Process for obtaining fibers integral with calcium carbonate particles

• US 6,387,212 B1
• Filed: 08/09/2000
• Issued: 05/14/2002
• Est. Priority Date: 02/20/1998
• Status: Expired due to Term

• Current Assignee: Specialty Minerals Incorporated (Minerals Technologies Incorporated)
• Original Assignee: L'Air Liquide SA
• Inventors: Christian, Richard
• Primary Examiner(s): NGUYEN, TAN D
• Application Number:
  US09/601,891
• Time in Patent Office: 643 Days
• Field of Search: 162/9, 162/158, 162/183, 162/181.1, 162/181.4, 162/181.5, 162/181.2
• US Class Current: 162/9
• CPC Class Codes: C01F 11/18 Carbonates
• CPC Class Codes: D21C 5/025 De-inking
• CPC Class Codes: D21C 9/004 inorganic compounds
• CPC Class Codes: D21H 17/01 Waste products, e.g. sludge
• CPC Class Codes: D21H 17/64 Alkaline compounds
• CPC Class Codes: D21H 17/65 Acid compounds
• CPC Class Codes: D21H 17/66 Salts, e.g. alums
• CPC Class Codes: D21H 17/675 Oxides, hydroxides or carbonates
• CPC Class Codes: D21H 17/70 forming new compounds in situ, e.g. within the pulp or paper, by chemical reaction with other substances added separately
• CPC Class Codes: Y02W 30/64 Paper recycling

Abstract

The invention relates to a process for obtaining fibers integral with calcium carbonate particles, in which the fibers to be treated are contacted with carbon dioxide generator means and at least one composition comprising Ca⁺⁺ ions capable of reacting with the carbon dioxide so as to give “in fine” a precipitation of calcium carbonate “in situ” on the fibers. Preferably, the carbon dioxide generator used is calcium bicarbonate.

Claims

1. Process for obtaining fibers integral with calcium carbonate particles, which comprises:

preparing a first composition comprising calcium bicarbonate;

preparing a second composition comprising calcium hydroxide; and

mixing the first and second compositions in the presence of said fibers thereby precipitating calcium carbonate particles in contact with at least some of said fibers.

2. Process according to claim 1, wherein the calcium bicarbonate present in the first composition is obtained by treating calcium carbonate with carbon dioxide.

3. Process according to claim 2, wherein the calcium carbonate is present in the form of an aqueous suspension containing between 0.5 g/l and 10 g/l.

4. A process according to claim 3, wherein the calcium carbonate is present in an amount of 1.5 to 3 g/l.

5. A process according to claim 4, wherein the calcium carbonate is present in an amount of 2 g/l.

6. Process according to claim 2, wherein the carbon dioxide is injected in the form of pure gas or diluted to a total pressure of at least atmospheric pressure.

7. Process according to claim 1, wherein at least some Ca⁺⁺ ions present in the first composition originate from a calcium carbonate-loaded liquor.

8. Process according to claim 1, wherein at least some Ca⁺⁺ ions present in the second composition originate from a lime solution.

9. Process according to claim 1, wherein the first composition is filtered before mixing with the second composition.

10. Process according to claim 1, wherein the second composition is filtered before mixing with the first composition.

11. Process according to claim 1, wherein the second composition is an aqueous lime suspension, the calcium hydroxide concentration being between 1 g/l and 10 g/l.

12. A process according to claim 11, wherein the calcium hydroxide is in a concentration of 1.5 to 2.5 g/l.

13. A process according to claim 12, wherein the calcium hydroxide is in a concentration of 2 g/l.

14. Process according to claim 1, wherein the calcium bicarbonate present in the first composition is prepared by treating an aqueous medium containing calcium carbonate obtained from paper recycling or from deinking sludges, with carbon dioxide.

15. Process according to claim 1, wherein at least a portion of the first composition comprises residual liquors obtained from a papermaking machine.

16. Process according to claim 1, wherein at least a portion of the second composition comprises residual liquors obtained from a papermaking machine.

17. Process according to claim 1, wherein residual liquors obtained from a papermaking machine are separated into an unfiltered fraction and a filtered fraction with the unfiltered fraction being used to prepare the first composition and the filtered fraction used to prepare the second composition.

18. Process according to claim 1, in which the first composition is a solution of calcium bicarbonate and the second composition is a solution of lime water, wherein said compositions are filtered before mixing to remove colored insoluble residues before the precipitation of the calcium carbonate and to obtain a calcium carbonate with a whiteness of at least 95.

19. Process according to claim 1, wherein the fibers to be treated are present in the form of a fiber suspension in water containing between 1 to 15% of fibers by weight.

20. A process according to claim 19, wherein the fibers are present in an amount of 5 to 10% by weight.