Remote magneto-elastic analyte, viscosity and temperature sensing apparatus and associated methods of sensing

• US 6,397,661 B1
• Filed: 12/30/1998
• Issued: 06/04/2002
• Est. Priority Date: 12/30/1998
• Status: Expired due to Fees

• Current Assignee: University Of Kentucky Research Foundation (University of Kentucky)
• Original Assignee: University Of Kentucky Research Foundation (University of Kentucky)
• Inventors: Stoyanov, Plamen G., Grimes, Craig A.
• Primary Examiner(s): Williams, Hezron
• Assistant Examiner(s): MILLER, ROSE MARY
• Application Number:
  US09/223,689
• Time in Patent Office: 1,252 Days
• Field of Search: 324/204, 324/207.13, 324/209, 324/235, 324/239, 324/633, 324/71.1, 73/540.1, 73/540.2, 73/544.1, 73/645.3, 738/65, 73/240.1, 73/310.5, 73/542-- 5, 73/543.8, 73/614.9, 73/52, 73/617.5, 73/617.9, 73/240.5, 73/240.6, 73/300.4, 73/300.2, 73/32.A
• US Class Current: 73/24.06
• CPC Class Codes: G01K 7/38 the variations of temperature influencing the magnetic permeability
• CPC Class Codes: G01N 11/16 by measuring damping effect upon oscillatory body
• CPC Class Codes: G01N 2291/014 Resonance or resonant frequency
• CPC Class Codes: G01N 2291/015 Attenuation, scattering
• CPC Class Codes: G01N 2291/0222 Binary liquids
• CPC Class Codes: G01N 2291/02818 Density, viscosity
• CPC Class Codes: G01N 2291/02827 Elastic parameters, strength or force
• CPC Class Codes: G01N 2291/02881 Temperature
• CPC Class Codes: G01N 29/0609 Display arrangements, e.g. colour displays indicating or recording in connection with measuring in general G01D
• CPC Class Codes: G01N 29/2412 using the magnetostrictive properties of the material to be examined, e.g. electromagnetic acoustic transducers [EMAT]; investigating the presence of flaws using eddy currents G01N27/90, magnetostrictive transducers B06B1/08, measuring magnetostrictive properties G01R33/18
• CPC Class Codes: G01N 29/341 with time characteristics
• CPC Class Codes: G01N 9/002 using variation of the resonant frequency of an element vibrating in contact with the material submitted to analysis G01N9/34 takes precedence

Abstract

An analyte, viscosity, or temperature sensing apparatus for operative arrangement within a time-varying magnetic field, including a sensor with an outer surface that is chemically, frictionally, or thermally responsive and adhered to a base magnetostrictive element, and a receiver to measure a first and second value for magneto-elastic emission intensity of the sensor taken at, respectively, a first and second interrogation frequency. A change in mass or a change in material stiffness of the sensor due to the responsiveness, the viscosity and mass density of a fluid therearound, or the temperature, can be identified. The receiver, alternatively, measures a plurality of successive values for magneto-elastic emission intensity of the sensor taken over an operating range of successive interrogation frequencies to identify a value for the sensor'"'"'s magneto-elastic resonant frequency (a fundamental frequency or harmonic thereof). Several sensors in an ordered array will provide a “package” of information.

Claims

1. An analyte sensing apparatus for operative arrangement within a time-varying magnetic field, comprising:

a sensor having an outer surface of a material that is chemically responsive to the analyte, said material being adhered to a base magnetostrictive element, said sensor having a magneto-elastic resonant frequency;

a receiver to measure a first and second value for magneto-elastic emission intensity of said sensor taken at, respectively, a first and second interrogation frequency; and

a unit to identify a change in mass of said sensor using a ratio of said first and second values.

2. The apparatus of claim 1 wherein said chemically responsive material is adhered over a portion of said base magnetostrictive element by an adhesive layer compatible with both said material and said base magnetostrictive element;

and said sensor is incorporated within an array of magnetostrictive elements comprising a viscosity sensing element.

3. The apparatus of claim 1 wherein said first interrogation frequency is less than said magneto-elastic resonant frequency by an interval, Δ

f, and said second interrogation frequency is greater than said magneto-elastic resonant frequency by approximately said interval, Δ

f.

4. The apparatus of claim 3 wherein said interval, Δ

f, is a value between 0.001% and 40% of said magneto-elastic resonant frequency, said magneto-elastic emission is an acoustic emission, said magneto-elastic resonant frequency is an acoustic resonant frequency, and said receiver is an electroacoustic device containing a transducer.

5. The apparatus of claim 1 wherein:

said chemically responsive material is a chemically receptive polymer layer having a plurality of microspheres, said chemical responsiveness comprising absorption of subatomic particulate matter from the analyte; and

said sensor and a magnetizable magnetically hard element are contained for operation within a chamber of a support member.

6. The apparatus of claim 1 wherein said chemically responsive material is a chemically receptive porous polymer layer, said chemical responsiveness comprising interaction with the analyte causing a change in material stiffness of said sensor, and said base magnetostrictive element extends from a support member from which a second magnetostrictive element also extends to sense viscosity of a fluid therearound.

