material in a solvent; b) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and homogenizing the resultant dispersion, thereby forming spherical particles having a selected particle and uniform particle size distribution; c) following the homogenizing, adding a particle shape-modifying surface active material to the spherical particles; and d) removing the solvent, thereby producing irregularly shaped polymer particles having substantially the same selected particle size and particle size distribution as that of the spherical particles.

Claims

1. A method for the preparation of polymer particles comprising the steps of:

a) forming an organic phase by dissolving a polymer material in a solvent;

b) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer and homogenizing the resultant dispersion, thereby forming spherical particles having a selected particle size and uniform particle size distribution;

c) following the homogenizing, adding a particle shape-modifying surface active material to the spherical particles; and

d) removing the solvent, thereby producing irregularly shaped polymer particles having substantially the same selected particle size and particle size distribution as that of the spherical particles.

2. The method of claim 1 further comprising the step of washing and drying the irregularly shaped polymer particles produced in step d).

3. The method of claim 1 wherein addenda selected from charge control agent and pigment are added in step a).

4. The method of claim 1 wherein a promoter is added in step b).

5. The method of claim 1 wherein the organic solvent is selected from the group consisting of chloromethane, dichloromethane, ethyl acetate, n-propyl acetate, iso-propyl acetate, vinyl chloride, methyl ethyl ketone, trichloromethane, carbon tetrachloride, ethylene chloride, trichloroethane, toluene, xylene, cyclohexanone and 2-nitropropane.

6. The method of claim 1 wherein the organic solvent is selected from propyl acetate and ethyl acetate.

7. The method of claim 1 wherein the particle shape-modifying surface active material is selected from the group consisting of cationic surface active material, anionic surface active material, and nonionic surface active material.

8. The method of claim 7 wherein the cationic surface active material is an ammonium salt or a condensation polymerization product of one or more dicarboxylic acids and an aminoalcohol, diamine, or diol, wherein at least one group contained in an organic dicarboxylic acid chain carries a positive charge.

9. The method of claim 7 wherein the anionic surface active material is a condensation polymerization product of one or more dicarboxylic acids and an aminoalcohol, diamine, or diol, wherein at least one group contained in an organic dicarboxylic acid chain carries a negative charge.

10. The method claim 7 wherein the nonionic surface active material is selected from the group consisting of a polyalkylene oxide, a polyethyleneimine, a polyallylvinylether, a polyallylacrylamide, and a polymerization condensation product of one or more dicarboxylic acids and an aminoalcohol, diamine, or diol.

11. The method of claim 1 wherein the surface active material to polymer ratio ranges from 0.0001 to about 50% by weight of total solids dissolved in the mixture.

12. The method of claim 1 wherein the particulate stabilizer is selected from the group consisting of highly cross-linked latex polymeric material, and colloidal silica.

13. The method of claim 1 wherein the amount of particulate stabilizer is between 1 to 15 parts based on 100 parts of total solids in the polymer particles.

14. The method of claim 1 wherein the relationship in volume between the aqueous phase and the organic phase ranges from 1:

1 to 9;

1.

15. The method of claim 1 wherein the organic phase contains addenda selected from lubricants and waxes.

16. The method of claim 1 wherein the polymer material is selected from the group consisting of olefin homopolymers and copolymers, polytrifluoroolefins, polyamides, acrylic resins, polystyrene and copolymers of styrene with unsaturated monomers, cellulose derivatives, polyesters, polyvinyl resins and ethylene-allyl alcohol copolymers.

17. The method of claim 16 wherein the polymer material is selected from the group consisting of polyethylene, polypropylene, polyisobutylene, polyisopentylene, polytetrafluoroethylene, polytrifluorochloroethylene, polyhexamethylene adipamide, polyhexamethylene sebacamide, polycaprolactam, polymethylmethacrylate, polymethylacrylate, polyethylmethacrylate styrene-methylmethacrylate, ethylene-methylacrylate copolymers, ethylene-ethyl acrylate copolymers, and ethylene-ethyl methacrylate copolymers.

18. The method of claim 1 wherein the polymer material is selected from the group consisting of polyester and butyl acrylate-styrene copolymer.

19. The method of claim 3 wherein the pigment employed comprises from 1.0 to 40.0 weight %, based upon the weight of total solids present in the polymer particles.

20. The method of claim 3 wherein the pigment employed comprises from 4.0 to 20.0 weight %, based upon the weight of total solids present in the polymer particles.

21. Electrophotographic toner particles produced by the method described in claim 1.