Catalytic hydrocarbon dehydrogenation system with prereaction

• US 6,392,113 B1
• Filed: 10/03/2000
• Issued: 05/21/2002
• Est. Priority Date: 10/03/2000
• Status: Active Grant

• Current Assignee: ABB Lummus Global Inc.
• Original Assignee: ABB Lummus Global Inc.
• Inventors: Gartside, Robert J.
• Primary Examiner(s): Griffin, Walter D.
• Assistant Examiner(s): Nguyen, Tam M.
• Application Number:
  US09/678,567
• Time in Patent Office: 595 Days
• Field of Search: 585/654, 585/440, 585/616
• US Class Current: 585/654
• CPC Class Codes: C07C 11/06 Propene
• CPC Class Codes: C07C 5/321 Catalytic processes
• CPC Class Codes: C07C 5/333 Catalytic processes
• CPC Class Codes: Y02P 20/584 Recycling of catalysts

Abstract

The performance of an endothermic catalytic dehydrogenation process is increased without requiring additional catalyst regeneration and reheat air flow and compression by partially prereacting the preheated hydrocarbon feed and then reheating the partially dehydrogenated effluent from the prereactor to the same hydrocarbon preheat temperature prior to the main catalytic reactor. The preferable source of the heat for reheating is the effluent air from the reheat and regeneration of the catalyst in the main reactor. This same effluent air is used to regenerate the catalyst in the prereactor as needed.

Claims

1. A catalytic endothermic process for dehydrogenating hydrocarbons comprising the steps of:

a. heating an oxygen-containing gas;

b. passing said heated oxygen-containing gas through a first bed of dehydrogenation catalyst to both provide heat to said dehydrogenation catalyst for the endothermic dehydrogenation and to regenerate said catalyst by oxidizing carbonaceous deposits and thereby providing a first effluent gas;

c. preheating said hydrocarbon to a desired reaction temperature;

d. passing said preheated hydrocarbon through an unheated prereactor dehydrogenation catalyst bed wherein the exothermic heat of the dehydrogenation reaction therein is provided by said preheated hydrocarbon and said hydrocarbon is partially dehydrogenated and cooled below said desired reaction temperature;

e. reheating said cooled partially dehydrogenated hydrocarbon to said desired reaction temperature;

f. passing said reheated partially dehydrogenated hydrocarbon through said heated and regenerated first bed of dehydrogenation catalyst whereby said hydrocarbon is further dehydrogenated and said first bed of dehydrogenation catalyst is cooled.

2. A process as recited in claim 1 and further comprising the step of passing said heated oxygen-containing gas through a second bed of dehydrogenation catalyst after said first bed of dehydrogenation catalyst has been heated and regenerated and while said hydrocarbon is passing through said prereaction dehydrogenation catalyst bed and said first bed of dehydrogenation catalyst and thereby heating and regenerating said second bed of dehydrogenation catalyst and providing a second effluent gas and reheating said cooled partially dehydrogenated hydrocarbon by heat transfer from said second effluent gas.

3. A process as recited in claim 2 and further including the step of injecting a fuel gas into said second effluent gas and thereby further heating said second effluent gas.

4. A process as recited in claim 2 and further comprising the step of regenerating said prereactor dehydrogenation catalyst with a portion of said second effluent gas.

5. A process as recited in claim 1 wherein said step of regenerating said catalyst further includes the subsequent step of contacting said catalyst with a reducing gas.