8. The apparatus of claim 1 wherein:

said chemically responsive material is a sorbent polymer film selected from the group consisting of a poly(isobutylene), ethylene-propylene rubber, poly(isoprene), and poly(butadiene) film;

said polymer film is adhered over a substantial portion of said base magnetostrictive element by an adhesive layer compatible with both said polymer film and said base magnetostrictive element; and

the analyte is in vapor form.

9. The apparatus of claim 1 wherein said chemically responsive material is an outer polymer hydrogel monolayer reactive to electrostatic forces of subatomic particles within the analyte, and said magnetostrictive element is made of an alloy that remains generally unchanged over a preselected range of temperatures.

10. The apparatus of claim 1 wherein said chemically responsive material is a chemically receptive polymer layer, said chemical responsiveness comprises a loss of matter from said polymer layer, and said base magnetostrictive element is made of an alloy of an element selected from the group consisting of iron, cobalt, samarium, yttrium, gadolinium, terbium, and dysprosium;

and further comprising a magnetizable on-off switch comprising a magnetically hard element.

11. The apparatus of claim 1 wherein the analyte is a gas comprising subatomic particles, said chemically responsive material is a zeolite layer, said chemical responsiveness comprises interaction with at least a portion of said subatomic particles to cause a gain in matter of said zeolite layer, said magneto-elastic emission is an acoustic emission, and said receiver is an electroacoustic device containing a transducer.

12. The apparatus of claim 1 wherein:

said first interrogation frequency is less than said magneto-elastic resonant frequency by an interval, Δ

f, said second interrogation frequency is greater than said magneto-elastic resonant frequency by approximately said interval, Δ

f, said interval being a value between 0.001% and 40% of said magneto-elastic resonant frequency; and

said receiver is an electromagnetic pick-up coil, said magneto-elastic emission is an electromagnetic emission, and said magneto-elastic resonant frequency is a harmonic of a fundamental resonant frequency of said sensor.

13. The apparatus of claim 12 wherein:

said chemically responsive material is a chemically receptive polymer layer having a plurality of microspheres which is adhered over a substantial portion of said base magnetostrictive element;

said chemical responsiveness comprises swelling of said microspheres as a function of the analyte moisture content; and

said sensor is incorporated within an array of magnetostrictive elements comprising a viscosity sensing element.

14. The apparatus of claim 1 further comprising a second sensor having a second resonant frequency different from said magneto-elastic resonant frequency, said second sensor for sensing a viscosity of a fluid therearound;

and wherein said receiver is used to measure a third and fourth value for magneto-elastic emission intensity of said second sensor taken at, respectively, a third and fourth interrogation frequency.

7. An analyte sensing apparatus for operative arrangement within a time-varying magnetic field, comprising:

a sensor having an outer surface of a material that is chemically responsive to the analyte, said material being adhered to a base magnetostrictive element, said sensor having a magneto-elastic resonant frequency;

a receiver to measure a first and second value for magneto-elastic emission intensity of said sensor taken at, respectively, a first and second interrogation frequency, and

a unit to identify a change in material stiffness of said sensor using a ratio of said first and second values;

wherein said magneto-elastic resonance frequency is a harmonic of a fundamental resonant frequency of the sensor; and

a pre-correlation made between a series of emission intensity ratio values taken for said sensor and a corresponding series of material stiffness values is used for said identification of said change in material stiffness.

15. An analyte sensing apparatus for operative arrangement within a time-varying magnetic field, comprising:

a sensor having an outer surface of a material that is chemically responsive to the analyte, said material being adhered to a base magnetostrictive element;

a receiver to measure a plurality of successive values for magneto-elastic emission intensity of said sensor taken over an operating range of successive interrogation frequencies to identify a magneto-elastic resonant frequency value for said sensor; and

a unit to identify a change in mass of said sensor using said identified magneto-elastic resonant frequency value.

16. The apparatus of claim 15 wherein:

said magneto-elastic resonant frequency value corresponds with a relative maximum of said plurality of successive values for magneto-elastic emission intensity measured; and

a pre-correlation made between a series of magneto-elastic resonant frequency values for said sensor and a corresponding series of mass change values for said sensor is used for said identification of said change in mass.

17. The apparatus of claim 15 wherein:

said magneto-elastic emission is an acoustic emission, and said receiver is an electroacoustic device containing a transducer for operation over a range of frequencies from 1 KHz to 1 GHz;

said chemically responsive material is a chemically receptive polymer layer, said chemical responsiveness comprising absorption of subatomic particulate matter from the analyte causing an increase in said mass and a change in material stiffness of said sensor; and

further comprising a magnetizable on-off switch comprising a magnetically hard element.

18. The apparatus of claim 15 wherein:

said magneto-elastic emission is an acoustic emission, and said receiver is an electroacoustic device containing a transducer;

said chemically responsive material is a polymer layer having swellable gel membrane complexes, said chemical responsiveness comprising diffusion of selected ion species of the analyte into said polymer layer to sense glucose concentration; and

a pre-correlation made between a series of acoustic resonant frequency values for said sensor and a corresponding series of mass change values for said sensor is used for said identification of said change in mass.

