Aqueous suspension concentrate

• US 6,383,984 B1
• Filed: 01/18/2000
• Issued: 05/07/2002
• Est. Priority Date: 01/29/1999
• Status: Expired due to Term

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Aven, Michael
• Primary Examiner(s): Carr, Deborah D.
• Application Number:
  US09/484,563
• Time in Patent Office: 840 Days
• Field of Search: 568/420, 568/333, 514/686, 504/116
• US Class Current: 504/116.1
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16

Abstract

The invention relates to an aqueous, concentrated suspension (SC) for crop protection active compounds which comprises

(a) 50 to 400 g/L of at least one crop protection active compound;

(b) 50 to 500 g/L of at least one adjuvant, which reduces the surface tension in the spray dilution 40 mN/m or less and does not promote the particle growth of the crop protection active compound;

(c) at least one surfactant selected from the groups (c1) and (c2):

(c1) 5 to 75 g/L of one or more non-ionic dispersants,

(c2) 10 to 100 g/L of one or more anionic dispersants,

(d) up to 150 g/L of one or more anti-freezing agents,

(e) up to 25 g/L of one or more defoamers,

(f) up to 25 g/L of one or more preservatives, and

(g) 200 to 800 g/L of water,

wherein the adjuvant (b) is selected from the group consisting of amine alkoxylates, polyoxyalkylene triglycerides, alkylpolyglycosides, alkenyl succinic anhydride derivatives, polyvinylpyrrolidones, perfluoroalkyl acids derivatives, and mixtures thereof;

and to the use of such a concentrate suspension as a pesticide.

Claims

1. A method for the enhancement of the efficacy of crop protection active compounds which comprises combining said crop protection active compounds with an effective amount of at least one adjuvant, which has the capability of reducing the surface tension in an aqueous spray dilution to 40 mN/m or lower being selected from the group consisting of amine alkoxylates, polyoxyalkylene triglycerides, alkylpolyglycosides, alkenyl succinic anhydride derivatives, polyvinylpyrrolidones, perfluoroalkyl acids derivatives, and mixtures thereof.

5. A SC in accordance with claim 1 comprising 55 to 150 g/L of at least one perfluoro(C_6-18)alkylphosphonic acid, perfluoro(C_6-18)alkylphosphinic acid or a mixture thereof.

2. An aqueous, concentrated suspension (SC) for crop protection active compounds which comprises

(a) 50 to 400 g/L of at least one crop protection active compound;

(b) 50 to 500 g/L of at least one adjuvant, which has the capability of reducing the surface tension in the spray dilution to 40 mN/m or lower and does not promote the particle growth of the crop protection active compound;

(c) at least one surfactant selected from the groups (c1) and (c2);

(c1) 5 to 75 g/L of one or more non-ionic dispersants, and

(c2) 10 to 100 g/L of one or more anionic dispersants,

(d) up to 150 g/L of one or more anti-freezing agents,

(e) up to 25 g/L of one or more defoamers,

(f) up to 25 g/L of one or more preservatives, and

(g) 200 to 800 g/L of water,

wherein the adjuvant (b) is selected from the group consisting of amine alkoxylates, polyoxyalkylene triglycerides, alkylpolyglycosides, alkenyl succinic anhydride derivatives, polyvinylpyrrolidones, perfluoroalkyl acids derivatives, and mixtures thereof.

3. A SC in accordance with claim 2 wherein the crop protection active compound (a) comprises a benzoylbenzene of formula I

wherein

R¹ represents a halogen atom, an optionally substituted alkyl, alkanoyloxy or alkoxy group; or a hydroxy group,

R² represents a halogen atom, an optionally substituted alkyl group,

R³ represents a halogen atom or an optionally substituted alkyl group,

m is 0 or an integer of 1 to 3;

R⁴ independently represents a halogen atom, an optionally substituted alkyl or alkoxy group or a nitro group;

R⁵ represents an optionally substituted alkyl group;

R⁶ represents a halogen atom, a cyano, carboxy, hydroxy or nitro group or an optionally substituted alkyl, alkoxy, alkenyl, alkylthio, alkylsulphinyl, alkylsulphonyl or amino group;

R⁷ represents a halogen atom or a nitro group, an optionally substituted alkyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, cycloalkyl, cycloalkyloxy, aryloxy group; and

n is 0, 1 or 2.

4. A SC in accordance with claim 2 comprising 75 to 450 g/L of at least one alkylpolyglycoside, at least one amine ethoxylate or at least one alkenyl succinic anhydride diglucamide.

6. A SC in accordance with claim 2 wherein the ratio of the crop protection active compounds (a) to said adjuvant (b) is between 1:

05 and 1;

100, preferably between 1;

0.75 and 1;

10.

7. A SC in accordance with claim 2 comprising in addition to the components (a) to (g):

(h) 0.1 to 30 g/l of at least one thickener.

8. A SC in accordance with claim 2 wherein the non-ionic dispersant (c1) is a block copolymer which consists of a polyoxypropylene and polyoxyethylene moieties.

9. A SC in accordance with claim 2 wherein the anionic dispersant (c2) is an amino sulfonate or an alkali or earth alkali sulfonate.

10. A SC in accordance with claim 2 wherein the anti-freezing agent (d) is an alkyleneglycol derivative.

11. A SC in accordance with claim 2 wherein the defoamer (e) is a silicone derivative.

12. A method for combating a fungus at a locus which comprises diluting a formulation as claimed in any of the claims 2 to 11 with water and treating said locus with the obtained diluted aqueous formulation.