19. The apparatus of claim 15 wherein said receiver is an electromagnetic pick-up coil, said magneto-elastic emission is an electromagnetic emission, said magnetostrictive element is elongated in shape, and further comprising, in proximity to said sensor, a magnetizable magnetically hard element for generating a DC bias field.

20. The apparatus of claim 15 further comprising a second sensor for sensing temperature, both said sensors extending from a support member;

said receiver to further measure a second plurality of successive values for magneto-elastic emission intensity of said second sensor taken over a second operating range of successive interrogation frequencies to identify a magneto-elastic resonant frequency value for said second sensor.

21. A method of sensing an analyte with a sensor having a chemically responsive material adhered to a base magnetostrictive element, the sensor having a magneto-elastic resonant frequency, comprising the steps of:

applying a time-varying magnetic field;

measuring a first and second value for magneto-elastic emission intensity of the sensor with a receiver operating at, respectively, a first and second interrogation frequency; and

using a ratio of said first and second values to identify a change in mass, of the sensor due to the chemical responsiveness of said sensor to said analyte.

22. The method of claim 21 wherein said first interrogation frequency is less than the magneto-elastic resonant frequency by an interval, Δ

f, and said second interrogation frequency is greater than the magneto-elastic resonant frequency by approximately said interval;

said interval being a value between 0.001% and 40% of the magneto-elastic resonant frequency.

23. The method of claim 21 wherein said chemically responsive material is a polymer layer, the chemical responsiveness comprising absorption of subatomic particulate matter from the analyte, said receiver is an electroacoustic device containing a transducer to aid in said step of measuring;

and further comprising, prior to said step of using, the step of pre-correlating a series of emission intensity ratio values taken for the sensor and a corresponding series of mass values for the sensor.

24. The method of claim 23 wherein said polymer layer is a hydrogel reactive to electrostatic forces of said subatomic particulate matter, said step of pre-correlating is used for said step to identify a change in mass, and further comprising the step of applying a known relationship between said change in mass and the analyte for the sensing thereof.

25. The method of claim 21 wherein said receiver is an electromagnetic pick-up coil, said magneto-elastic emission is an electromagnetic emission, said chemically responsive material is a layer which is adhered over a portion of said base magnetostrictive element by an adhesive compatible with both said layer and said element, and said element is made of an alloy that remains generally unchanged over a preselected range of temperatures;

and further comprising, using said ratio of first and second values to identify a change in material stiffness, if any, of the sensor due to the chemical responsiveness.

26. The method of claim 21 further comprising the step of measuring a third and fourth value for magneto-elastic emission intensity of a second sensor with said receiver operating at, respectively, a third and fourth interrogation frequency to sense a viscosity of a fluid therearound;

both said sensors extending from a support member in an ordered array.

27. A method of sensing an analyte with a sensor having a chemically responsive material adhered to a base magnetostrictive element, comprising the steps of:

applying a time-varying magnetic field;

measuring a plurality of successive values for magneto-elastic emission intensity of the sensor with a receiver operating over a range of successive interrogation frequencies to identify a magneto-elastic resonant frequency value for the sensor;

pre-correlating a series of resonant frequency values taken for the sensor and a corresponding series of mass values for the sensor; and

using said identified magneto-elastic resonant frequency value and said step of pre-correlating to identify a change in mass, of the sensor.

28. The method of claim 27 wherein:

said receiver is an electroacoustic device containing a transducer to aid in said step of measuring, said magneto-elastic emission is an acoustic emission, said magneto-elastic resonant frequency value corresponds with a relative maximum of said plurality of successive values for magneto-elastic emission intensity measured; and

further comprising the step of applying a known relationship between said change in mass and the analyte for the sensing thereof.

30. The method of claim 27 further comprising the steps of measuring a second plurality of successive values for magneto-elastic emission intensity of a second sensor with said receiver operating over a second range of successive interrogation frequencies to identify a magneto-elastic resonant frequency value for said second sensor, and pre-correlating a second series of resonant frequency values taken for said second sensor and a corresponding second series of viscosity values for a fluid surrounding said second sensor.

29. A method of sensing an analyte with a sensor having a chemically responsive material adhered to a base magnetostrictive element comprising the steps of:

applying a time-varying magnetic field;

applying a DC bias magnetic field;

measuring a plurality of successive values for magneto-elastic emission intensity of the sensor with a receiver operating over a range of successive interrogation frequencies to identify a magneto-elastic resonant frequency value for the sensor;

pre-correlating a series of resonant frequency values taken for the sensor and a corresponding series of material stiffness values for the sensor; and

using said identified magneto-elastic resonant frequency value and said step of pre-correlating to identify a change in material stiffness of the sensor;

wherein said receiver is an electromagnetic pick-up coil and said element is made of an alloy that remains generally unchanged over a preselected range of temperatures.